• Title/Summary/Keyword: n-6/n-3 ratio

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Effect of Influent C/N Ratio and DO on Denitrification of Nitrate Polluted Groundwater in a Biofilter Process (Biofilter 공정에서 유입 C/N비와 DO가 지하수의 질산성 질소제거에 미치는 영향)

  • Lee, Moo-Jae;Park, Sang-Min;Park, Noh-Back;Jun, Hang-Bae;Kim, Kong-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.355-361
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    • 2006
  • In this study, effects of influent C/N(COD/Nitrate) ratio and dissolved oxygen(DO) concentration on biological nitrate removal from groundwater were investigated in the fixed-type biofilter. Influent nitrate of 30 mg/L was removed completely by biological denitrification at the C/N ratio of 10 and 4.0, while residual nitrate of 5 mg/L occurred at the C/N ratio of 2.0, which resulted from deficiency of organic electron donor. Furthermore, nitrite was accumulated up to about 5 mg/L as the C/N ratio decreased to 2.0. Increase in DO concentration also inhibited denitrification activity at the relatively high C/N ratio of 5.0, which decreased the nitrate removal efficiency. Although the influent DO concentration was reduced as low as 0.3 mg/L using sodium sulfite($Na_2SO_3$), effluent nitrite was up to 3.6 mg/L. On the other hand, nitrate was completely removed without detection of nitrite at the DO concentration of 0.3 mg/L using nitrogen gas($N_2$) sparging. The organic matter for denitrification in biofilter were in the range from 3.0 to $3.5gSCOD/g{NO_3}^--N$, while utilized these values increased at the high DO concentration of 5.5 mg/L. In addition to the high DO concentration and the low influent C/N ratio, DO control by chemical such as sodium sulfite affected on biological denitrification, which resulted in the reduction of nitrate removal efficiency and nitrite build-up in a biofilter.

Performance of cyclic loading for structural insulated panels in wall application

  • Nah, Hwan-Seon;Lee, Hyeon-Ju;Choi, Sung-Mo
    • Steel and Composite Structures
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    • v.14 no.6
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    • pp.587-604
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    • 2013
  • There are few technical documents regulated structural performance and engineering criteria in domestic market for Structural insulated panels in Korea. This paper was focused to identify fundamental performance under monotonic loading and cyclic loading for SIPs in shear wall application. Load-displacement responses of total twelve test specimens were recorded based on shear stiffness, strength, ultimate load and displacement. Finally energy dissipation of each specimen was analyzed respectively. Monotonic test results showed that ultimate load was 44.3 kN, allowable shear load was 6.1 kN/m, shear stiffness was 1.2 MN/m, and ductility ratio was 3.6. Cyclic test was conducted by two kinds of specimens: single panel and double panels. Cyclic loading results, which were equivalent to monotonic loading results, showed that ultimate load was 45.4 kN, allowable shear load was 6.3 kN/m. Furthermore the accumulated energy dissipation capability for double panels was as 2.3 times as that for single panel. Based on results of structural performance test, it was recommended that the allowable shear load for panels should be 6.1 kN/m at least.

Evaluation of the Nutritional and Storage Quality of Meatballs Formulated with Bee Pollen

  • Turhan, Sadettin;Yazici, Fehmi;Saricaoglu, Furkan Turker;Mortas, Mustafa;Genccelep, Huseyin
    • Food Science of Animal Resources
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    • v.34 no.4
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    • pp.423-433
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    • 2014
  • In this study, the nutritional and storage quality of meatballs formulated with different levels (0, 1.5, 3.0, 4.5 and 6.0%) of bee pollen were investigated during storage at $41^{\circ}C$ for 9 d. Protein content of meatballs increased, while moisture content decreased with increased pollen. The addition of pollen improved cooking loss but decreased the redness (Hunter a value) and sensory scores. Textural parameters (hardness, springsness, gumminess, and chewiness) were affected by pollen addition and the hardness and gumminess values of meatballs decreased as the pollen content increased. While C18:0 content of meatballs slightly decreased with pollen addition, C18:2n-6c, C18:3n-3, C20:5n-3, and PUFA contents increased. The PUFA/saturated fatty acids (P/S) ratio increased from 0.05 in the control to 0.09 in meatballs with 6.0% pollen. The n-6/n-3 ratio decreased from 11.84 in the control to 3.65 in the meatballs with 6.0% pollen. The addition of pollen retarded the lipid oxidation and inhibited the bacterial growth in meatballs. The pH, redness, TBA value and total aerobic mesophilic bacteria, coliform bacteria and S. aureus counts values changed significantly during storage. The results suggest that bee pollen could be added to enhance the nutritional and storage quality of meatballs with minimal changes in composition and/or sensory properties.

Effect of Magnesium and Calcium Ions on the Phosphorus Removal by Aluminium Coagulation (마그네슘 및 칼슘 이온이 알루미늄 응집에 의한 인 제거에 미치는 영향)

  • Tian, Dong-Jie;Lee, Beom;Lee, Young-Ju;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.4
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    • pp.231-236
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    • 2011
  • The effects of magnesium and calcium ions on phosphorus removal by aluminium coagulation were investigated with various jar tests using settled raw sewage. Maximum TP (total phosphate) removal occurred at pH around 5~6 with aluminium coagulation, and it decreased above pH 6. TP and $H_nPO_4^{n-3}$ removal efficiencies, however, were kept above 95% at pH above 6 by adding the divalent metallic ions like magnesium or calcium ions on aluminium coagulation process. At molar ratio of Al/P ($Al^{3+}/H_nPO_4^{n-3}$) above 3, TP removal efficiency was as high as 80%, and residual TP less than 0.2 mg/L occurred at Al/P ratio above 6. TP removal efficiency was improved by adding magnesium or calcium ions and the optimum $Al^{3+}/Mg^{2+}$ and $Al^{3+}/Ca^{2+}$ ratios were about 2. The required dose of aluminium coagulant was reduced for equivalent amount of TP removal by adding magnesium or calcium ions, as a result sludge generation was also reduced.

Effects of Type of Oilseed and Level of Concentrate on Fermentation, Biohydrogenation of Fatty Acids and Conjugated Linoleic Acid Production in a Rumen-Simulated Continuous Culture System (지방급원 형태와 수준에 따른 연속배양장치 내 반추위 발효성상, 지방산의 수소첨가 현상 및 Conjugated Linoleic Acid 생산에 미치는 영향 연구)

  • Choi, N.J.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.617-626
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    • 2003
  • This experiment employed a rumen simulated continuous culture system to examine the possibility of improving the rumen bypass of polyunsaturated fatty acids (PUFA) by using a high proportion of concentrate in the feed, and compared soya and linseed in terms of conjugated linoleic acid (CLA) production. No effect of type of fat source was observed on ruminal fermentation. A high proportion of concentrate (80%) in the feed decreased (P<0.001) vessel pH but increased (P<0.01) ammonia nitrogen, total VFA, acetate, butyrate and valerate concentrations compared with a low proportion (40%). Fat sources (soya vs. linseed) and concentrate ratio in the feed did not affect digestibilities of organic matter (OM), total nitrogen, neutral detergent fiber (NDF) and acid detergent fiber (ADF). Soya increased the flows of trans C18:1, C18:2 n-6 and C18:3 n-3 compared with linseed. The difference in fat source alone did not affect the flow of CLA but this was increased when high levels of soya and linseed were associated with a high proportion of concentrate in the feed. There was no effect of fat source on biohydrogenation of C18:1 n-9 and C18:2 n-6, but biohydrogenation of C18:3 n-3 and total C18 PUFA was higher with the linseed than with the soya treatment. A high proportion of concentrate decreased biohydrogenation of C18:2 n-6, C18:3 n-3 and total C18 PUFA compared with a low proportion.

Biodegradation Enhancement of The Mixture of Kerosene and Diesel by using Biosurfactant from Pseudomonas aeruginosa F722 (Pseudomonas aeruginosa F722부터 유래된 biosurfactant를 이용한 등.경유 혼합물의 생분해율 향상)

  • ;;;skubo Motoki
    • KSBB Journal
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    • v.18 no.6
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    • pp.529-535
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    • 2003
  • We studied degradation effects of hydrophobic substrate such as kerosene and diesel by adding a biosurfactant originated from Pseudomonas aeruginosa F722 and chemical surfactants (Tween 80 and detergent) with aeration. The surface tensions of the biosurfactant, Tween 80 and detergent were 30mN/m, 39mN/m and 31mN/m, respectively. When the concentration of biosurfactant added in C-medium was 0.01 and 0.15%(w/v), the ratios of hydrocarbon degradation were 94.3% and 94.2% respectively. It was 6.2%(w/v) higher than when the concentrations of added biosurfactant were 0.05, 0.1 and 0.2%. The degradation ratios of the chemical surfactants (Tween 80 and detergent) were 94.5% and 93.5% respectively. The effects of the biosurfactant and chemical surfactants were similar on the degradation ratio in mixtures of kerosene and diesel. However, the population of viable p. aeruginosa F722 at the end of the cultivation period was twice as higher in the biosurfactant than that in the chemical surfactant. We also studied the effect of aeration (0.5vvm) on the degradation ratio. The biosurfactant addition experiment was conducted with 0.5vvm air, 35$^{\circ}C$, 150rpm, pH 8.0, 3days, 1.0% (w/v) substrate. When p. aeruginosa F722 and 0.15%(w/v) biosurfactant were added, the degradation ratio of hydrocarbon was 94.8%. Without p. aeruginosa F722, it was 68%. Thus, with aeration, the degradation ratio of hydrocarbon was increased by 26.8%. In addition, the cultivation time was shortened by 1/3. The degradation ratios of hydrocarbon in shaking culture (cultivation time; 3days) and stationary culture (cultivation time; 10days) were 94.8 and 93.7% respectively. Thus, the addition of biosurfactant and aeration enhanced the degradation of hydrocarbon originated kerosene and diesel.

MR Spectoscopic Patterns Early and Late Cerebral Ischemic Infarct: Correlation with Clinical Findings (초기 및 지연기 허혈성 뇌경색의 양자 자기공명분광양상 : 임상소견과의 비교)

  • 이종석;장기현;송인찬;고영환;강동화;한문희;노재규
    • Investigative Magnetic Resonance Imaging
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    • v.3 no.2
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    • pp.146-153
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    • 1999
  • Purpose : To evaluate the proton MR spectroscopy (MRS) findings of early and late ischemic infarcts and to compare these MRS findings with clinical symptoms. Materials and Methods : We obtained MRs spectra of 28 consecutive patients with early ischemic infarct (15 me, 13 women) between 2-10 (mean 6.2) days after stroke onset. Follow-up MRS was carried out between 20-32 (mean 25) days in 12 patients. The MRs spectra were acquired at 1.5T MR unit using single voxel technique with PRESS sequence, TR of 2000ms, TE of 288 (144)ms, and voxel size of 2cm x 2cm x 2cm in the three areas; an infarct lesion, the brain parenchyma adjacent to the lesion, and contralateral normal brain parenchyma. The NAA/creatine, choline/creatine, and lactate/creatine ratios were calculated in each spectrum. The spectra of MRS were compared with clinical symptoms. Results : In early infarct, decreased NAA/creatine ratio (n=22) and increased lactate/creatine ratio (n=25) were found in the infarct lesion. Choline/creastine ratio was within normal range (n=25). On follow-up MRS in late stage, NAA/creatine ratio in the infarct lesion decreased further (n=5), did not change (n=6), or increased (n=1). Lactate/creatine ratio became less elevated (n=10), or did not changed (n=2). Choline/creatine ratio had a trend for increase. The decreased NAA/creatine and increased lactate/creatine ratios were correlated well with the severity of symptoms, respectively. Conclusion : Decreased NAA/creatine and increased lactate/creatine ratios were common MRS findings characteristic in early ischemic infarct and correlated well with clinical severity. On follow-up MRS in late stage, NAA/creatine ratio decreased further or did not change, and lactate/creatine ratio became less elevated.

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Concentrations and Natural 15N Abundances of NO3-N in Groundwater and Percolation Water from Intensive Vegetable Cultivation Area in Japan (일본 노지채소 집약 재배지역 토양 침출수 중의 NO3-N 농도와 질소 안정동위원소 자연존재비(δ15N))

  • Park, Kwang-Lai;Choi, Jae-Seong;Baek, Hyung-Jin;Kim, Won-Il;Jung, Goo-Bok;Yun, Sun-Gang;Cho, Jin-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.3
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    • pp.119-126
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    • 2003
  • Nitrate-N concentrations and the corresponding ${\delta}^{15}N$ values were determined with water samples collected periodically from artesian wells (3 and 6 m deep), underdrainage and gushout waters in a Welsh onion cultivated area in the Kushibiki Fan, Saitama Prefecture, Japan. Average $NO_3-N$ concentrations in waters from 3 and 6 m wells were 25.7 and $2.8mg\;L^{-1}$, whereas ${\delta}^{15}N$ values were 3.6 and 4.7‰, respectively. The $NO_3-N$ concentration and ${\delta}^{15}N$ value of the underdrainge water were $35.5mg\;L^{-1}$ and 6.6‰, reflecting rapid input of chemical fertilizers and farmyard manure. The mean values of $NO_3-N$ concentration and ${\delta}^{15}N$ in the gushout water flown out of the edge of Kushibiki Fan were $19.4mg\;L^{-1}$ and 7.9‰, respectively. As a results the ${\delta}^{15}N$ values of the gushout water were higher than those of the artesian wells and underdrinage water. The ${\delta}^{15}N$ values of total-N and $NO_3-N$ of the soils were 6.1 and 5.10‰, respectively, while those for nitrification-inhibitor containing fertilizer and slow-release fertilizers were -6.1 and -2.2‰, respectively.

Backfat Characteristics of Barrows and Gilts Fed on Tuna Oil Supplemented Diets during the Growing-finishing Periods

  • Jaturasitha, S.;Srikanchai, T.;Chakeredza, S.;ter Meulen, U.;Wicke, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.8
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    • pp.1214-1219
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    • 2008
  • This study was conducted to evaluate the effect of supplementing tuna oil to diets of growing-finishing pigs (barrows and gilts) on backfat characteristics when slaughtered at different weights. Four hundred and eighty crossbred (Large White$\times$Landrace$\times$Duroc) pigs averaging 30 kg were allotted to 12 treatment combinations (40 pigs/treatment combination) in a completely randomized design with a $2{\times}2{\times}3$ factorial arrangement of treatments. The treatments were: dietary tuna oil supplementation (0 and 2%); sex (barrows and gilts); and slaughter weight (90, 100 and 110 kg). As pigs reached their slaughter weight, they were randomly selected (8 pigs/treatment combination; 96 pigs in total) and slaughtered. Backfat colour, hardness and fatty acid profile were assessed. There were significant (p<0.05) differences in colour (L* and a* values) among treatments. Backfat of the control group was harder than on the tuna oil (p<0.001) and that of barrows was harder than of gilts (p<0.05). In addition, the thiobarbituric acid reactive substances (TBARS) values of fat from the tuna oil group stored for 3 days were higher (p<0.001) than the control group. The TBARS values of gilts tended to be higher than those of barrows and increased with increasing slaughter weight in the tuna oil group. The cholesterol and triglyceride levels were not affected by diet and sex but the triglyceride level increased with increasing slaughter weight (p<0.01). The tuna oil group had higher polyunsaturated fatty acid (PUFA) content, ratio of PUFA: saturated fatty acid (SFA) and total n-3 fatty acids but lower monounsaturated fatty acids content and n-6:n-3 fatty acids than the control group (p<0.01). Gilts had higher PUFA and n-6 fatty acids in backfat than barrows (p<0.05). The backfat from both 90 and 100 kg slaughter-weight groups had a lower ratio of n6:n3 fatty acid than the 110 kg slaughter-weight group (p<0.05). However, this was more pronounced in the tuna oil group. The PUFA: SFA was also increased while the n-6:n-3 ratio tended to reach the recommended levels for healthy eating in human beings of <5. However, due to oxidative susceptibility, barrows should not be slaughtered at more than 100 kg for the meat to be acceptable to consumers.

Evaluation of indirect N2O Emission from Nitrogen Leaching in the Ground-water in Korea (우리나라 농경지에서 질소의 수계유출에 의한 아산화질소 간접배출량 평가)

  • Kim, Gun-Yeob;Jeong, Hyun-Cheol;Kim, Min-Kyeong;Roh, Kee-An;Lee, Deog-Bae;Kang, Kee-Kyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1232-1238
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    • 2011
  • This experiment was conducted to measure concentration of dissolved $N_2O$ in ground-water of 59 wells and to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector in agricultural areas of Gyeongnam province from 2007 to 2010. Concentrations of dissolved $N_2O$ in ground-water of 59 wells were ranged trace to $196.6{\mu}g-N\;L^{-1}$. $N_2O$ concentrations were positively related with $NO_3$-N suggesting that denitrification was the principal reason of $N_2O$ production and $NO_3$-N concentration was the best predictor of indirect $N_2O$ emission. The ratio of dissolved $N_2O$-N to $NO_3$-N in ground-water was very important to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector. The mean ratio of $N_2O$-N to $NO_3$-N was 0.0035. It was greatly lower than 0.015, the default value of currently using in the Intergovernmental Panel on Climate Change (IPCC) methodology for assessing indirect $N_2O$ emission in agro-ecosystems (IPCC, 1996). It means that the IPCC's present nitrogen indirect emission factor ($EF_{5-g}$, 0.015) and indirect $N_2O$ emission estimated with IPCC's emission factor are too high to use adopt in Korea. So we recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector. Using the estimated value of 0.0034 as the emission factor ($EF_{5-g}$) revised the indirect $N_2O$ emission from agricultural sector in Korea decreased from 1,801,576 ton ($CO_2$-eq) to 964,645 ton ($CO_2$-eq) in 2008. The results of this study suggest that the indirect Emission of nitrous oxide from upland recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector.