• Title/Summary/Keyword: modifiers

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Properties of Polymer-Modified Cement Mortars Using Methylmethacrylate - Butyl Acrylate Latexes (MMA/BA 합성 라텍스 혼입 폴리머 시멘트 모르타르의 성질)

  • 형원길;송해룡;김완기;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.123-128
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    • 2001
  • The Purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effect of the monomer ratio on the typical properties of polymer-modified mortars with methyl methacrylate-butyl acrylate latexes. The polymer latex-modified mortars are prepared with 5, 10, IS and 20% of polymer cement ratio respectively, and properties of modified mortars such as water absorption, compressive and flexural strengths, chloride-ion penetration depth are tested. The test results indicate that the monomer ratio is very important factors to characterize the strength properties of polymer-modified mortars, but the water absorption and chloride-ion penetration depth are influenced by polymer-cement ratio rather than monomer ratios.

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Studies on Rheological Properties of High Solids Coating Colors (I) - Effect of Rheology Modifiers on Viscoelastic Properties -

  • Yoo, Sung-Jong;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.39-45
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    • 2012
  • For a fundamental study for high concentration pigment coating, the effects of alkali swellable emulsion (ASE) type rheology modifier and surface adsorption emulsion (SAE) type rheology modifier on both the stability and the viscoelastic behavior of a coating color were elucidated. The coating color prepared with SAE type rheology modifier showed superior thermal and mechanical stability than that with ASE type. In the high concentration and high speed coating process, the mechanical stability of a coating color was a key parameter since both impact force and shear force were increased with the increase of coating color concentration and coating speed, respectively.

Categorial Grammar and Quantifer Floating (범주문법과 양화사 유동)

  • 강범모
    • Korean Journal of Cognitive Science
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    • v.2 no.1
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    • pp.73-86
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    • 1990
  • This study aims to give a syntactic and semantic analysis of the phe- nomenon of Quantifier Floating in the framework of Generalixed Cate- gorial Grammar. Floated quantifiers like neys-i as in Hakayngtul-i neys-i swul-ul masyessta are syntactically analyxed as VP modifiers(VP/VP), and semantically as involving nominalixed properties. Related forms like neys(NP/NP) and neys-ul(TV-TV) are also given rigorous syntactic and semantic analysis. A successful anaysis sheds light on the possiblity of using Categorial Grammar, which is subject to adjacency principle, for the (computer) processing od Korean.

Enzymatic Synthesis of Glycosyl Acrylate and Methacrylate (배당화 아크릴레이트와 메타크릴레이트의 효소적 합성)

  • Park, Dae-Won;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.1
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    • pp.37-44
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    • 2004
  • Glycosyl acrylate and methacrylate were synthesized by lipase-catalyzed esterification of vinyl acrylate and vinyl methacrylate with ${\beta}$-methyl glucoside in t-butanol as a reaction medium. At the optimum conditions of initial concentration of 150g/l ${\beta}$-methyl glucoside, molar ratio of 1 : 3, 5%(w/v) lipase(Novozym 435) and $50^{\circ}C$, we attained up to 100% conversion for enzymatic glycosylation of vinyl acrylate and vinyl methacrylate by supersaturated solvent process. The polymerizable glycosyl acrylates and methacrylate are expected to have biomedical application as hydrophilic monomers and hydration modifiers to be used for biocdmpatible hydrogel.

Bacillus subtilis 유래 Glycerol-3-phosphate Cytidylyltransferase의 화학적 수식

  • 박영서
    • Microbiology and Biotechnology Letters
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    • v.25 no.2
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    • pp.173-177
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    • 1997
  • Glycerol-3-phosphate cytidylyltransferase from Bacillus subtilis was modified with various chemical modifiers to determine the active sites of the enzyme. Treatment of the enzyme with group-specific reagents diethylpyrocarbonate, N-bromosuccinimide, or carbodiimide resulted in complete loss of enzyme activity, which shows histidine, tryptophan, and glutamic acid or aspartic acid residues are at or near the active site. In each case, inactivation followed pseudo first-order kinetics. Inclusion of glycerol-3-phosphate and/or CTP prevented the inactivation, indicating the presence of tryptophan and glutamic acid or aspartic acid residues at the substrate binding site. Analysis of kinetics of inactivation showed that the loss of enzyme activity was due to modification of a two histidine residues, single tryptophan residue, and two glutamic acid or aspartic acid residues.

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SHS of Oxide Systems Based on MCR of Quartz Modified by Organometallic Compounds

  • Soh, Dea-Wha;Tlek, Ketegenov;Z.A., Mansurov
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.666-669
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    • 2002
  • The differences of the effects of mechanical substance pre-activation in the mills with divers force effect schemes on the self-propagating high temperature synthesis (SHS) of the $SiO_2$ + 37.5% Al system were investigated. The power saturation of activated material state are estimated referring on the variations of dilatometry curve paths. The effects of activation time on the temperature of sample self-ignited in the furnace, combustion temperature and completeness of the quartz reaction with aluminium were determined. The enhancing effects of organic modifiers of quartz particle surfaces on the further SHS synthesis development were shown.

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Synthesis and characterization of visible light active photocatalytic $TiO_2$

  • Kim, Duk-Su;Park, Kyu-Sung;Kim, Il-Doo;Kim, Ho-Gi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1116-1120
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    • 2002
  • Using thermal hydrolysis and hydrothermal treatment, photocatalytic $TiO_2$ powders were synthesized. During the synthesis, the addition of other transition metals such as iron, copper, etc., affected the photocatalytic capability of synthesized powders, and enabled the activation by visible light. To enhance photocatalytic capacity of gas phase decomposition, the rate-determining adsorption rate of pollutant gases were improved via surface modification of $TiO_2$ powders. The surface modifiers were implanted using mechanochemical synthesis of dopants and photocatalytic powders.

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Polymers with Phosphodiester Bonds: from Models of Biopolymers to Liquid Membranes and Polymer-Inorganic Hybrids

  • Penczek, Stanislaw
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.89-89
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    • 2006
  • Polyalkylene phosphates - polymers that are built on the repeating unit of the diester of phosphoric acid: -[OP(O)(OH)Oalkylene]-, are known to form backbones of nucleic and teichoic acids. Various synthetic ways will be reported for the synthesis of the bare chains, where "alkylene" in the formula above means mostly two or three methylene groups. Some other structures have also been prepared. Several applications of these polymers are to be discussed, namely as liquid membranes, as components of two-block copolymers (ionic-nonionic diblock dihydrophilic) used as modifiers of CaCO3 crystallization, and as components of the inorganic-polymer hybrid materials. Some other applications in the biomedical field will also be discussed.

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Improving the Properties of Industrial Polyurethane with Nanoclay, Hectorite

  • Seydibeyoglu, M.O.;Guner, F.S.;Ece, I.;Isci, S.;Gungor, N.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.281-281
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    • 2006
  • In this study, the polyurethane which has versatile applications has been reinforced with the natural clay, hectorite. The hectorite has better properties than montmorillonite. There are studies on polyurethane and montmorillonite but polyurethane and hectorite composite is published first time. Polyurethane is industrial polyurethane which makes the study to be applicable to the industry. Exfoliated structure has been obtained without using organic modifiers due to the hydrophilic nature of the polymer matrix and the mineral clay. Mechanical properties have been improved as well.

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Strength Properties of Polymer-Modified Mortars Using Methylmethacrylate-Ethyl Acrylate Latexes according to Amount of Emulsifier (유화제 첨가량에 따른 MMA/EA 합성 라텍스 폴리머 시멘트 모르타르의 강도특성)

  • 형원길;조영철;김완기;이대수;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.421-424
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    • 2003
  • The purpose of this study is to clarify the effect of the emulsifier ratio on strength properties of the polymer-modified mortars using methylmethacrylate-ethyl acrylate(MMA/EA) latexes, and to obtain basic data necessary to develope appropriate latexes for cement modifiers. Polymer-modified mortars using MMA/EA latexes are prepared with various monomer ratios, and tested for air content, flexural and compressive strengths. From the test results, we knew that the water-cement ratio is decreased and the air content is increased with an increase in the amount of emulsifier. In general, the superior flexural and compressive strengths of polymer-modified mortars using MMA/EA latexes is obtained at a bound MMA content of 60 percent and a emulsifier ratio of 6 percent.

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