• 제목/요약/키워드: modifiers

검색결과 258건 처리시간 0.026초

Effects of Modifiers on the Supercritical $CO_2$ Extraction of Licorice (Glycyrrhiza glabra) and the Morphology of Licorice Tissue

  • Kim, Hyun-Seok;Lim, Gio-Bin;Kim, Byung-Yong
    • Food Science and Biotechnology
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    • 제14권1호
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    • pp.6-10
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    • 2005
  • Optimal extraction conditions such as pressures, temperatures, and modifiers on glycyrrhizin extraction from licorice were investigated using supercritical $CO_2\;(SC-CO_2)$ at 3 mL/min flow rate. Morphology of licorice tissue, after glycyrrhizin extraction, was examined by SEM, and absolute density ($g/cm^3$) measurement and glycyrrhizin content were determined by HPLC. Pure $SC-CO_2$ had no effect on glycyrrhizin extraction, but recovery of glycyrrhizin ($32.66{\pm}0.77%$) was enhanced when water was used as modifier. The highest recovery was $97.22{\pm}2.17%$ when 70% (v/v) aqueous methanol was added to 15% (v/v) $SC-CO_2$ at 50 MPa and $60^{\circ}C$. Under optimal extraction conditions, 30 MPa pressure and $60^{\circ}C$ heating temperature, glycyrrhizin recovery reached maximum ($102.67{\pm}1.13%$) within 60 min. Licorice tissue was severely damaged by excessive swelling, and absolute density of licorice residues was highest when aqueous methanol was used as a modifier.

소비자의 UCC 참여 유형과 참여동기 분석 (Consumer's Types of the Participation and the Motivation for the UCC Services)

  • 김연정
    • 가족자원경영과 정책
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    • 제12권1호
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    • pp.91-105
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    • 2008
  • This study identifies key determinants and types of participation in UCC Services. The research examines the how the major factors in perception of social presence, fun and entertainment, self-expression, arousal, human relations, positive feedback, information sharing, monetary business opportunity, and user friendliness of web structure contribute to participation in UCC Services. The data used in this study were collected by a web-based survey so that 629 internet users were available for analysis. Some of the practical implications of the results are follows. We have categorized that the type of people participating in UCC Services were readers, modifiers, remixers, and creators. Digital consumers directly connected with other consumers by producing their own digital contents. Multiple regression analysis among the creators group was not included due to small sample size. Self expression, fun and joy and the convenience of the web interface showed strong positive significant impacts on the UCC Service participation of all participation types. Information sharing, other's positive reputation and arousal showed a positive significant impact on the modifiers or remixers type groups. Monetary business opportunity and human relations were not significant in any UCC type group.

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X-Ray Diffractometric Study on Modification Mechanism of Matrixes for Electrothermal AAS Determination of Volatile Lead and Bismuth

  • 김영상;최종문
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.56-60
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    • 2000
  • The mechanism of a matrix modification for the trace determination of volatile lead and bismuth by an electro-thermal atomic absorption spectrophotometry was studied by a X-ray diffractometry (XRD). For the investigation of structures, the ash products of the elements were produced by using a palladium as a matrix modifier with or without aluminum or nickel as an auxiliary modifier. The same charring conditions as in the analysis of samples were applied together with much concentrated solution of analytical elements and modifiers in a graphite furnace to get a large amount of the product for XRD. The XRD patterns showed PbPd3 for lead and BiPd3 for bismuth. These mean that the reaction procedures through the charring and atomization were changed from $Pb^{2+}$ ${\rightarrow}$ PbO ${\rightarrow}$$Pb^0$ to $Pb^{2+}$ ${\rightarrow}$ PbO ${\rightarrow}PbPd_3$ ${\rightarrow}$ Pb o for lead and from $Bi^{3+}$ ${\rightarrow}$ BiO ${\rightarrow}$ Bi o to $Bi^{3+}$ ${\rightarrow}$ BiO ${\rightarrow}$ $BiPd_3$ ${\rightarrow}$ $Bi^0$ for bismuth by the addition of modifiers. The volatile elements were stabilized by the formation of palladium alloys through a charring process. Charring temperatures were raised about 500 $^{\circ}C$ by the alloying and the atomization was also stabilized for the enhancement of sensitivities.

충격보강제에 의한 PLA stereocomplex의 강인화 연구 (Toughening of PLA stereocomplex by Impact modifiers)

  • 남병욱;이범석
    • 한국산학기술학회논문지
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    • 제13권2호
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    • pp.919-925
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    • 2012
  • 광학 이성질체인 PLLA와 PDLA를 전 조성에서 블렌드하여 PLA stereocomplex(SC)를 제조하였고 DSC를 통해 PLLA matrix안의 SC결정 형성 정도를 파악하였다. 결과적으로 PLA SC blend의 PDLA 함량이 SC 결정 생성 정도에 영향을 주며 PLLA/PDLA=50/50의 조성일 때 가장 많은 SC 결정이 생성되었다. 더 나아가 고유의 낮은 충격강도를 보강하기 위하여 PLLA/PDLA=92/8, 85/15 조성에서 충격보강제(Impact modifiers)를 도입하였다. 제조된 PLA SC/Impact modifiers의 열적기계적 성질은 DSC, HDT, Izod Impact tester, UTM을 통해 측정하였다. DSC 측정 결과 PLA SC 결정은 Strong120(Impact modifier)가 10-20wt% 도입되면 감소하는 경향을 보이나 반면에 Elvaloy가 도입될 때에는 아무런 영향을 주지 않는 것으로 관찰되었다. HDT의 값은 PDLA의 도입에 따라 급격하게 $100^{\circ}C$이상으로 증가하였다. 하지만 Strong120과 Elvaloy가 도입됨에 따라 감소하는 경향을 보였다. 결국 Toughening된 PLA SC에서 10wt%의 Impact modifier를 blend하여 가장 최적의 충격강도와 굴곡탄성율을 갖는 물성을 발견할 수 있었다.

A 4-step Inference Method for Natural Language Propositions Involving Fuzzy Quantifiers and Truth Qualifiers

  • Okamoto, Wataru
    • 한국지능시스템학회:학술대회논문집
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    • 한국퍼지및지능시스템학회 2003년도 ISIS 2003
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    • pp.579-582
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    • 2003
  • In this paper, we propose a 4-step inference method needed for constructing a natural language communication system. The method is used to obtain fuzzy quantifier Q′when QA is Fisr τ⇔ Q′(m′A) is mF is m"is τ is inferred (Q, Q′: quantifiers, A: fuzzy subject, m′, m": modifiers, y: fuzzy predicate, τ: truth qualifier). We show that Q′is resolved step by step for two types of Q, including a non-increasing type (few,...) and a non-decreasing type(most,...).

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아크릴산과 메타크릴산의 효소적 배당화 (Enzymatic Glycosylation of Acrylic Acid and Methacrylic Acid)

  • 박돈희;김해성
    • KSBB Journal
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    • 제16권1호
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    • pp.82-86
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    • 2001
  • Glyco-acrylate and methacrylate were synthesized by lipase-catalyzed glycosylation of acrylic acid, methacrylic acid and their vinyl esters with $\beta$-methyl fructoside and glycerol in t-butanol as a reaction medium. At the optimum conditions for enzymatic glycosylation of acrylic acid and vinyl methacrylate, we attained up to 80% conversion for glyco-acrylate from acrylic acid and 90% conversion for glyco-methacrylate from vinyl methacrylate. The polymerizable glyco-acrylates and methacrylate have biomedical application as hydrophilic monomers and hydration modifiers to be use for hydrogel contact lens formulation.

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English Floating Quantifiers and Lexical specification of Quantifier Retrieval

  • Yoo, Eun-Jung
    • 한국언어정보학회지:언어와정보
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    • 제5권1호
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    • pp.1-15
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    • 2001
  • Floating quantifiers(FQs) in English exhibit both universal and language specific proper- ties This paper discusses how such syntactic and semantic characteristics can be explained in terms of a constraint-based, lexical approach to the floating quanti- fer construction within the framework of Head-Driven Phrase Structure Grammar(HPSG). Based on the assumption and FQs are base-generated VP modifiers, this paper proposes and account in which the semantic contribution of FQs consists of a "lexically retrieved" universal quantifier taking scope over the VP meaning.P meaning.

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Application of Ionic Liquids as Mobile Phase Modifier in HPLC

  • Polyakova Yulia;Koo Yoon-Mo;Row Kyung-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제11권1호
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    • pp.1-6
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    • 2006
  • Ionic liquids are receiving an upsurge of interest as 'green' solvents; primarily as replacements for conventional media in chemical processes. Although ionic liquids are rather 'young' modifier, their great potential in high-performance liquids chromatography (HPLC) has already been demonstrated. This review presents an overview of the applications of ionic liquids as mobile phase modifiers in HPLC.

New Analytical Method Using Polar Modifiers in Supercritical Fluid Chromatography and Its Application to the Separation of Fatty Alcohol Ethers

  • 표동진;이규선;이학주;김호현;Milton L. Lee
    • Bulletin of the Korean Chemical Society
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    • 제17권6호
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    • pp.496-498
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    • 1996
  • Fatty alcohol ethers, nonionic surfactants which are used as general purpose emulsifiers were separated by use of water-modified carbon dioxide mobile phase in capillary supercritical fluid chromatography. Much greater peak intensities and improved separation were observed in the chromatogram with on-line modified mobile phase than with pure CO2. A simple method for the preparation of on-line modified mobile phase is also introduced.

Gasoline engine black sludge - occurrence, causes & testing

  • Lewis, Eric-J.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1987년도 제6회 학술강연회초록집
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    • pp.1-27
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    • 1987
  • 1. Gasoline engine sludge is a major worldwide problem 2. U.S. and European sludge have similarities 3. Stop-go driving and longer oil drains make the problem worse 4. Fuel is a major influencing factor 5. Increased use of cracked components may be cause 6. Sludge can be peproduced in controlled field tests 7. Daimler benz M102E and ford PV-2 (VE) tests have been developed to overcome problem by higher oil quality 8. The M102E and PV-2 respond in a similar way to increased dispersancy 9. High dispersant ocp viscosity modifiers appear to have unique adbantage in both tests

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