• 제목/요약/키워드: nano electrode

검색결과 552건 처리시간 0.026초

ITO/CNT 나노 복합체의 염료감응형 태양전지의 이용 (ITO/CNT Nano Composites as a Counter Electrode for the Dye-Sensitized Solar Cell Applications)

  • 박종현;;정현준;조태연;윤순길
    • 한국전기전자재료학회논문지
    • /
    • 제24권1호
    • /
    • pp.76-80
    • /
    • 2011
  • The ITO/Cabon Nano Tube (CNT) nano composites were deposited by nano cluster deposition (ITO) and arc discharge deposition (CNT) on glass substrates. The structural, optical and photovoltaic performance of ITO/CNT nano composites as a counter electrode of dye-sensitized solar-cells (DSSCs) such films were investigated. At low temperature below $250^{\circ}C$, the ITO films deposited on CNT. The ITO/CNT nano composit showed a good optical and electrical property for the counter electrode of DSSCs. When the as-prepared ITO/CNT nano composites are used for the counter electrodes, the photovoltaic parameters are $V_{OC}$ = 0.69 V, $J_{SC}$ = 5.69 mA/$cm^2$, FF = 0.32, and $\eta$ = 0.53 %. The ITO/CNT nano composites showed the possibility for the counter electrode applications of DSSCs.

다층 RIE Electrode를 이용한 아크릴의 O2/N2 플라즈마 건식 식각 ([O2/N2] Plasma Etching of Acrylic in a Multi-layers Electrode RIE System)

  • 김재권;김주형;박연현;주영우;백인규;조관식;송한정;이제원
    • 한국재료학회지
    • /
    • 제17권12호
    • /
    • pp.642-647
    • /
    • 2007
  • We investigated dry etching of acrylic (PMMA) in $O_2/N_2$ plasmas using a multi-layers electrode reactive ion etching (RIE) system. The multi-layers electrode RIE system had an electrode (or a chuck) consisted of 4 individual layers in a series. The diameter of the electrodes was 150 mm. The etch process parameters we studied were both applied RIE chuck power on the electrodes and % $O_2$ composition in the $N_2/O_2$ plasma mixtures. In details, the RIE chuck power was changed from 75 to 200 W.% $O_2$ in the plasmas was varied from 0 to 100% at the fixed total gas flow rates of 20 sccm. The etch results of acrylic in the multilayers electrode RIE system were characterized in terms of negatively induced dc bias on the electrode, etch rates and RMS surface roughness. Etch rate of acrylic was increased more than twice from about $0.2{\mu}m/min$ to over $0.4{\mu}m/min$ when RIE chuck power was changed from 75 to 200 W. 1 sigma uniformity of etch rate variation of acrylic on the 4 layers electrode was slightly increased from 2.3 to 3.2% when RIE chuck power was changed from 75 to 200 W at the fixed etch condition of 16 sccm $O_2/4\;sccm\;N_2$ gas flow and 100 mTorr chamber pressure. Surface morphology was also investigated using both a surface profilometry and scanning electron microscopy (SEM). The RMS roughness of etched acrylic surface was strongly affected by % $O_2$ composition in the $O_2/N_2$ plasmas. However, RIE chuck power changes hardly affected the roughness results in the range of 75-200 W. During etching experiment, Optical Emission Spectroscopy (OES) data was taken and we found both $N_2$ peak (354.27 nm) and $O_2$ peak (777.54 nm). The preliminarily overall results showed that the multi-layers electrode concept could be successfully utilized for high volume reactive ion etching of acrylic in the future.

반응성 이온 식각법에 의해 제작된 탄소나노튜브 전극의 전기화학적 특성 (Electrochemical Properties of Individual Carbon Nanotube Fabricated by Reactive Ion Etching)

  • 황숙현;최현광;김상효;한영문;전민현
    • 한국재료학회지
    • /
    • 제21권2호
    • /
    • pp.89-94
    • /
    • 2011
  • In this work, fabrication and electrochemical analysis of an individual multi-walled carbon nanotube (MWNT) electrode are carried out to confirm the applicability of electrochemical sensing. The reactive ion etching (RIE) process is performed to obtain sensitive MWNT electrodes. In order to characterize the electrochemical properties, an individual MWNT is cut by RIE under oxygen atmosphere into two segments with a small gap: one segment is applied to the working electrode and the other is used as a counter electrode. Electrical contacts are provided by nanolithography to the two MWNT electrodes. Dopamine is specially selected as an analytical molecule for electrochemical detection using the MWNT electrode. Using a quasi-Ag/AgCl reference electrode, which was fabricated by us, the nanoelectrodes are subjected to cyclic voltammetry inside a $2{\mu}L$ droplet of dopamine solution. In the experiment, RIE power is found to be a more effective parameter to cut an individual MWNT and to generate "broken" open state, which shows good electrochemical performance, at the end of the MWNT segments. It is found that the pico-molar level concentration of analytical molecules can be determined by an MWNT electrode. We believe that the MWNT electrode fabricated and treated by RIE has the potential for use in high-sensitivity electrochemical measurement and that the proposed scheme can contribute to device miniaturization.

Dependence of Xe Plasma Flat Fluorescent Lamp On the Electrode Gap and Dielectric Layer Thickness

  • Kang, Jong-Hyun;Lee, Yang-Kyu;Heo, Sung-Taek;Oh, Myung-Hoon;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
    • /
    • pp.1519-1521
    • /
    • 2007
  • In this work, a coplanar-type plasma flat fluorescent lamp having cross type of electrode was fabricated by screen printing and sealing technique. Cross type of electrode with a dielectric layer were screen-printed on a rear glass plate, and then fired at $550^{\circ}C$. Phosphor was printed on and fired at $450^{\circ}C$. Finally, the lamp was sealed by frit glass at $450^{\circ}C$. The lamp of cross electrode type was studied depending on the electrode gap and the thickness of dielectric layer.

  • PDF

Characterization of Photoelectron Behavior of Working Electrodes with the Titanium Dioxide Window Layer in Dye-sensitized Solar Cells

  • Gong, Jaeseok;Choi, Yoonsoo;Lim, Yeongjin;Choi, Hyonkwang;Jeon, Minhyon
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
    • /
    • pp.346.1-346.1
    • /
    • 2014
  • Porous nano crystalline $TiO_2$ is currently used as a working electrode in a dye-sensitized solar cell (DSSC). The conventional working electrode is comprised of absorption layer (particle size:~20 nm) and scattering layer (particle size:~300 nm). We inserted window layer with 10 nm particle size in order to increase transmittance and specific surface area of $TiO_2$. The electrochemical impedance spectroscope analysis was conducted to analysis characterization of the electronic behavior. The Bode phase plot and Nyquist plot were interpreted to confirm the internal resistance caused by the insertion of window layer and carrier lifetime. The photocurrent that occurred in working electrode, which is caused by rise in specific surface area, increased. Accordingly, it was found that insertion of window layer in the working electrode lead to not only effectively transmitting the light, but also increasing of specific surface area. Therefore, it was concluded that insertion of window layer contributes to high conversion efficiency of DSSCs.

  • PDF

나노 채널 구조를 가진 산화 주석 박막 전극 제조 및 전기화학적 특성 평가 (Fabrication of Nano-Channeled Tin Oxide Film Electrode and Evaluation of Its Electrochemical Properties)

  • 박수진;신헌철
    • 한국재료학회지
    • /
    • 제22권1호
    • /
    • pp.1-7
    • /
    • 2012
  • Thin film electrode consisting purely of porous anodic tin oxide with well-defined nano-channeled structure was fabricated for the first time and its electrochemical properties were investigated for application to an anode in a rechargeable lithium battery. To prepare the thin film electrode, first, a bi-layer of porous anodic tin oxides with well-defined nano-channels and discrete nano-channels with lots of lateral micro-cracks was prepared by pulsed and continuous anodization processes, respectively. Subsequent to the Cu coating on the layer, well-defined nano-channeled tin oxide was mechanically separated from the specimen, leading to an electrode comprised of porous tin oxide and a Cu current collector. The porous tin oxide nearly maintained its initial nano-structured character in spite of there being a series of fabrication steps. The resulting tin oxide film electrode reacted reversibly with lithium as an anode in a rechargeable lithium battery. Moreover, the tin oxide showed far more enhanced cycling stability than that of powders obtained from anodic tin oxides, strongly indicating that this thin film electrode is mechanically more stable against cycling-induced internal stress. In spite of the enhanced cycling stability, however, the reduction in the initial irreversible capacity and additional improvement of cycling stability are still needed to allow for practical use.

염료감응형 태양전지의 탄소나노튜브 상대전극의 광투과도와 전기화학적 특성이 에너지 변환 효율에 미치는 영향 (Effect of Electrochemical Properties and Optical Transmittance of Carbon Nanotubes Counter Electrodes on the Energy Conversion Efficiency of Dye-sensitized Solar Cells)

  • 한영문;황숙현;강명훈;김영주;김현국;김상효;배효준;최현광;전민현
    • 한국전기전자재료학회논문지
    • /
    • 제24권4호
    • /
    • pp.333-339
    • /
    • 2011
  • In this work, electrochemical characteristics and optical transmittance of carbon nanotubes (CNTs) counter electrodes which had different amount of CNTs in CNTs slurries were analyzed. Two-step heat treatment processes were applied to achieve well-fabricated CNTs electrode. Three sets of CNTs electrodes and dye-sensitized solar cells (DSSCs) with CNTs counter electrodes were prepared. As the amount of CNTs increased, sheet resistance of CNTs electrode decreased. CNTs electrode with low sheet resistance had low electrochemical impedance and fast redox reaction. On the other hand, in case of CNTs counter electrode with low density of CNTs, performance of the dye-sensitized solar cell was improved due to its high optical transmittance. We found that the transmittance of CNTs counter electrode influence the performance of dye-sensitized solar cells.

높은 위상지연값을 갖는 FFS mode에서 전극 위치에 따른 전기광학적 특성 연구 (Study on electro-optical characteristics of FFS mode with high $d{\Delta}n$ according to the electrode position)

  • 하경수;조은미;박지웅;김성수;정준호;김민수;김미영;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
    • /
    • pp.310-311
    • /
    • 2008
  • We have studied electro-optical characteristics of fringe-field switching (FFS) mode with high $d{\Delta}n$ according to the electrode position. In this device, the fringe-electric field drives the LCs to rotate so that the dielectric torque is electrode-positional dependent, which results in electrode-position dependency in the LC's rotating angle. We confirmed polarization microscope image and chromaticity diagram at the different electrode position with LC that have high $d{\Delta}n$. Since the FFS mode is influenced by horizontal and vertical electric field, the FFS mode modulates light using both phase retardation and polarization rotation effect, which had already been verified with previous studies. However, from another point of view, tight modulation of FFS mode has been demonstrated by performing experiment and calculated simulation at the high $d{\Delta}n$ LC cell.

  • PDF

액정 매질내의 풀러린 입자의 Dielectrophoretic force를 이용한 전자종이 디스플레이의 연구 (Research on electricnic paper-like displays using dielectrophoretic force of fullerene particles immersed in liquid crystal medium)

  • 김미경;김미영;김성민;;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
    • /
    • pp.57-58
    • /
    • 2009
  • The dynamics of nano or micro sized-particles in liquid crystal (LC) medium under an external electric field is of theoretical and technological interest. A fullerene of 10 wt% was doped into the LC medium and its electric field induced motion was controlled by both in-plane and vertical electric fields. In the proposed device, pixel electrode I and pixel electrode II were designed consecutively on the bottom substrate and common electrode on the top of the substrate. When the electric field was applied, the fullerenes start to move in direction of applied electric field. The dark, grey and white states in the proposed device can be obtained by suitable combination of the polarity of applied electric field at pixel electrode I, pixel electrode II and common electrode. The dynamical motions of fullerene particles in LC medium suggest that fullerene can be designed for electronic-paper like displays.

  • PDF