• Journal of the Korean Society for Precision Engineering
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• v.27 no.12
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• pp.113-118
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• 2010

For a present study, woven type carbon fibers were surface-modified by oxygen plasma to improve adhesive strength between carbon fibers and epoxy. The change of hydrophilic properties by the plasma modification was investigated through the contact angle measurement and the calculation of surface energy of carbon fiber due to the oxygen plasma modification. FESEM and XPS analyses were performed to study the chemical and physical changes on the surface of carbon fibers due to the oxygen plasma modification. Pin-on-disk wear tests were conducted under dry condition using unmodified and plasma-modified carbon/epoxy composites to investigate the effect of plasma modification on the wear behavior of woven type carbon/epoxy composites. The results showed that the friction coefficient and the wear rate of plasma-modified carbon/epoxy composites were lower than those of unmodified carbon/epoxy composites, respectively. XPS analysis showed that new functional group of a carbonyl type was created on the carbon fibers by the $O_2$ plasma treatment, which enhanced adhesive strength between carbon fibers and epoxy, leading to improve wear properties

• Interaction and multiscale mechanics
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• v.2 no.1
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• pp.31-44
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• 2009

While the classical theory of Griffith is the foundation of modern understanding of brittle fracture, it has a number of significant shortcomings: Griffith theory does not predict crack initiation and path and it suffers from the presence of unphysical stress singularities. In 1998, Francfort and Marigo presented an energy functional minimization method, where the crack (or its absence) as well as its path are part of the problem's solution. The energy functionals act on spaces of functions of bounded variations, where the cracks are related to the discontinuity sets of such functions. The new model presented here uses modified energy functionals to account for molecular interactions in the vicinity of crack tips, resulting in Barenblatt cohesive forces, such that the model becomes free of stress singularities. This is done in a physically consistent way using recently published concepts of Sinclair. Here, for the consistency of the model, it becomes necessary to allow for crack reversibility and to consider local minimizers of the energy functionals. The latter is achieved by introducing different time scales. The model is solved in its global as well as in its local version for a simple one-dimensional example, showing that local minimization is necessary to yield a physically reasonable result.

• Journal of the Korean Chemical Society
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• v.57 no.1
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• pp.104-108
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• 2013

The adsorption characteristics of Cd(II) and Pb(II) in aqueous solution using granular activated carbon (GAC), activated carbon fiber (ACF), modified ACF (NaACF), and a mixture of GAC and NaACF (GAC/NaACF) have been studied. The surface properties, such as morphology, surface functional groups, and composition of various adsorbents were determined using X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) measurements. The specific surface area, total pore volume, and pore size distribution were investigated using nitrogen adsorption, Brunauer-Emmett-Teller (BET), and Barrett-Joyner-Halenda (BJH) methods. In this study, NaACF showed a high adsorption capacity and rate for heavy metal ions due to the improvement of its ion-exchange capabilities by additional oxygen functional groups. Moreover, the GAC and NaACF mixture was used as an adsorbent to determine the adsorbent-adsorbate interaction in the presence of two competitive adsorbents.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.12
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• pp.184-190
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• 2009

Tri-acetyl-cellulose(TAC) film surface was modified by atmospheric-pressure plasma technique to obtain the hydrophilic functional groups and improve the contact angle. TAC film was modified with N2 plasma ionized in dielectric barrier discharge(DBD) reactor under atmospheric pressure. We measured the change of the contact angle and the surface energy with respect to the plasma treatment conditions such as plasma treatment power, discharge gap and Ｎ2 gas flow rate. As the plasma treatment speed of 100[mm/sec], the plasma treatment power of 1.5[kW], discharge gap 2[mm] and the $N_2$ gas flow rate 140[LPM], the best contact angle and the highest surface energy were obtained. The degree of hydrophilization depended strongly on the plasma-treating time and discharge power.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.35-35
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• 2011

Phase change material(PCM) has thermal energy storage and been attracted attention. Latent heat of the organic PCM can keep maintaining temperature when the change of outside energy conditions influence to PCM. Thus, many researchers have interested to thermal energy storage ability and investigated to applications such as thermal storage of solar energy, bioclimatic building, icebank, medical application, clothing industry and so on. Among the many applications, investigation of the PCM in clothing industry is also important because the people has interest functional factor called health-care in the clothing. In addition, PCM can give them mild environment condition such suitable temperature control or humidity. To fabrics, the PCM has various methods such as microcapsule, padding and modified cross-section formation(Sheath/core). Sheath core PCM fabric has a better benefit of durability than other method. However, PCM sheath/core spinning is difficult. In addition, dyeing property is important to use clothing industry due to visual images. In this study, we investigated dyeing properties of Nylon/PCM sheath/core fabrics. Especially, we observed the relation between dyeing property and PCM including ratio. Various temperature and pH conditions were also studied to optimize dyeing properties as acid dye.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.827-835
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• 2000

Adsorption characteristics of uranium on activated carbon whose surface is modified with $HNO_3$ and/or NaOH were investigated. Na-OAC, which was the activated carbon treated with both $HNO_3$ and NaOH. showed higher adsorption capacity than OAC, which was treated with $HNO_3$, as well as Na-AC, which was treated with only NaOH. This can be explained based on the surface functional groups increased by surface modification of activated carbon and the change of solution pH as adsorption proceeds. From these experimental results, it is thought that the pH of uranium solution and surface functional groups on the activated carbon surface are the governing factors in the uranium adsorption system.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.204-204
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• 1999

The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

• Advances in nano research
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• v.8 no.3
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• pp.191-202
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• 2020

The article brings the study of nonlocal, surface and the couple stress together to apparent the frequency retaliation of FG nanobeams (Functionally graded). For the examination of frequency retaliation, the article considers the accurate spot of neutral axis. This article aims to enhance the coherence of proposed model to accurately encapsulate the significant effects of the nonlocal stress field, size effects together with material length scale parameters. These considered parameters are assimilated through what are referred to as modified couple stress as well as nonlocal elasticity theories, which encompasses the stiffness-hardening and softening influence on the nanobeams frequency characteristics. Power-law distribution is followed by the functional gradation of the material across the beam width in the considered structure of the article. Following the well-known Hamilton's principle, fundamental basic equations alongside their correlated boundary conditions are solved analytically. Validation of the study is also done with published result. Distinct parameters (such as surface energy, slenderness ratio, as nonlocal material length scale and power-law exponent) influence is depicted graphically following the boundary conditions on non-dimensional FG nanobeams frequency.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.108-108
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• 2011

Organometallic complexes containing unpaired spins, such as metalloporphyrin or metallophthalocyanine, have extensively studied with increasing interests of their promising model systems in spintronic applications. Additionally, the use of these complexes as an acceptor molecule in chemical sensors has recently received great attentions. In this presentation, we have investigated adsorption of nitric oxide (NO) molecules at Co-porphyrin molecules on Au(111) surfaces with scanning tunneling microscopy and spectroscopy at low temperature. At the location of Co atom in Co-porphyrin molecules, we could observe a Kondo resonance state near Fermi energy in density of states (DOS) before exposing NO molecules and the Kondo resonance state was disappeared after NO exposing because the electronic spin structure of Co-porphyrin were modified by forming a cobalt-NO bonding. Furthermore, we could locally control the chemical reaction of NO dissociations from NO-CoTPP by electron injections via STM probe. After dissociation of NO molecules, the Kondo resonance state was recovered in density of state. With a help of density functional theory (DFT) calculations, we could understand that the modified electronic structures for NO-Co-porphyrin could be occurred by metal-ligand hybridization and the dissociation mechanisms of NO can be explained in terms of the resonant tunneling process via molecular orbitals.

• Journal of Electrochemical Science and Technology
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• v.8 no.2
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• pp.155-161
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• 2017

Carbon felts were prepared under various thermal conditions to improve the electrochemical properties of vanadium redox flow batteries. The number of C-O and/or C-OH functional groups on the surface of the electrodes treated under airless conditions was much larger than that of the untreated and partially oxygen-treated electrodes. The carbon felt treated under airless conditions had the lowest surface area. The overall kinetic properties of the redox reaction were greatly improved for the carbon felt treated under airless conditions; i.e., the reversibility of the anodic and cathodic reactions associated with the $VO_2{^+}/VO^{2+}$ couple became more reversible. Single-cell tests indicated that the carbon felt exhibited an excellent discharge capacity of $3.1Ah{\cdot}g^{-1}$ at $40mA{\cdot}cm^{-2}$, and the corresponding Coulombic, voltage, and energy efficiencies were 89.5%, 91.8%, and 82.2%, respectively.