• 제목/요약/키워드: napA

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새로운 N,N,O계 세 자리 리간드의 합성과 전위차적정법에 의한 전이금속 착물의 안정도상수의 결정 (Synthesis of New N,N,O Tridentate Ligands and Determination of Stability Constants of Transition Metal Complexes by Potentiometry)

  • 김선덕;이도협
    • 한국환경과학회지
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    • 제15권8호
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    • pp.799-809
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    • 2006
  • Hydrobromic acid salts of new N, N, O tridentate ligands containing phenol, 2-[(2-Methylamino- ethyl- amino)-methyl]-phenol(H-MMP. 2HBr), 5-Bromo-2-[(2-Methylamino-ethylamino)-methyl]-phenol (Br- MMP. 2HBr), 5-Chloro-2-[(2-Methylamino-ethylamino)-methyl]-phenol(Cl-MMP. 2HBr), 5-Methyl-2-[(2-Methylamino-ethylamino)-methyl]-phenol(Me-MMP. 2HBr), 5-Methoxy-2-I(2-Methylamino-ethylamino)- methyl]-phenol(MeO- MMP. 2HBr) and. 1-[(2-Methylamino-ethylamino)- methyl]-naphthalen-2-ol(Nap- MMP. 2HBr) were synthesized. The synthesized ligands were confirmed by C. H. N. atomic analysis, UV-visible and IR spectroscopies, $^1$H NMR, $^{13}$C NMR and mass analysis. The potentiometry study revealed that the proton dissociation constants(logK$_n^H$) of the synthesized ligands and stability constants (logK$_{ML}$, logK$_{LM2}$) of transition metal complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) ions occurred in three steps and the order of the calculated overall proton dissociation constants(log$\beta_p$) and stability constants (logK$_{ML}$) of ligands was Br-MMP. 2HBr < Cl-MMP 2HBr < H-MMP. 2HBr < Nap-MMP. 2HBr < Me-MMP. 2HBr < MeO-MMP. 2HBr. The order showed a similar trend to that of Hammett substituent constants($\delta_p$). The synthesized ligands usually form 2:1(ML$_2$) complexes with transition metal ions. The order of the stability constants of each transition metal ions was Co(II) < Ni(II) < Cu(II) ;> Zn(II) ;> Cd(II) ;> Pb(II).

Physical Analysis of nahQ tnpA Genes from Pseudomonas fluorescens

  • Seol, Ja-Young;Chol, Soon-Young;Min, Kyung-Hee
    • Journal of Microbiology
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    • 제39권4호
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    • pp.338-342
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    • 2001
  • Pseudomonas fluorescens SM11 is a naphthalene-degrading strain whose dissimilatory genes are cho-mosomally encoded. We have cloned the 2.9 kb Sal I fragment harboring genes for the naphthalene-degrading upper pathway. The nucleotide sequences were determined to be nahQ, napA, and partial regions of nahE genes. The nahQ encods a protein of 188 amino acid residues with a deduced molec-ular wight of 20.8kDa. The high homology with other proteins suggests that NAhQ may be an active and useful protein whtich gives as selective advantage to naphthalene degradatin. Transposase(TnpA)encodes a polypetide chain with a molecular mass of 41.8kDa consisting of 376 amino acid residues. The deduced anino acid sequence of tnpA revealed 96% idenitity with putative transposase of P. stutzeri OX1,. It was assumed that transposase plays an important role in the evloution of the catabloic-path way in the regulation of nah expression.

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지형도 공급단가 결정에 관한 연구 (A study on the Decision of the Map Price)

  • 박경식;박지언;김창우;이재기
    • 한국측량학회:학술대회논문집
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    • 한국측량학회 2004년도 춘계학술발표회논문집
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    • pp.413-418
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    • 2004
  • The purpose of this research calculates the map manufacture cost and there are we even though we determine proper map price. We distinguished the budget item of NGI in 2003 with the direct cost to the overhead cost. A map manufacture cost classified a direct and overhead cost as a nap manufacture cost commonness cost and no relation cost and was calculated. The result to analyze the item of the charge, It is impossible to withdraw the map manufacture cost selling the map. This is because a map sale price inexpensive than the map manufacture price. We presented a two alternative in research to see consequently about a map price raising.

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디퓨저/노즐을 이용한 압전형 마이크로 펌프의 펌핑 특성에 미치는 입출구 위치의 영향 (Effect of Inlet and Outlet Position on the Pumping Characteristics of a Diffuser/Nozzle Based Piezoelectric Micropumps)

  • 장훈희;김창녕;정진
    • 설비공학논문집
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    • 제19권5호
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    • pp.411-417
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    • 2007
  • This study has been conducted to investigate pumping characteristics of diffuser/nozzle based piezoelectric micropumps. The micropumps include a piezo disk (an actuator), a chamber and a set of diffuser and nozzle. Flow in the current micropumps is controlled by a set of diffuser and nozzle, not by a nap valve. The diffuser/nozzle based micropumps are more reliable in operation and are easier in manufacturing than the flap valve based micropumps. The flow rates of the piezoelectric micropumps have been closely analyzed with a numerical calculation. It has been found that the positions of the inlet and outlet of the micropump can influence the performance of the diffuser/nozzle based piezoelectric micropumps. This study may provide fundamental understanding for the design and analysis of the piezoelectric micropumps.

졸음운전과 교통사고 (Drowsy Driving and Traffic Accidents)

  • 이상학
    • 수면정신생리
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    • 제10권2호
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    • pp.84-87
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    • 2003
  • Drowsy driving is a major cause of automobile crashes and can lead to more serious injuries than other causes of traffic accidents. Factors increasing the risk of drowsy driving and related crashes include sleep loss, late night driving, untreated or unrecognized sleep disorders, use of sedating medications and consumption of alcohol. Young people, especially young males, shift workers, and people with untreated sleep apnea syndrome and narcolepsy are well known as the population groups at highest risk. To prevent drowsy driving and its consequences, getting adequate and quality sleep is both easier and much more successful than any remedial measure. Other helpful behaviors include avoidance of alcoholic beverages and limiting late night driving. Taking a short nap or consuming caffeine can make a short-term difference in driving alertness. In addition, information should be actively provided to the public about the importance of sleep disorders and their consequences. To reduce injuries and death caused by drowsy driving, it is a prerequisite to increase public awareness that drowsy driving can cause serious automobile crashes and has morbidity and mortality rates as high as those of drunk driving.

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암반에 근입된 SIP 말뚝의 지지력 특성에 관한 연구 (A Study on the Characteristics of Bearing Capacity for SIP Piles constructed on Rock Mass)

  • 김태훈;박준홍;이송
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2002년도 춘계학술대회 논문집
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    • pp.295-300
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    • 2002
  • In this research problems of recent design methods and their improvement for SIP in domestic areas were studied by using the characteristics of load-settlement curves and bearing capacity from field loading tests. Elastic and plastic settlement for total settlement in each loading step conducted domestic areas had a tendency. From these tendency and bearing capacity determined by loading tests we can ascertain that empirical chart can be assistant tool in SIP design. It showes that SIP design using N-value in domestic area with soil condition of grarute type results in very conservative bearing capacity, to be opposed in soil with unprofitable geological condition the design can be insecure. Also, we can ascertain that Meyerhof's bearing capacity used modified N-value on tip part of pile is more applicable than recent design method where tip bearing capacity is 20NAp N-value limited to 50. These results show that modified design method can he more economic than before because of using pile's bearing capacity to tolerable load of pile material.

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The Environmental Change of Korea based on the Isopollen Map during the Holocene

  • Yoon, Soon-Ock
    • 한국제4기학회지
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    • 제22권2호
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    • pp.6-11
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    • 2008
  • Vegetation change reconstructed by pollen analysis is effective to clarify natural conditions such as climate and soil as well as intensity of human activity. Pollen analysis in Korea is difficult to obtain peaty soil sedimented by low relief geomorphollogically and formation age is usually confined to obtain information during young Holocene as well as little absolute age data. Isopollen map was constructed in order to analyze the change of vegetation environment time-spatially during Holocene based on the 30 data with age dated from 78 results from pollen analysis in Korea. The indicatives for vegetation environment were the main trees in Korea such as Alnus, Pinus, Quercus and AP/NAP during the periods of 6,000 y.BP, 4,000 y.BP, 3,000 y.BP, 2,000 y.BP, 1,000 y.BP. As a result, the regional time-spatial patterns of vegetation distribution appeared clearly on the isopollen map. The dominant vegetation stage was repeated in the different pattern e.g. the dominance between Alnus and Quercus at West Coast and between Pinus and Quercus at East Coast competitively.

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Two New Records of the Ichneumonidae (Hymenoptera) Species from Korea

  • Kim, Chang-Jun;Kang, Gyu-Won;Lee, Jong-Wook
    • Animal Systematics, Evolution and Diversity
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    • 제28권4호
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    • pp.317-321
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    • 2012
  • Previously, 13 species in six genera of the subfamily Banchinae and 29 speices in 16 genera of the subfamily Pimplinae were known from Korea. In this paper, two species, Rynchobanchus minomensis (Uchida, 1933) and Theronia laevigata nigra Uchida, 1928 are new to Korea. Also, the genus Rynchobanchus is recorded for the first time in Korea. Only one species of Theronia, Theronia atalantae (Poda, 1761), was recorded from Korea by Uchida (1928). New Korean names proposed for these two species are "Eol-gul-ga-si-maep-si-beol" and "Geom-jeong-nap-jak-maep-si-beol" for the R. minomensis and T. laevigata nigra, respectively. A key to the species of Theronia, diagnosis and photographs of diagnostic characters of them are provided.

평택지구 토탄의 화분분석 (A Pollen Analysis in the Peat Sediments from Pyung Taek County Korea)

  • 오지영
    • Journal of Plant Biology
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    • 제14권3호
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    • pp.66-73
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    • 1971
  • Pollen analysis was made on peat deposits in the area of Pyung Taek County, Central Korea. Arboreal pollen(AP) of Alnus, Abies, Ligustrum, Viburnum and Carpinus composed 70-80% of the total pollen detected in this sample area. Judging from the large amount of arboreal pollens, one can assume that those species were dominant in this district when the pollen was deposited. Among the arboreal pollens, Alnus pollen occurred more often than any other trees. Pollens of Betula, Tilia and Ulmus occurred rarely in each layers of peat deposit. The pollen diagram showed that Pinus and Abies markedly increased from the bottom to the top of the peat, while Ligustrum, Quercus and Tilia decreased proportionately. Non-arboreal pollens (NAP) and spores composed about 30 percent at the lower layer, but decreased considerably in the upper layer.

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설악산 식물군락 유기물층의 화분분석학적 연구 (Pollen Analytical Study on Humus Accumulated at Plant Communities of Mt. Seolag)

  • 강상준
    • Journal of Plant Biology
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    • 제30권4호
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    • pp.267-276
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    • 1987
  • A pollen analytical study was carried out on the accumulated humus samples collected from 27 sites under the different plant communities of Mt. Seolag. These pollen spectra were then compared with the actual vegetation. The aboreal pollen(AP) and non-abnoreal pollen(NAP) were 1 Family 25 Genus and 5 Family 5 Genus, respectively. Among the aboreal pollen identified, the pollen of Pinus, Quercus, Betula and Acer were appeared in abundance and the coniferous pollen of Pinus was occupied at least 20%-65% through all the sites studied. The pollens of Abies, Betula, accer, Quercus, Carpinus, Corylus, Fraxinus, Styrax, Prunus and Ericaceae were in accordance with the present vegetation but the other pollens were inconsistent with the actual vegetaton. It suggests that it was caused by the difference between Wehseolag and Namseolag of subalpine zone in Mt. Seolag was 200 m by pollen spectra. Quercus was distributed at the lower part of Namseolag and the subalpine boreal elements were increased with increasing altitudes. The pollen spectra of each site was put together into 5 groups of pollen assemblage by cluster analysis and the community coefficient (CC) was over 60% between all sites studied.

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