• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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• pp.192-195
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• 1995

PZT powders were prepared by the molten salt synthesis method. The porous PZT was prepared from a mixture of PZT an polyvinylacohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The piezolectirc and acoustic properties with various PVA wt% were studied, Piezoelectric coefficient d$\sub$33/ of porous PZT ceramics was almost same to that of single phase PZT ceramics, The thickness mode coupling factor k$\sub$t/ was 0.53~0.59 in comparable with the single phase PZT ceramics(k$\sub$t/=0.7)

• 한국결정성장학회지
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• 제7권4호
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• pp.555-559
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• 1997

lead acetate, scandium acetate, niobium isopropoxide를 전구체로 사용한 솔-젤법으로 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말을 제조하였다. 젤 분말에 대한 결정화 거동과 상변화가 연구되었다. 솔-젤법을 이용하여 $700^{\circ}C$에서 1시간 동안 열처리를 행하여 97 % 이상의 매우 순수한 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 상을 얻을 수 있었으며 0.2 $\mu \textrm{m}$ 이하의 평균 입자 크기를 가진 매우 미세한 분말의 제조가 가능하다.

• 한국세라믹학회지
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• 제27권1호
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• pp.67-73
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• 1990

The behavior of optical properties of ion exchanged glasses was investigated inthis study. The used glasses were soda-lime-silica glasses that were produced by float process. The coloring effect by Ag colloids is measrued by spectral transmittance, color coordinates, dominant wavelength and excitation purity resulting from silver ions exchange of glasses immersed into the mixed molten salt with AgNO3. Ion exchange coloring of glasses made it possible to obtain glasses with a range from yellow to brown, and transmittance was decreased with increasing the amount of Ag colloids which reduced from Ag+ions. Also, obtain from yellow to reddish brown with increasing purity by reheating treatment in air for ion exchanged glasses. The size of Ag colloids are 0.02~0.1${\mu}{\textrm}{m}$ with ion exchange conditions.

• 한국세라믹학회지
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• 제27권1호
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• pp.127-135
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• 1990

Characteristics of the sol-gel derived (Ba1-xPbx)TiO3 powders are compared with those of powders prepared by the calcining ofmixed oxides method (CMO) and molten salt synthesis method(MSS). The sol-gel derived powder has a higher surface area (50$m^2$/g) than those of CMO(3.8$m^2$/g) and MSS(11.5$m^2$/g) derived powders. In the sol-gel method, the (Ba1-xPbx)TiO3 was synthesized at $600^{\circ}C$ for 1hr, indicating that this method has a crystalline temperature 20$0^{\circ}C$-30$0^{\circ}C$ lowr than those of the CMO and MSS methods.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.205-208
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• 1995

PZT powders were prepared by the molten salt synthesis method. The porous PZT specimens were prepared from a mixture of PZT and Polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The pulse-echo response of PZT-polymer 3-3 type composite transducer with various PVA wt.% were studied, The fall time of pulse-echo response of PZT-polymer 3-3 type composite transducer was shorten to that of solid PZT-maded transducer. Therefore, a good transmitting and receiving properties could be obtained. The distance between transducer and reflector was in good agreement both solid PZT and PZT-polymer 3-3 type composite fabricated transducer.

• Nuclear Engineering and Technology
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• 제46권3호
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• pp.395-406
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• 2014

This study provides a fundamental understanding of a cold finger melt crystallization technique by exploring the heat and mass transfer processes of cold finger separation. A series of experiments were performed using a simplified LiCl-CsCl system by varying initial CsCl concentrations (1, 3, 5, and 7.5 wt%), cold finger cooling rates (7.4, 9.8, 12.3, and 14.9 L/min), and separation times (5, 10, 15, and 30 min). Results showed a potential recycling rate of 0.36 g/min with a purity of 0.33 wt% CsCl in LiCl. A CsCl concentrated drip formation was found to decrease crystal purity especially for smaller crystal formations. Dimensionless heat and mass transfer correlations showed that separation production is primarily influenced by convective transfer controlled by cooling gas flow rate, where correlations are more accurate for slower cooling gas flow rates.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.273-273
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• 2010

최근 들어 에너지 개발과 환경문제의 해결방안으로 열전발전 및 열전냉각에 많은 관심과 연구가 진행되고 있다. 열전소재의 특성 향상을 위해 열전성능지수를 높이기 위하여 나노 입자상을 열전소재 내에 분산하고자 하는 연구가 진행되었다. Grain 내에 나노 입자를 분산하기 위해서는 원료 입자에서부터 나노 입자가 열전소재 내에 분산되어야 하며 이것은 산화물 나노입자의 코어-쉘 형성으로부터 가능하다. 이 과정에서 나노 입자를 열전소재 내에 코어로 분산하기위한 나노입자의 합성 및 제어가 필수적이다. 본 연구에서는 용융염법을 이용한 BaTiO3 나노 일자를 합성하고 이들을 용매에 분산하는 것을 목표로 하였다. 염으로는 KCl, LiCl, NaCl 및 이들의 혼합 염을 사용하였으며 염의 청가량, 염의 종류, 반응온도 및 반응시간의 변화에 따라 BaTiO3 나노 입자를 합성하였다. 또한, 합성된 나노 입자의 입자크기와 응집 제어를 통해 나노입자들의 분산 상태를 확인해 보았다. 이 결과는 SEM, TEM, 입도측정기, XRD등의 측정 결과를 통하여 확인하고자 하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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• pp.358-360
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• 1995

PZT powders were prepared by the molten salt synthesis method. The porous PZT specimens were prepared from a mixture of PZT and polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The pulse-echo response of porous PZT transducer with various PVA wt.% were studied. The fall time of pulse-echo response of porous PZT transducer was shorten to that of solid PZT-maded transducer. Therefore, a good transmitting and receiving properties could be obtained. The distance between transducer and reflector was in good agreement both solid PZT and porous PZT fabricated transducer.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 추계학술대회 논문집
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• pp.183-186
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• 1994

Porous piezoelectric ceramics of P7T have been newly developed to apply for transducers in an echo sounder PZT powders were prepared by the molten salt synthesis method. The porous PZT was prepared from a mixture of PZT and polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The piezoelectric and acoustic properties with various PVA wt.% have studied. The density of porous PZT ceramics was decreased linearly with increasing the PVA sphere wt.%. Piezoelectric coefficient d$\_$33/ of porous PZT ceramics was almost same to that of single phase PZT ceramics. The thickness mode coupling factor k$\_$t/ was ranged over 0.53∼0.59 comparable with the single phase PZT ceramics(k$\_$t/=0.7).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.330-330
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• 2011

공기 중 산소를 이용한 다양한 산화반응에 적합한 이종상 촉매 개발이 공업적으로나, 학문적으로 중요한 의미를 갖는다. 우리는 수산화 인회석(hydroxyapatite, HAP)에 Ru이 도입된 새로운 이종상 촉매를 합성하였으며, 이를 이용하여 알콜 산화 반응을 통해 반응성을 관찰하였다. 우리는 다양한 형태의 결정구조와 표면구조를 가지는 HAP를 합성하였으며, 이를 AFM, ICP, XRD, SEM를 통하여 결정구조를 분석하였다. 각각에 대해서 수용액상에서 Ion exchange 반응을 통하여 Ru를 HAP 표면에 치환하여 여러 종류의 RuHAP를 합성하였다. 특히, 알콜 산화반응을 통해 HAP의 결정 형태에 따라서 반응성의 차이를 가짐을 알 수 있었다. HAP는 Molten salt synthesis 방법을 이용하여 합성한 일정한 형태의 단결정과 무정형의 다결정 즉, 두 가지 다른 형태를 이용하여 각각에 대해 칼슘이 부족한 형태로써, Ca과 Ru과의 Ion exchange 반응을 통해 다양한 종류의 HAP를 합성하여 알콜 산화반응의 촉매로서 가지는 반응성을 연구하였다.