• Title/Summary/Keyword: modified electrodes

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Micro-electromechanical Model of a Piezoelectric fiber/Piezopolymer matrix composite Actuator (압전섬유/압전지지 복합재 작동기의 전기-기계적 마이크로모델)

  • Kim, Cheol;Koo, Kun-Hyung
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.372-377
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    • 2001
  • Piezoelectric Fiber Composites with Interdigitated Electrodes (PFCIDE) were previously introduced as an alternative to monolithic wafers with conventional electrodes for applications of structural actuation. This paper is an investigation into the performance improvement of piezoelectric fiber composite actuators by changing the matrix material. This paper presents a modified micro-electromechanical model of a piezoelectric fiber/piezopolymer matrix composite actuator with interdigitated electrodes (PFPMIDE). Various concepts from different backgrounds including three-dimensional linear elastic and dielectric theories have been incorporated into the present linear piezoelectric model. The rule of mixture and the modified method to calculate the effective properties of fiber composites are extended to apply to the PFPMIDE model. The new model is validated comparing with available experimental data and other analytical results.

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Alizarin Red S modified electrochemical sensors for the detection of aluminum ion

  • Chang, Seung-Cheol
    • Journal of Sensor Science and Technology
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    • v.19 no.6
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    • pp.421-427
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    • 2010
  • Alizarin Red S modified screen printed carbon electrodes were developed for the electrochemical detection of aluminum ion. The electrodes developed use screen-printed carbon electrodes(SPCEs) coupled with chemical modification with an organic chelator, Alizarin Red S(ARS), for aluminum ion detection in aqueous solution. For sensor fabrication ARS was directly immobilized on the surface of SPCEs using PVA-SbQ(The poly(vinyl alcohol) bearing stryrylpyridinium groups). Aluminum concentrations were indirectly estimated by amperometric determination of the non-complexed ARS immobilized on the electrodes, after its complexation with aluminum. The sensitivity of the sensor developed was $3.8\;nA{\mu}M^{-1}cm^{-2}$ and the detection limit for aluminum was $25\;{\mu}M$.

A Study on the Measurement of Heart Rate Variability using the Modified Laplacian Electrodes (수정된 라플라시안 센서를 이용한 심박변이도 측정에 관한 연구)

  • Lee, Chung-Keun;Shin, Hang-Sik;Kim, Hong-Rae;Lee, Jeong-Whan;Kim, Yong-Jun;Lee, Myoung-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.5
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    • pp.1050-1056
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    • 2009
  • Heart Rate Variability(HRV) is a parameter that represents monitoring variability of time intervals between R-peak in electrocardiography. HRV serves to various applications, such as indices of autonomic functions, prediction of cardiac sudden death, assessment of stress and emotional, etc. However, as measuring R-peak in ECG needs at least 3-electrodes, and it is inconvenient for end users. In this paper, we suggested the modified laplacian electrodes for measuring HRV at one-point, which are producted by MEMS fabrication and have the two circular electrodes on the pad. For optimal position and direction, we performed an experiment that compared with pearson correlation coefficient and the amplitude of signals, between standard lead II and proposed electrodes. We analyzed the HRV parameters, such as standard deviation of the NN interval(SDNN), high frequency(HF), low frequency(LF), LF/HF ratio. The result showed that the average correlation coefficient and amplitude are 0.967 and 0.685 mVpp at the position 2. The coeffiecient correlation between the standard HRV and proposed electrode-HRV is 0.999

Concurrent Electrocatalysis and Sensing of Hydrazine and Sulfite and Nitrite Ions using Electrodeposited Gold Nanostructure-Modified Electrode

  • Seo, Yeji;Manivannan, Shanmugam;Kang, Inhak;Shin, Woo-Seung;Kim, Kyuwon
    • Journal of Electrochemical Science and Technology
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    • v.8 no.1
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    • pp.25-34
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    • 2017
  • Concurrent electrocatalysis and sensing of hydrazine, sulfite ions, and nitrite ions in a mixture were studied using electrodes modified by electrodeposited Au nanostructures (NSs). The ${\beta}$-cyclodextrin-mixed silicate sol-gel composite was drop-casted on the electrode surface and nucleation guided by ${\beta}$-cyclodextrin occurred, followed by the electrodeposition of Au NSs. The additive, ${\beta}$-cyclodextrin, played an evident role as a structure-directing agent; thus, small raspberry-like Au NSs were obtained. The modified electrodes were characterized by surface characterization techniques and electrochemical methods. The Au NSs-modified electrodes effciently electrocatalyzed the oxidation of toxic molecules such as hydrazine and sulfite and nitrite ions even in the absence of any other electron transfer mediator or enzyme immobilization. Well-resolved oxidation peaks along with decreased overpotentials were noticed during the electrooxidation process. The fabricated Au nanostructured electrode clearly distinguished the electrooxidation peaks of each of the three analytes from their mixture.

Physioelectrochemical Investigation of Electrocatalytic Oxidation of Saccharose on Conductive Polymer Modified Graphite Electrode

  • Naeemy, A.;Ehsani, A.;Jafarian, M.;Moradi, M.
    • Journal of Electrochemical Science and Technology
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    • v.6 no.3
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    • pp.88-94
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    • 2015
  • In this study we investigated the electrocatalytic oxidation of saccharose on conductive polymer- Nickel oxide modified graphite electrodes based on the ability of anionic surfactants to form micelles in aqueous media. This NiO modified electrode showed higher electrocatalytic activity than Ni rode electrode in electrocatalytic oxidation of saccharose. The anodic peak currents show linear dependency with the square root of scan rate. This behavior is the characteristic of a diffusion controlled process. Under the CA regime the reaction followed a Cottrellian behavior and the diffusion coefficient of saccharose was found in agreement with the values obtained from CV measurements.

Effects of Aging on Electrocatalytic Activities of Pt and Pd Nanoparticles

  • Dutta, Gorachand;Yang, Haesik
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.27-32
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    • 2016
  • Although the time dependences of the electrocatalytic activities of Pt and Pd nanoparticles during electrochemical operations have been widely studied, the time dependences under nonpolarized conditions have never been investigated in depth. This study reports the changes in the electrocatalytic activities of Pt and Pd nanoparticles with aging in air and in solution. Pt (or Pd) nanoparticle-modified electrodes are obtained by adsorbing citrate-stabilized Pt (or Pd) nanoparticles on amine-modified indium-tin oxide (ITO) electrodes, or by electrodeposition of Pt (or Pd) nanoparticles on ITO electrodes. The electrocatalytic activities of freshly prepared Pt and Pd nanoparticles in the oxygen reduction reaction slowly decrease with aging. The electrocatalytic activities decrease more slowly in solution than in air. An increase in surface contamination may cause electrocatalytic deactivation during aging. The electrocatalytic activities of long-aged Pt (or Pd) nanoparticles are significantly enhanced and recovered by NaBH4 treatment.

Study on Discharge Characteristics in AC Plasma Display Panel with Open Dielectric Structure (개방형 유전체 구조를 갖는 교류형 플라즈마 디스플레이의 방전 특성 연구)

  • Cho, Byung-Gwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.906-909
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    • 2012
  • The address discharge characteristics of a open dielectric structure compared with the conventional panel structure are investigated by measuring the discharge firing voltage. The open dielectric structure could easily produce the discharge between the scan and the sustain electrodes by erasing the dielectric layer between two electrodes. Due to the changes in the discharge firing characteristics of the open dielectric structure between the two sustain electrodes, the conventional reset waveform including the address waveform needs to be modified. The modified driving waveform suitable for the open dielectric structure is proposed and examined in AC PDP.

Implementation of Wearable Heart Activity Monitoring System having Modified Bipolar Electrode and Correlation Analysis with Clinical Electrocardiograph(ECG) (수정된 바이폴라 전극을 갖는 착용형 심장활동 모니터링 시스템 구현 및 임상 심전도와의 상관관계 분석)

  • Lee, Kang-Hwi;Lee, Jeong-Whan;Lee, Young-Jae;Kim, Kyeong-Seop;Yang, Heui-Koung;Shin, Kun-Su;Lee, Myoung-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.6
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    • pp.1102-1108
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    • 2008
  • Wearable physiological signal monitoring systems are regarded as an important sensing unit platforms in ubiquitous/mobile healthcare application. In this paper, we suggested the modified bipolar electrodes implemented on the portable heart activity monitoring system, which minimized the distance of electrodes formed on a attachable pad. The proposed electrode configuration is useful in mobile measurement environments, but has a disadvantage of reduced amplitude of the heart action potential. In order to overcome the shortcoming of the suggested electrode configuration, we implemented the amplifying circuit to increase the signal-gain and decrease the artifacts. For evaluations, we analyzed the specificity of measured cardiography using the proposed electrodes through the comparing of heart activity monitoring system with standard clinical ECG(lead2) by pearson correlation coefficients. The result showed that the average correlation coefficient is $0.903{\pm}0.036,\;0.873{\pm}0.072$ at V3, V4 chest lead position, respectively. Thus, the modified bipolar electrode is quite suitable to monitor the electrical activity of the heart in the situation of the mobile environment, and could be considered having high similarity with standard clinical ECG.

Glucose Oxidation on Gold-modified Copper Electrode

  • Lim, Ji-Eun;Ahn, Sang Hyun;Pyo, Sung Gyu;Son, Hyungbin;Jang, Jong Hyun;Kim, Soo-Kil
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2685-2690
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    • 2013
  • The activities of Au-modified Cu electrodes toward glucose oxidation are evaluated according to their fabrication conditions and physico-chemical properties. The Au-modified Cu electrodes are fabricated by the galvanic displacement of Au on a Cu substrate and the characteristics of the Au particles are controlled by adjusting the displacement time. From the glucose oxidation tests, it is found that the Au modified Cu has superior activity to the pure Au or Cu film, which is evidenced by the negative shift in the oxidation potential and enhanced current density during the electrochemical oxidation. Though the activity of the Au nanoparticles is a contributing factor, the enhanced activity of the Au-modified Cu electrode is due to the increased oxidation number of Cu through the electron transfer from Cu to more electronegative Au. The depletion of electron in Cu facilitates the oxidation of glucose. The stability of the Au-modified Cu electrode was also studied by chronoamperometry.