• Title/Summary/Keyword: modified electrodes

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The Electrocatalytic Reduction of Molecular Oxygen with Clay Modified Electrodes (점토광물을 이용한 산소환원의 전기화학적 촉매성에 관한 연구)

  • Oh Sung-Hun;Hwang Jin-Yeon;Shim Yoon-Bo;Lee Hyomin;Yoon Jihae
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.1-9
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    • 2005
  • The electrocatalytic reduction of O₂ was investigated with methyl viologen and methylene blue incorporated clay-modified electrodes. Clay suspensions were prepared with Na-montmorillonite, Ca-montmorillonite, and kaolinite. The methyl viologen-clay modified electrodes were made by coating clay suspensions adsorbing methyl viologen on a glassy carbon electrode. Cyclic voltammetry were performed in aqueous media to investigate the electrocatalytic property of the modified electrode in reducing O₂. A Na-montmorillonite modified electrode showed the greatest adsorption capacity for methyl viologen. The modified electrode made of Na-montmorillonite suspension of 0.87 g/10 mL and a 2.5 mM of methyl viologen solution showed the most effective electrocatalytic property, where the catalytic reduction potential was shifted by 242.6 mV toward the positive potential. The electrocatalytic ability was more significant in acidic (pH=3.7) and alkaline (pH=12.7) media than the neutral pH range (6.3∼8.3). The methyl viologen-Na-montmorillonite modified electrode had the good reproducibility and maintain the electrocatalytic property over 20 times reuse.

Organic Thin-Film Transistors with Screen Printed Silver Source/Drain Electrodes

  • Kim, Sam-Soo;Kim, Min-Soo;Choi, Gyu-Seok;Kim, Heon-Gon;Kim, Yong-Bae;Lee, Dong-Gu;Roh, Jae-Seong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1305-1307
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    • 2007
  • We show that the electrical properties of organic thinfilm transistors(OTFTs) can be enhanced by controlling the morphology of interface between screen printed electrodes and gate dielectrics. Modified surface of the insulator layer($SiO_2$) affect on the interface energy of electrode on $SiO_2$ layer. Contact angle measurement and FT-IR spectrum shows that the interface is properly modified. OTFTs device with high efficiency has been realized through modification of interface layer.

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Modified Ramp Reset Waveform for High Contrast Ratio in AC PDPs

  • Kim, Jae-Sung;Yang, Jin-Ho;Ha, Chang-Hoon;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.199-202
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    • 2002
  • In general, the background light produced during the reset period deteriorates the dark room contrast ratio in AC PDP. In this paper, we propose a modified ramp reset pulse that can reduce the background light to imperceptible level. In the new reset waveform, the discharges between the scan and sustain electrodes are minimized by applying a positive bias voltage to the sustain electrode and only the weak discharges between the scan and address electrodes occur during the reset period. We adopted a MgO coated phosphor layer to get the same level of voltage margin in the new reset pulse scheme compared to that of the conventional ramp reset pulse one. As a result, the voltage margin is maintained at the same level and the dark room contrast ratio is improved dramatically.

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Electrocatalytic Reduction of Dioxygen at Schiff base Co(II) Complexes supported Glassy Carbon Electrode in various pH Solution

  • Park, Kyoung-Hee;Rim, Chae-Pyeong;Chjo, Ki-Hyung;Jeon, Seungwon;Choi, Yong-Kook
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.617-622
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    • 1995
  • Electrocatalytic reduction of dioxygen has been investigated by cyclic voltammetry at glassy carbon electrode modified with new Co(II)-Schiff base complexes in aqueous solutions of various pH. The reduction potentials of dioxygen at chemically adsorbed electrodes show the dependence of pH between pH 4 and 14. The catalytic effect is large and the reaction occurs via two or four electron transfer in various pH solution.

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Grounding Resistance and Current Characteristics of the Planar Earth Structure using Multiple Discharge Paths (다중방전 경로를 이용한 편상접지체의 접지저항 및 전류특성)

  • Kim, Young-Sun;Kim, Dong-Min;Lee, Ki-Sik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1564-1570
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    • 2016
  • This study proposes a newly modified form of existing ground electrodes in order to secure trust of grounding system for large current caused by a stroke of lightning. Proposed planar earth structure has a several needle electrodes around a circular rod and 4 plane electrodes in all directions. The plane electrodes are fused with the insulator on the linear rod, so that they're electrically isolated. The concept is to increase the discharge amount of earth structure using multiple discharge paths like needle and plane electrodes. To check the discharge efficiency of the suggested scheme, the discharge currents are compared with typically used two kinds of ground rods. To ensure accuracy in the measurement of the discharge current, the same material was used for the comparison model. Also, the ground resistance are simulated by CDEGS commercial software and the results are compared with measured data. Based on this kind of experimental study, the suggested ground rod can be used when designing a ground system or when constructing a ground system at the site.

The Variations of Grounding Resistance of the Vertical Electrodes by Soil Models (대지구조 모델에 따른 봉형 접지전극의 접지저항값 변화)

  • Shim, Keon-Bo;Kim, Won-Bae;Seo, Gil-Mo;Cho, Geum-Bae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.9
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    • pp.57-63
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    • 2012
  • The basic purpose of grounding is for human safety and normal operation of system related to electrical shock hazard by faults of electrical equipments. A grounding electrode is defined as a conducting element that connects electrical systems and/or equipment to the earth. The lowest possible resistance connection to the earth is sought from the grounding electrode. The grounding electrode is the foundation of the electrical safety system. The resistance to ground of vertical electrodes buried in the two deference soil structures has been analyzed for a length of electrodes and soil parameters. The equation of ground resistance of vertical electrodes are Tagg's equation for uniform soil models, and modified equation of Dwight equation for two-layer soil model. In this paper, compared with results of two equations are calculated values of vertical electrode in uniform and two-layer soil models.

DSSCs Efficiencies of Photo Electrode Thickness and Modified Photo Electrode Surface Area (광전극 두께와 표면적 변형에 따른 DSSC의 효율 특성)

  • Kwon, Sung-Yeol;Yang, Wook;Zhou, Ze-Yuan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.2
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    • pp.115-120
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    • 2014
  • Photo electrode is an important component for DSSC. DSSCs electrical characteristics and efficiencies fabricated with different $TiO_2$ photo electrodes thickness and modified phoro electrode surface area were studied. $11{\mu}m$ $TiO_2$ photo electrode shows a 4.956% efficiency. The highest short circuit current density was a $9.949mA/cm^2$. Efficiencies and short circuit current density increased as tape casting thickness decreased. Modified surface area of the photo electrode by needle stamp processing were studied. 200 times needle stamp processing on photo electrodes shows a highest 5.168% efficiency. Also the short circuit current density was a $10.261mA/cm^2$.