• 제목/요약/키워드: multifunctional materials

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Vacuum Filtration method를 이용한 단섬유(short fiber) 배열 영향성 분석 (Study on the Fiber Alignment using Vacuum Filtration Method)

  • 이성권;김무선;이호용;최성웅
    • Composites Research
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    • 제36권3호
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    • pp.162-166
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    • 2023
  • 복합재료는 일반적인 고강도 구조체에 활용성이 증가하고 있지만 최신의 복합적인 전자기기 내부 소자 등과 같은 multifunctional 재료들의 성능 특성 요구가 증가하고 있다. 기기의 방열 특성의 경우 대표적으로 요구되는 물성인 반면 복합재료의 경우 적층 공정으로 인해 수직 방향의 열적 특성 제어는 해결해야 될 문제 중 하나이다. 본 연구에서는 vacuum filtration 방법을 이용하여 Carbon fiber reinforced polymer를 제작하였다. 복합재료 제작 공정에서는 섬유들의 분산에 활용성이 가장 뛰어난 세 가지 solvent들을 사용하여 solvent의 영향을 살펴보았다. 또한 세가지의 aspect ratio를 가지는 단섬유 carbon fiber들의 수직 방향의 배열성을 확인하기 위해 현미경을 통한 morphology를 관찰하였고 제작된 시편의 열전도도 측정을 통해 배열성을 검토하였다. 시편의 열전도도 측정 결과 단섬유 carbon fiber의 aspect ratio가 낮을수록 높은 열전도도를 보였으며 through-plane 방향의 열전도도는 DMF, NMP, Acetone 순으로 각각 8.69 W/m·K, 10.32 W/m·K, 13.01 W/m·K의 증가되는 값을 보였다.

Reaction Condition Dependency of Propagating Behavior in the Polymerization Reaction by Thermal Front

  • Huh, Do-Sung;Choe, Sang-Joon;Lee, Burm-Jong
    • Bulletin of the Korean Chemical Society
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    • 제23권2호
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    • pp.325-329
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    • 2002
  • In this study, the dependency of the behavior of propagating front on the reaction condition in frontal polymerization reaction has been studied. We have used some multifunctional acrylates as a monomer and ammonium persulfate as an initiator for the polymerization reactions. In frontal polymerization, a method of producing polymeric materials via a thermal front that propagates through the unreacted monomer/initiator solution, the behavior of self propagating front shows various dynamic patterns depending on the reaction condition. We have obtained some spin modes of propagating front in the number of 'hot spots' or 'spin heads' by changing the reaction condition. The effect of the reactor tube diameter on the mode of propagating front has also been studied by using some reactor tubes with different size of tube diameter and it has been examined in some detail by adopting an experimental method of two-tubes system.

Nanoporous Block Copolymer Micelle/Micelle Multilayer Films with Dual Optical Properties

  • Cho, Jin-Han;Hong, Jin-Kee;Char, Kook-Heon;Caruso, Frank
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.310-310
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    • 2006
  • We have demonstrated the formation of highly nanoporous films composed of two different BCMs through layer-by-layer (LbL) assembly on substrates. The films thus prepared showed tunable optical properties, with strong antireflective properties with light transmission above 99%. Considering the wide application areas of both LbL multilayers and block copolymer thin films, the approaches introduced in present study are likely to open up new possibilities for devices with multifunctional properties.

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Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • 한국세라믹학회지
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    • 제40권12호
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

굽힘 성형을 위한 금속 샌드위치 판재의 내부구조재 개발 (The Development of Inner Structure of Metallic Sandwich Plates for Bending)

  • 성대용;정창균;윤석준;심도식;이상훈;안동규;양동열
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 추계학술대회 논문집
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    • pp.301-304
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    • 2005
  • Metallic sandwich plates are ultra-light materials with not only high strength and stiffness but also multifunctional. Inner dimpled shell structure can be fabricated by piecewise sectional forming process, and then bonded with same material face sheets by resistance welding. Tests have shown that sandwich plates with dimpled shell structure subject to bending have more collapse load, energy absorption and deflection before collapse than other types of sandwich plates. Consequently, inner dimpled shell structure can improve formability of sandwich plates for bending.

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Dye-resist Properties of Hetero-multifunctional Dye-resist Agents in Acid Dyeing of Wool

  • Oh Myung-Joon;Koh Joon-Seok;Kim Jae-Pil
    • Fibers and Polymers
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    • 제7권2호
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    • pp.117-122
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    • 2006
  • The dye-resist effect and leveling properties of hetero-mulifunctional dye-resist agents in acid dyeing of wool were investigated. The dye-resist agent with dichlorotriazinyl group achieved better resist effectiveness than those with monochlo-rotriazinyl group. The resist effectiveness was improved by increasing the number of sulfonate group in dye-resist agents. Also, the resist agents with more sulfonate groups showed better dye-assist effectivness, attributable to the increased electrostatic attraction between dye-resist agents and the cationic dye. However, the leveling properties of dye-resist agents decreased with the number of sulfonate groups in the molecule.

Metalorganic chemical vapor deposition of semiconducting ZnO thin films and nanostructures

  • Kim Sang-Woo
    • 한국결정성장학회지
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    • 제16권1호
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    • pp.12-19
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    • 2006
  • Metalorganic chemical vapor deposition (MOCYD) techniques have been applied to fabricate semiconducting ZnO thin films and nanostructures, which are promising for novel optoelectronic device applications using their unique multifunctional properties. The growth and characterization of ZnO thin films on Si and $SiO_2$ substrates by MOCYD as fundamental study to realize ZnO nanostructures was carried out. The precise control of initial nucleation processes was found to be a key issue for realizing high quality epitaxial layers on the substrates. In addition, fabrication and characterization of ZnO nanodots with low-dimensional characteristics have been investigated to establish nanostructure blocks for ZnO-based nanoscale device application. Systematic realization of self- and artificially-controlled ZnO nanodots on $SiO_2/Si$ substrates was proposed and successfully demonstrated utilizing MOCYD in addition with a focused ion beam technique.

치과용 고분자 수복재료의 개발 (Development of Dental Restorative Materials)

  • 정찬문;안광덕
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 추계학술대회
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    • pp.140-141
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    • 1996
  • Bis-GMA is an important component in commercial dental restorative composites, but its hydroxy groups are considered to promote water absorption of the cured composite in a mouth. In this work, multifunctional methacrylates were prepared by blocking the hydroxy groups in bis-GMA with methacryloyl groups. Comparing to bis-GMA, new prepolymers having three methacryloyl groups (BPA-3M) and four methacryloyl groups (BPA-4M) showed much lower viscosities. Photopolymerization conversion of BPA-3M was slightly higher than that of bis-GMA. Water absorption of the photo-cured composite containing BPA-3M was measured for one month and found to be much lower than that of bis-GMA.

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농촌마을 어메니티 자원의 속성별 가치 평가 - 농촌다움의 가치평가 - (Valuing Amenity attributes of Farm Village using Choice Experiment - Valuing Rurality-)

  • 정현희
    • 농촌계획
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    • 제20권4호
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    • pp.243-252
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    • 2014
  • This study strengthens importance of farm land has possessed rurality. Thus the amenities of farm village were offered to the symbolical attributes of rurality and it was extracted four amenities attributes for valuing the amenities. Possessing the importance of rurality for agricultural and rural development and rural tourism evaluated each attribute by Choice Experiment(CE) for sustainable development make full use of rurality. Applying for Conditional-Logit model estimated the value of attributes then consumer's benefit feeling form each attributes was offered to the value of a unit change. Through this study, I wish to apply for the direction of rural development as important material and the compensation in the operation of agricultural output offering social benefit as political reference materials.

Effects of multi-walled carbon nanotubes on the hydration heat properties of cement composites

  • Ha, Sung-Jin;Rajadurai, Rajagopalan Sam;Kang, Su-Tae
    • Advances in concrete construction
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    • 제12권5호
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    • pp.439-450
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    • 2021
  • In recent years, nano-reinforcing materials are widely utilized in cement composites due to their unique multifunctional properties. This study incorporated multi-walled carbon nanotubes (MWCNTs) into the cementitious composites at ratios of 0.1%, 0.3%, and 0.5%, and investigated their influence on the flowability, mechanical strength, and hydration heat properties. The addition of MWCNTs enhanced the compressive and split tensile strengths approximately by 18-51%. In the semi-adiabatic temperature rise test, the internal hydration heat of the composites reduced by 5%, 9%, and 12% with the increase of MWCNTs in 0.1%, 0.3%, and 0.5%. This study further performed hydration heat analysis and estimated the adiabatic temperature rise, thermal stress, and thermal crack index. The internal hydration heat of the concrete decreased by 5%, 10%, and 13% with the increase of MWCNTs. The thermal stress of the concrete decreased with increase in the addition of MWCNTs, and the obtained temperature crack index was effective in controlling the thermal cracks.