• Title/Summary/Keyword: modified base materials

Search Result 85, Processing Time 0.025 seconds

Effect of Bi4Zr3O12 on the properties of (KxNa1-x)NbO3 based ceramics

  • Mgbemere, Henry. E.;Akano, Theddeus T.;Schneider, Gerold. A.
    • Advances in materials Research
    • /
    • v.5 no.2
    • /
    • pp.93-105
    • /
    • 2016
  • KNN-based ceramics modified with small amounts of $Bi_4Zr_3O_{12}$ (BiZ) has been synthesized using high-throughput experimentation (HTE). The results from X-ray diffraction show that for samples with base composition $(K_{0.5}Na_{0.5})NbO_3$ (KNN), the phase present changes from orthorhombic to pseudo-cubic with more than 0.2 mol% BiZ addition; for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.9}Ta_{0.1})O_3$ (KNNLT), the phase present changes from a mixture of orthorhombic and tetragonal symmetry to pseudo-cubic with more than 0.4 mol % while for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.86}Ta_{0.1}Sb_{0.04})O_3$ (KNNLST), the phase present is tetragonal with <0.3 mol% BiZ addition and transforms to pseudo-cubic with more dopant addition. The microstructures of the samples show that addition of BiZ decreases the average grain size and increases the volume of pores at the grain boundaries. The values of dielectric constant for KNN and KNNLT compositions increase slightly with BiZ addition while that for KNNLST decreases gradually with BiZ addition. The dielectric loss values are between 0.02 and 0.04 for KNNLT and KNNLST compositions while they are ~ 0.05 for KNN samples. The resistivity values increases with BiZ addition and values in the range of $10^{10}{\Omega}cm$ and $10^{12}{\Omega}cm$ are obtained. The piezoelectric charge coefficient ($d{^*}_{33}$) is highest for KNNLST samples and decreases gradually from ~400 pm/V to ~100 pm/V with BiZ addition.

Effectiveness of biphasic calcium phosphate block bone substitutes processed using a modified extrusion method in rabbit calvarial defects

  • Lim, Hyun-Chang;Song, Kyung-Ho;You, Hoon;Lee, Jung-Seok;Jung, Ui-Won;Kim, Suk-Young;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
    • /
    • v.45 no.2
    • /
    • pp.46-55
    • /
    • 2015
  • Purpose: This study evaluated the mechanical and structural properties of biphasic calcium phosphate (BCP) blocks processed using a modified extrusion method, and assessed their in vivo effectiveness using a rabbit calvarial defect model. Methods: BCP blocks with three distinct ratios of hydroxyapatite (HA):tricalcium phosphate (TCP) were produced using a modified extrusion method:HA8 (8%:92%), HA48 (48%:52%), and HA80 (80%:20%). The blocks were examined using scanning electron microscopy, X-ray diffractometry, and a universal test machine. Four circular defects 8 mm in diameter were made in 12 rabbits. One defect in each animal served as a control, and the other three defects received the BCP blocks. The rabbits were sacrificed at either two weeks (n=6) or eight weeks (n=6) postoperatively. Results: The pore size, porosity, and compressive strength of the three types of bone block were $140-170{\mu}m$, >70%, and 4-9 MPa, respectively. Histologic and histomorphometric observations revealed that the augmented space was well maintained, but limited bone formation was observed around the defect base and defect margins. No significant differences were found in the amount of new bone formation, graft material resorption, or bone infiltration among the three types of BCP block at either of the postoperative healing points. Conclusions: Block bone substitutes with three distinct compositions (i.e., HA:TCP ratios) processed by a modified extrusion method exhibited limited osteoconductive potency, but excellent space-maintaining capability. Further investigations are required to improve the processing method.

Strengthening Mechanism of Hybrid Short Fiber/Particle Reinforced Metal Matrix Composites (섬유/입자 혼합 금속복합재료의 강화기구 해석)

  • 정성욱;이종해;정창규;송정일;한경섭
    • Composites Research
    • /
    • v.13 no.1
    • /
    • pp.50-60
    • /
    • 2000
  • This paper presents an analytical method considering tensile strength enhancement in hybrid $Al_2O_3$ fiber/particle/aluminum composites(MMCs). The tensile strength and elastic modulus of the hybrid MMCs are even 20% higher than those of the fiber reinforced MMCs with same volume fraction of reinforcements. This phenomenon is explained by the cluster model which is newly proposed in this research, and the strengthening mechanisms by a cluster is analyzed using simple modified rule of mixtures. From the analysis, it is observed that cluster structure in hybrid MMCs increase the fiber efficiency factor for the tensile strength and the orientation factor for the elastic modulus. The present theory is then compared with experimental results which was performed using squeeze infiltrated hybrid MMCs made of hybrid $Al_2O_3$ short fiber/particle preform and AC8A alloy as base metal, and the agreement is found to be satisfactory.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 1998.11c
    • /
    • pp.1065-1068
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mate(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2/g$ when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 1998.11b
    • /
    • pp.717-720
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mat(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2/g$ when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 1998.11a
    • /
    • pp.397-400
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mat(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2$/g when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF

Improvement of Insulation Performance of Vehicle Rubber Hoses (자동차용 고무호스의 진동 절연성능 향상에 관한 연구)

  • Jung, Heon-Seob;Min, Byung-Kwon;Lee, Seong-Hoon;Woo, Hee-Soo;Park, Hyun-Ho
    • Transactions of the Korean Society for Noise and Vibration Engineering
    • /
    • v.22 no.9
    • /
    • pp.837-844
    • /
    • 2012
  • We considered an approach in terms of materials for improvement of insulation performance of vehicle rubber hoses. Ethylene propylene rubber(EPDM) for heater hoses in cooling system and acrylic rubber(AR) for intercooler hose in intake system were chosen for mixing for the vibration and noise performance. We modified EPDM and AR through changing compound of base polymer, reinforcement fillers and additives. Dynamic mechanical analysis(DMA) was used to measure viscoelastic properties such as shear modulus and loss factor($tan{\delta}$). Vehicle acceleration test was also conducted to observe indoor changes in insulation performance of hoses.

Current aspects and prospects of glass ionomer cements for clinical dentistry

  • Park, Eun Young;Kang, Sohee
    • Journal of Yeungnam Medical Science
    • /
    • v.37 no.3
    • /
    • pp.169-178
    • /
    • 2020
  • Glass ionomer cement (GIC) is a tailor-made material that is used as a filling material in dentistry. GIC is cured by an acid-base reaction consisting of a glass filler and ionic polymers. When the glass filler and ionic polymers are mixed, ionic bonds of the material itself are formed. In addition, the extra polymer anion reacts with calcium in enamel or dentin to increase adhesion to the tooth tissue. GICs are widely used as adhesives for artificial crowns or orthodontic brackets, and are also used as tooth repair material, cavity liner, and filling materials. In this review, the current status of GIC research and development and its prospects for the future have been discussed in detail.

Electrical Properties of Silicone Rubber Filled with Surface Treated Alumina Trihydrate

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
    • /
    • v.7 no.3
    • /
    • pp.134-140
    • /
    • 2006
  • The effect of surface treatment of fillers on the mechanical, electrical properties, and tracking performance of silicone rubber insulators have been investigated. For base polymer, $\alpha,\;\omega$) vinyl poly(dimethyl-methylphenyl) siloxane(VPMPS) containing dimethyl siloxane and methylphenyl siloxane was prepared by the equilibrium polymerization. High voltage silicone rubber composites(HVSRC) were prepared from VPMPS, nano-silica, and alumina trihydrate (ATH) modified by various coupling agents. Bound rubber of uncured silicone rubber, cross-linking density of the vulcanizate as well as the mechanical, electrical properties, and tracking performance were measured.

A study on the MC Carbide Morphologies Directionally Solidified Superalloys (일방향응고 초내열합금에서 MC 탄화물 형상에 관한 연구)

  • Kim, Seung-Eon;Jo, Chang-Yong;Kim, Hak-Min
    • 한국기계연구소 소보
    • /
    • s.20
    • /
    • pp.57-63
    • /
    • 1990
  • The morphologies of MC carbides (M stands for metal) and creep-rupture properties in directionally solidified Rene 80 having standard and Hf-modified chemistries were studied. It was found that Hf depressed the melting point, $\gamma$- $\gamma$’ eutectic temperature and $\gamma$’ solvus of nickel-base superalloy Rene 80, but did not depress MC carbide forming temperature. The morphologies of MC carbides depended upon solidification sequence, which led to blocky type in the early stage and script type in the late stage of solidification. Creep failure occurs through the crack initiation at the transverse components of longitudinal grain boundaries or interdendritic carbides in directionally solidified superalloys. It could be concluded MC carbide morphologies played an important role in creep properties of DS superalloys, that is, Hf additions increased the creep ductilities and lives of Rene 80.

  • PDF