• 한국세라믹학회지
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• 제52권2호
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• pp.83-91
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• 2015

The redox reaction $M^{(x+n)+}+\frac{n}{2}O^{-2}{\rightleftarrows}M^{x+}+\frac{n}{4}O_2$ of multivalent ions in glass melts influences the melting process and final properties of the glass including the fining (removal of bubbles), infrared absorption and homogenization of melts, reaction between metal electrodes and melts or refractory and melts, and transmission and color of glass. In this review paper, the redox behaviors that occur frequently in the glass production process are introduced and the square wave voltammetry (SWV) is described in detail as an in situ method of examining the redox behavior of multivalent ions in the melt state. Finally, some voltammetry results for LCD glass melts are reviewed from the practical viewpoint of SWV.

• 상하수도학회지
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• 제18권5호
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• pp.573-579
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• 2004

Electroflotation, which is used as an alternative to sedimentation, is a separation treatment process that uses small bubbles to remove low-density particulates. Making allowances for recent collision efficiency diagram based on trajectory analysis, it is necessary to tailor zeta potential of bubbles that collide with negatively charged particles. In this paper, the study was performed to investigate the effects of magnesium and aluminium ions on zeta potential of bubbles. And, it was studied to find out factors which could affect the positively charged bubbles. Consequently, zeta potential of bubbles increased both with higher concentration of metal ions and in the acidic pH value. And, a probable principle that explained the procedure of charge reversal could be a combined mechanism with both specific adsorption of hydroxylated species and laying down of hydroxide precipitate. It also depended on the metal ion concentration in the solution to display its capacity to control the bubble surface.

• 대한화학회지
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• 제67권4호
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• pp.222-225
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• 2023

Metallic salts of C10-18 aliphatic carboxylic acids were prepared and their scanning electron microscopic images were analyzed for the morphology dependency with the metal and the carboxylic acid. Regardless of metal ion, metal salts of dicarboxylic acids showed a high crystallinity with a fiber image (SuA-Na). The aromatic dicarboxylates also represented a morphology of a rectangular-rod or board shapes (IA-Li, IA-Ba). With Na ion, most aliphatic carboxylate (MA, PA, SA) showed a fiber-like crystallinity. However, other monovalent Li, K and multivalent Mg, especially Al ion resulted a glassy-amorphous in the metallic salts of acids (MA, PA, SA). With divalent Ba and Ca ions, the metal salt of aliphatic acids expressed a branched round cluster shape as in SA-Ca, SA-Ba. Both Li and Mg ions with a similar size showed a strong morphological similarity in the metallic salts of aliphatic acids MA, PA, SA. In the case of Na and Ca ions with a similar size (98, 106 pm), both ionic salts of stearic acid gave a branching effect for a fiber or round granular image. In the case of hydroxyl-aliphatic acids (HLA, HPA, HSA), the fiber images in HLA-Na and HSA-Na was appeared about 100 nm thicker than those of nonhydroxycarboxylates (LA-Na, SA-Na). The metallic salts of unsaturated C-18 carboxylic acids (OlA, LeA and LnA) showed an amorphous glassy image due to a kinked carbon chain.

• 멤브레인
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• 제13권3호
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• pp.143-153
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• 2003

본 연구에서는 양이온교환막 표면에 형성된 바이폴라 계면이 물분해 현상에 미치는 영향을 조사하였다. 실험결과, 전기투석 중 막표면에 형성된 고정화된 바이폴라 계면이 심각한 물분해를 유발함을 알 수 있었다. 특히, 고정화된 바이폴라 계면은 다가 양이온이 전해질로 이용되는 전기투석 시스템에서 양이온교환막 표면에 쉽게 형성됨을 알 수 있었다. 낮은 용해도적 상수를 갖는 다가 양이온들은 급격한 물분해를 유발하였는데 이는 이들이 막표면에서 쉽게 수산화물의 형태로 침적되며 따라서 수소-친화 그룹과 수산화-친화 그룹으로 구성된 바이폴라 계면이 막-용액 계면에 형성됨을 알 수 있었다. 따라서 물분해는 막 표면의 금속수산화물 층과 막의 고정전하 그룹간에 발생되는 강한 전기장에 의해 크게 활성화됨을 알수 있다. 또한 이와 유사하게 분자량이 큰 유기 상대이온들이 막표면에 누적되는 경우에도 고정화된 바이폴라 계면이 형성되어 한계전류밀도 이상에서 심각한 물분해를 유발하였다. 따라서 전기투석의 고전류 운전시 효율 향상을 위해서는 막표면에 유발되는 고정화된 바이폴라 계면의 형성을 억제하는 것이 매우 중요함을 알 수 있다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1993년도 지반.환경 매립에 관한 학술발표회 논문집
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• pp.28-44
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• 1993

Remediation actions in uncontrolled landfill site should be conducted after the investigation of contamination status and potential health risk or damage. Based on the above, proper control measures should be established and operated. Also continuous monitoring should be followed. In this study, the status of ground water contamination around Nanji Landfill Site was investigated. Monitoring wells were installed around the landfill and ground water was sampled once a month and analyzed. Water quality of each monitoring well was different depending on the horizontal and vertical distance from the landfill, and the seasonal leachate characteristics were not significantly changed because percolating water stayed long time in the deep waste layer. It was predicted that major multivalent cations were mainly precipitated as metal carbonate form, and chemical mass balances (CMBs) could be applied for the apportionment of leachate contamination to ground water quality of surrounding areas of Nanji Landfill. Parameters required to estimate pollutant flux to the receptor near landfill were listed and discussion to get these parameters was made. Finally, based on the above data, control measures of ground water contamination were suggested and discussed.

• 분석과학
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• 제30권2호
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• pp.75-81
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• 2017

5-methylthioninhydrin (5-MTN) is an amino acid sensitive reagent used for the development of latent fingermarks deposited on porous surfaces such as paper and wood. The present study demonstrates that the 5-MTN can be used as a latent footwear impression enhancement reagent, by reacting with trace multivalent metal ions, which are the main components of the latent footwear impression. 5-MTN and L-alanine complex (MTN-ALA) used for the latent footwear impression development was prepared, by mixing $4.5{\times}10^{-3}M$ 5-MTN (in methanol) and $4.5{\times}10^{-3}M$ L-alanine (in methanol) in 1:1 ratio, and keeping undisturbed at room temperature for 24 h. The latent footwear impressions were deposited on white and black non-porous surfaces (glass plate, polyethylene panel, polypropylene panel, acryl panel, polyvinyl chloride (PVC) panel, poly(methyl methacrylate) (PMMA) panel, acrylonitrile-butadiene-styrene (ABS) panel, tile), and a semi-porous surfaces (painted wood). The latent footwear impressions on these surfaces were treated with MTN-ALA complex by spraying. The fluorescence of footwear impressions (occurred due to the reaction between MTN-ALA and metal complexes) was observed under a 505 nm forensic light source and an orange barrier filter. The enhancement of latent footwear impression was achieved from black surfaces without any blurring. However, the fluorescence (enhancement) of footwear impression was not observed on the white PVC, PMMA, and ABS surfaces, because the incident light interfered and reflected on the surface. The sensitivity of MTN-ALA was superior to 2,2'-dipyridil, which is a representative non-fluorescing footwear impression enhancement reagent, and similar to 8-hydroxyquinoline, which is a representative fluorescing footwear impression enhancement reagent.

• Ecology and Resilient Infrastructure
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• 제4권1호
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• pp.63-70
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• 2017

가축용 항생제로 널리 사용되는 Tetracycline (TC)군은 주로 가축 분뇨를 통하여 환경에 퍼지게 된다. TC는 환경 내에서 중금속 양이온과의 리간드 결합을 통해 토양으로의 흡착량과 그 이동성이 변화되리라 예측된다. 그러나 지금까지 수용액 내에서 토양 외 반응을 통해 확인되었고 토양 내에서 식물에 대한 영향 평가는 미비한 실정이다. 본 연구의 목적은 토양 내 구리가 TC와 반응하여 TC에 의한 식물 독성에 미치는 영향을 확인하는데 있다. 본 실험은 토양에 $750mg\;kg^{-1}$의 TC와 각각 0, 2.5, 7.5, $17.5mg\;kg^{-1}$의 $CuSO_4$를 처리한 후, 처리된 토양에 상추를 재배하여 처리 농도에 따른 상추의 성장 정도를 비교하였다. 실험 결과 상추에 유의한 독성이 나타나는 것으로 확인된 $750mg\;kg^{-1}$의 TC가 처리된 토양에서 구리의 처리가 상추에 발현되었던 독성을 저감시키는 것을 확인하였다.