• Title/Summary/Keyword: morphology formation

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The Effect of Solvent and Solvent-Additives of Polymeric Dope Solutions on Membrane Morphology (용매와 용매 첨가제가 고분자 막 구조에 미치는 영향 연구)

  • 원종옥;박철민;강용수;박현채;김은영
    • Membrane Journal
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    • v.7 no.4
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    • pp.191-198
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    • 1997
  • Membrane formation mechanism by the phase inversion has been investigated in order to control the membrane morphology. It was found that finger-like structures were obtained when the heat of mixing between the solvent and non-solvent is exothermic, while sponge-like structures were obtained when they are endothermic in polystyrenes as well as in polyimides (Torlon and polyimide made frorn 3,3'4,4'-benzophenontetracarboxylic diahmydride and 1,4-phenylene diarnine) membranes. This concept was applied to control the morphology of polysulfone membranes simply by adding a solvent additive by adjusting the heat of mixing. A crude, but simple, relationship between the heat of mixing and the exchange rate of the solvent with non-solvent has been also developed.

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Seismic characteristics of a Π-shaped 4-story RC structure with open ground floor

  • Karabini, Martha A.;Karabinis, Athanasios J.;Karayannis, Chris G.
    • Earthquakes and Structures
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    • v.22 no.4
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    • pp.345-353
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    • 2022
  • The configuration of an open ground floor (pilotis) is a common and very critical irregularity observed in multistory reinforced concrete frame structures. The characteristics and the geometrical formation of the beams of the first story proved to be a critical parameter for the overall seismic behavior of this type of Reinforced Concrete (RC) structures. In this work the combination of open ground floor (pilotis) morphology with very strong perimetrical beams at the level of the first story is studied. The observation of the seismic damages and the in situ measurements of the fundamental period of four buildings with this morphology and Π-shaped plan view are presented herein. Further analytical results of a pilotis type Π-shaped RC structure are also included in the study. From the measurements and the analytical results yield that the open ground floor configuration greatly influences the fundamental period whereas this morphology in combination with strong beams can lead to severe local shear damages in the columns of the ground floor. The structural damage was limited in the columns of the ground floor and yet based on the changes of the in situ measured fundamental period the damaged level is assessed as DI=88%. Furthermore, due to the Π-shape of the plan view the tendency of the parts of the building to move independently strongly influences the distribution of the damages over the ground floor vertical elements.

Physical Properties of Major Bedrocks in Chungju-Goesan Area as Aggregates (충주-괴산일대에서 산출되는 주요 기반암의 골재로서의 물성특징)

  • Byoung-Woon You;Jaehyung Yu
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.649-659
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    • 2022
  • This study examined the granite, quartzite, phyllite, schist, and gneiss as aggregate resources among the original rock distributed in the Chungju-Goesan area. The granite distributed in the study area is mainly composed of Jurassic biotite granite, and the quartzite layer is from the Daehyangsan quartzite Formation distributed on the upper part of the Gyemyeongsan Formation and the Hyangsan-ri dolomitic limestone Formation. In addition, phyllite is pophyrytic phyllite-schist from the Hwanggangri Formation of the Okcheon group, schist is chlorite schist, from the Munjuri Formation of the Okcheon group, and gneiss is porphyroblastic gneiss which is the upper part of the Seochangri Formation. Aggregate quality evaluation factors of these rocks included fineness modulus, absorption, unit weight, absolute dry density, solid content, porosity, resistance to abrasion, and soundness. In the case of granite, it was found to be partially unsatisfactory in terms of unit weight, solid content, porosity, and resistance to abrasion. Gneiss was found to be out of the standard values in resistance to abrasion and schist in porosity and solid content. As for the overall quality of aggregate resources, it was analyzed that quartzite, gneiss, and phyllite showed excellent quality. Aggregate quality tests are performed simply for each rock, but the rock may vary depending on the morphology of the mineral. Therefore, when analyzing and utilizing the quality evaluation of aggregate resources, it will be possible to use them more efficiently if the rock-mineralological research is performed together.

Characteristics of the Haute Couture Design in Paris and Rome (파리와 로마의 오뜨 꾸띄르(Haute Couture) 디자인의 특성)

  • 공미선
    • Journal of the Korean Society of Costume
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    • v.39
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    • pp.39-58
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    • 1998
  • In this research, first of all, the special feat-ures of Haute Couture design world (1990∼1996) prevailed in Paris and Rome are investigated, and additionally the understanding of collection concept and design structure analysis are performed to show the various method-ology of creative design. Expression method and design method are the main criteria in analyzing, and the main results of this research are summarized as follows : 1. Most of designers in Paris and Rome ex-press the traditional costume style. Paris designers are focusing on the expression of design morphology through the abstraction and re-appearance without being confined to theme expression ; Rome designers are expressing their main ideas utilizing the fashion image as their theme in lieu of expressing the design morphology. 2. Most of the designers in Paris and Rome are using simple lines for their design. Paris designers prefer the plastic design based upon formal and symmetrical balance of informal and asymmetrical balance to the partial trans-formation design ; Rome designers are enjoy-ing rather the partial transformation using the detail and trimming than the plastic design.

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Preparation of Zein Microparticles Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 Zein 미립자 제조)

  • Ryu, Jong-Hoon;Lim, Gio-Bin
    • KSBB Journal
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    • v.27 no.4
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    • pp.237-242
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    • 2012
  • In this study, zein microparticles and drug-loaded zein microparticles were prepared using supercritical ASES technique. The effects of operating parameters on particle size and morphology were investigated. ASES-processed zein microparticles consisted of agglomerates of very fine unit particles. As temperature increased, the size of unit particles increased and their morphology became more spherical. The addition of water to the solvents for zein resulted in the formation of more spherical microparticles. The release characteristics of drug-loaded zein microparticles were also studied.

Thermal Behavior of Dickite (딕카이트의 열적 특성 연구)

  • 조현구
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.1
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    • pp.11-22
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    • 1999
  • Thermal behavior of dickite was studied by thermal analysis, X-ray diffraction analysis, electron microprobe analysis, and scanning electron microscopy, Dickite has an endothermic peak at about$ 650^{\circ}C$ and an exothermic one at $960^{\circ}C$ in the differential thermal analysis. The endothermic reaction is assigned to the decomposition of dickite to meta-dickite. Hydroxyl radicals are removed from dickite structure by the reaction, resulting in the weight loss about 10.5~14.5% and appearance of a 14$\AA$ phase different from other kaolin minerals. The reaction slowly proceed in the range of $200^{\circ}C$. As the completion of decomposition, aciclular mullite forms at the expense of meta-dickite plates with random crystallographic relationship. Mullites have diverse silica versus alumina ratio. The exothermic reaction without weight loss seems to be due to the formation of spinel and amorphous silica. The spinel phase shows cryptocrystalline globular morphology accompanying a little amount of silica. From spinel phase shows cryptocrystalling globular morphology accompanying a little amount of silica. From this work, it is suggested that mullite is formed from meta-dickite much lower temperature than the reported one in the previous works.

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Growth kinetics and pattern formation of ice dendrites at small subcoolings (작은 과냉각 상태에서 ice dendrite의 결정 성장 특성)

  • 구기갑
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.197-208
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    • 1995
  • An experiment study of the dendrite growth of ice crystals growing in quiescent pure subcooled water was made at small subcoolings of 0.035 K < ${\Delta}T$ < 1.000 K. It was observed that the growth kinetics and morphology are functions of not only subcooling but also thermal convection. When the subcooling is less than 0.35K, it was found that effect of thermal convection on growth kinetics of ice dendrites becomes important. Quantitiative measurements of growth velocity, $V_{G}$, and tip radii of the edge and basal planes, $R_{1}$ and $R_{2}$, were made simultaneously as a function of subcooling.

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Effect of Triton X-100 on the Growth and Morphology of Trichoderma koningii (Triton X-100이 Trichoderma koningii의 성장 및 형태에 미치는 영향)

  • 박희문;민경렴;맹필재;하영칠
    • Korean Journal of Microbiology
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    • v.29 no.5
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    • pp.314-318
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    • 1991
  • We investigated the effect of Triton X-100 on the growth and morphology of Trichoderma koningii by comparing various parameters representing the frowth of mold in the presence or absence of Triton X-100. The specific growth rate and doubling time of T. koningii were not affected by the addition of 0.05% Triton X-100 in batch culture. However, in the presence of Triton X-100, cultures reached its stationary phase earlier and showed reduced level in total yield of biomass. The addition of Triton X-100 into solid medium also resulted in decrease in the colony radial growth rate and this response was correlated with the formation of mycelia which showed increase in branching and septation in the presence of Triton X-100.

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Morphology and mechanical properties of LDPE/PS blends prepared by ultrasound-assisted melt mixing

  • Ryu, Joung Gul;Kim, Hyungsu;Kim, Myung Ho;Lee, Jae Wook
    • Korea-Australia Rheology Journal
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    • v.16 no.3
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    • pp.147-152
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    • 2004
  • Ultrasound-assisted melt mixing was applied to blending polystyrene (PS) and low density polyethylene(LDPE). The influence of the ultrasonic irradiation on the morphology and mechanical properties of the blends was investigated. It was observed that the domain sizes of the blend were significantly reduced and phase stability was well sustained even after a thermal treatment. Such morphological feature was consistent with the improvements in mechanical performance of the blends. The desirable results of ultrasonic compatibilization are mainly attributed to the in-situ formation of PS-LDPE copolymers as confirmed by a proper separation experiment. An important relationship between ultrasonic irradiation time and mechanical properties is revealed and an issue on the thermal stability of the blend is discussed.

Polymer Films with Electrospray Deposition, model and experiment

  • Rietveld Ivo B.;Kobayashi Kei;Yamada Hirofumi;Matsushige Kazumi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.284-284
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    • 2006
  • Electrospray deposited films of poly(vinylidene fluoride) were prepared with various conditions. A model has been developed, which provides the state of the electrosprayed droplet at impact. With a combination of the experimental films and the model calculations, it can be shown that growth rate, the increase of the sprayed solution on the substrate per second, defines the film morphology in electrospray deposition. Growth rate indicates which factors play the main role in the film formation process. The most important factors are liquid flow, surface tension and shear rate. The model can calculate the shear rate and it is shown that PVDF, and most likely polymers in general, has a large range of growth rates, where the morphology only depends on the shear rate of the depositing droplet. This method can also be used to describe electrospray deposition of other compounds.

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