• Title/Summary/Keyword: multivalent

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Nitrate Ion-Selective Membrane Electrode Based on Complex of Ammonia Modified Bakelite A-Ni(II) Nitrate (Bakelite A-Ni(II) 착물의 질산이온 선택성 막전극)

  • Kim, Hwan-Ki;Shin, Doo-Soon
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.271-279
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    • 1987
  • A nitrate ion-selective PVC membrane electrode based on ammonia modified bakelite A-Ni$(NO_3)_2$ complex as ion exchanger was prepared. The electrode gave a linear response with a Nernstian slope of 60mV per decade within the concentration range $1{\sim}10^{-4}$ M $KNO_3$ but nonresponse to hydrogen ion and multivalent anions. The selectivity, response time and life time of the electrode were investigated and it was found that the electrode exhibited good selectivity for four univalent anions ($Cl^-,\;Br^-,\;I^-,\;{ClO_4}^-$). Analytical application to the determination of nitrate were also studied.

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Ettect of Electrolytes on Flow Properties of Aqueous Bentonite Suspension

  • Kisoon Park;Taikyue Ree;Henry Eyring
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.303-312
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    • 1971
  • Dependence of the flow behavior of aqueous suspension of Black Hills bentonite on the concentration and the types of electrolytes was stydied. The flow properties were measured with a Couette-type totational viscometer. On addition of monovalent cations, the apparent viscosity determined from the reproducible flow curves (shear rate vs. shear stress) decreased followed by a rise as the ionic concentration further increased. Addition of multivalent cations (di- and tri-) resulted in the viscosity which increased to a maximum then decreased to a constant value. Anions of different chatges produced essentially the same relationship between viscosity and electrolyte concentration. The flow behavior of the electrolyte-containing suspensions was rationalized in terms of the Derjaguin-Landau-Verwey-Overbeek theory of colloidal stability and the generalized theory of viscosity.

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Characteristics of Groundwater Contamination in Uncontrolled Landfill and Pollution Control Measures (불량 매립지에서의 지하수 오염특성과 환경오염 방지방안)

  • 구자중;윤석표
    • Proceedings of the Korean Geotechical Society Conference
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    • 1993.05a
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    • pp.28-44
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    • 1993
  • Remediation actions in uncontrolled landfill site should be conducted after the investigation of contamination status and potential health risk or damage. Based on the above, proper control measures should be established and operated. Also continuous monitoring should be followed. In this study, the status of ground water contamination around Nanji Landfill Site was investigated. Monitoring wells were installed around the landfill and ground water was sampled once a month and analyzed. Water quality of each monitoring well was different depending on the horizontal and vertical distance from the landfill, and the seasonal leachate characteristics were not significantly changed because percolating water stayed long time in the deep waste layer. It was predicted that major multivalent cations were mainly precipitated as metal carbonate form, and chemical mass balances (CMBs) could be applied for the apportionment of leachate contamination to ground water quality of surrounding areas of Nanji Landfill. Parameters required to estimate pollutant flux to the receptor near landfill were listed and discussion to get these parameters was made. Finally, based on the above data, control measures of ground water contamination were suggested and discussed.

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Effect of Electrolytes on Rheological Properties of Young-Il Bentonite Suspension

  • Shin, Wha-Woo;Lee, Kwang-Pyo
    • Archives of Pharmacal Research
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    • v.8 no.2
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    • pp.91-98
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    • 1985
  • Dependence of the flow behavior of aqueous suspension of Young-Il bentonite on the concentration and the type of electrolytes was studied. Viscosity measurements were made was Rion Viscotester, using No. 3 rotor at 62.5 R. P. M. at 25.deg.C. As electrolyte concentration increased, the apparent viscosity was observed to increase. Changes in viscosity were in general agreement with predicted results based on the Hofmeister sequence and the Schulze-Hardy rule. The observed electrolyte effect on the apparent viscosity was discussed in terms of the Verwey-Overbeek theory.

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The Discussion of Glass Waveguide formed by ton-exchange (이온교환 방법에 의한 유리도파로 특성 고찰)

  • 박정일;김봉재;박태성;정흥배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.130-132
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    • 1994
  • We fabricated Ag ion exchange glass waveguide. Generally, ion-exchange glass waveguide. are suitable for passive integrated optical components such as directional and star couplers. Its advantages include low loss, ease of fabrication, and low material cost. So, we faricated Ag ion-exchange glass waveguides in AgNO$_3$ melt solution from 2 mole %. And we used Sodalime glass as a substrate in the fabrication process. As the results, we observed multivalent ion-exchange in a typical sodalime glass. Diffusion coefficient and depth are predicted by actual experimental data of Stewart. The exchange rate in silver-ion-exchanged waveguides are compared to the exchange time of waveguide fabrication.

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A case Study of Built in Kitchen System

  • Lee, Sae-Hwan
    • Journal of the Korea Furniture Society
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    • v.17 no.4
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    • pp.27-48
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    • 2006
  • Most of us spend the greater part of our lives in the kitchen, but of all the man environments it maybe the least well-explored share commitment to a cleaner and healthier environment. It has long been kitchen system belief that the environment is a precious gift. In case of built in kitchen system, because it depend upon the earth's resources to design and manufacture steel hardware products, human beings feel an abiding responsibility to act wisely in the environmental choices we make, large and small, every day. Built in kitchen system, designed and coordinated by study of designer, represents an open, complete, free and 'focused' way of conceiving, furnishing and organizing one's own kitchen. A space rich in technical values and home warmth, where few, simple and carefully designed components distinguish and characterize the various work spaces, from the area, intended for preparing and washing food, to the cooking area, and to a wide range of multivalent pieces of furniture, wood paneled wall units and shelves.

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A CLASS OF MULTIVALENT FUNCTIONS WITH NEGATIVE COEFFICIENTS DEFINED BY CONVOLUTION

  • Ali Rosihan M.;Khan M. Hussain;Ravichandran V.;Subramanian K.G.
    • Bulletin of the Korean Mathematical Society
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    • v.43 no.1
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    • pp.179-188
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    • 2006
  • For a given p-valent analytic function g with positive coefficients in the open unit disk $\Delta$, we study a class of functions $f(z) = z^p - \sum\limits{_{n=m}}{^\infty} a_nz^n(a_n{\geq}0)$ satisfying $$\frac 1 {p}{\Re}\;(\frac {z(f*g)'(z)} {(f*g)(z)})\;>\;\alpha\;(0{\leq}\;\alpha\;<\;1;z{\in}{\Delta})$$ Coefficient inequalities, distortion and covering theorems, as well as closure theorems are determined. The results obtained extend several known results as special cases.

MHC Multimer: A Molecular Toolbox for Immunologists

  • Chang, Jun
    • Molecules and Cells
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    • v.44 no.5
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    • pp.328-334
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    • 2021
  • The advent of the major histocompatibility complex (MHC) multimer technology has led to a breakthrough in the quantification and analysis of antigen-specific T cells. In particular, this technology has dramatically advanced the measurement and analysis of CD8 T cells and is being applied more widely. In addition, the scope of application of MHC multimer technology is gradually expanding to other T cells such as CD4 T cells, natural killer T cells, and mucosal-associated invariant T cells. MHC multimer technology acts by complementing the T-cell receptor-MHC/peptide complex affinity, which is relatively low compared to antigen-antibody affinity, through a multivalent interaction. The application of MHC multimer technology has expanded to include various functions such as quantification and analysis of antigen-specific T cells, cell sorting, depletion, stimulation to replace antigen-presenting cells, and single-cell classification through DNA barcodes. This review aims to provide the latest knowledge of MHC multimer technology, which is constantly evolving, broaden understanding of this technology, and promote its widespread use.

Electrostatic Adsorption of Uniformly Charged Electrolytes within Like-charged Electrodes

  • Jang, Seanea;Shin, Ghi Ryang;Kim, Soon-Chul
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1315-1323
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    • 2018
  • The classical-fluids density functional theory has been developed for studying the structural and the electrical properties of electrolyte solutions containing uniformly charged hard-spherical ions. The modified fundamental-measure theory has been used to evaluate the hard-sphere contribution. The mean-field approximation has been employed to calculate the cross correlation between the hard sphere contribution and the Coulomb interaction. The Poisson equation for ions carrying charges that are spatially separated has been solved. The present theory shows reasonably good agreement with the corresponding Monte Carlo simulation results. The calculated results show that the attraction between like-charged planar surfaces is the result of the intra-ionic correlation and depends strongly on the ion size, valence, mole fraction, and charge distribution of electrolytes.

Sorption of Eu(III) and Th(IV) on Bentonite Colloids Considering Their Precipitation and Colloid Formation (침전 및 콜로이드 형성을 고려한 Eu(III)와 Th(IV)의 벤토나이트 콜로이드에 대한 수착)

  • Baik, Min-Hoon;Lee, Jae-Kwang;Lee, Seung-Yeop;Kim, Seung-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.2
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    • pp.129-139
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    • 2008
  • In this study, a sorption experiment of multivalent nuclides such as Eu(III) and Th(IV) relatively stable for redox reactions was carried out for bentonite colloids which had been prepared from the domestic Gyeongju bentonite. The amounts of the nuclides lost by an attachment to bottle walls, by a precipitation, and by a colloid formation were estimated by performing blank tests for the sorption experiments. Sorption coefficients, $K_d's$, reflecting the mass losses were obtained and investigated for the sorption of Eu(III) and Th(IV) onto the bentonite colloids. The net sorption coefficients $K_d's$ considering all the three mass losses were measured as about $10^6-10^7\;mL/g$ and $7{\times}10^6-10^7\;mL/g$ for Eu(III) and Th(IV), respectively, depending on pH. In particular, a precipitation occurred mainly at a pH greater than 5 for Eu(III) and a precipitation and colloid formation significantly occurred at a pH greater than 3 for Th(IV). The precipitation and colloid formation of the multivalent nuclides of Eu(III) and Th(IV) therefore should be considered when $K_d's$ are rightly obtained over the pH range where their precipitation and colloid formation become significant at a given concentration.

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