• Title/Summary/Keyword: mode behavior

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Determination of radiolysis products in Tri-Octyl Amine by high performance liquid chromatography-mass spectrometer (HPLC-MS에 의한 Tri-Octyl Amine(TOA)의 방사선 분해산물 정량)

  • Yang, Han-Beom;Lee, Eil-Hee;Moon, Hyung-Sil
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.201-205
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    • 2005
  • Tri-octyl amine (TOA) is used in solvent extraction process for radioactive waste. This compound may be degraded to di-octyl amine (DOA), mono-octyl amine (MOA) by radioactive materials. Amount of TOA, DOA and MOA in TOA must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for TOA, DOA and MOA are studied with Phenomenex LUNA-$C_{18}$ ($4.6mm{\times}25cm$) analytical column and $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) eluent by liquid chromatography. Optimum condition for these compounds is $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) = 85 : 15 ratio. TOA, DOA and MOA compounds is well separated within 20 minute. Dynamic range is $30{\sim}160{\mu}g/mL$ for TOA, $5{\sim}100{\mu}g/mL$ for DOA and $0.1{\sim}5{\mu}g/mL$ for MOA, respectively. The detection limit are $0.1{\mu}g/mL$ for TOA, $1{\mu}g/mL$ for DOA (in SCAN mode) and $0.1{\mu}g/mL$ for MOA (in SIM mode) in this system with $20{\mu}L$ sample loop.

Improving Stability and Characteristic of Circuit and Structure with the Ceramic Process Variable of Dualband Antenna Switch Module (Dual band Antenna Switch Module의 LTCC 공정변수에 따른 안정성 및 특성 개선에 관한 연구)

  • Lee Joong-Keun;Yoo Joshua;Yoo Myung-Jae;Lee Woo-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.105-109
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    • 2005
  • A compact antenna switch module for GSM/DCS dual band applications based on multilayer low temperature co-fired ceramic (LTCC) substrate is presented. Its size is $4.5{\times}3.2{\times}0.8 mm^3$ and insertion loss is lower than 1.0 dB at Rx mode and 1.2 dB at Tx mode. To verify the stability of the developed module to the process window, each block that is diplexer, LPF's and bias circuit is measured by probing method in the variation with the thickness of ceramic layer and the correlation between each block is quantified by calculating the VSWR In the mean while, two types of bias circuits -lumped and distributed - are compared. The measurement of each block and the calculation of VSWR give good information on the behavior of full module. The reaction of diplexer to the thickness is similar to those of LPF's and bias circuit, which means good relative matching and low value of VSWR, so total insertion loss is maintained in quite wide range of the thickness of ceramic layer at both band. And lumped type bias circuit has smaller insertion itself and better correspondence with other circuit than distributed stripline structure. Evaluated ceramic module adopting lumped type bias circuit has low insertion loss and wider stability region of thickness over than 6um and this can be suitable for the mass production. Stability characterization by probing method can be applied widely to the development of ceramic modules with embedded passives in them.

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Infrared Spectroscopic Evidences for the Superconductivity of $La_2CuO_4$-related Compounds: A Superconductivity Probe

  • Park, Jeong Cheol;Jo, Seon Woog;Jeong, Jong Hak;Jeong, Gi Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1041-1043
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    • 2000
  • We present the effects of temperature (between 10 K and 298 K) and of hole concentration on the frequency and intensity of characteristic phonons in polycrystalline $La_2CuO_4-related$ compounds using FT-IR spectros-copy. The influences of the concentration of carrier doped on the phonon modes are prominent in the IR spectra of $La_2CuO_4-related$ compounds. For $La_2-xSrxCuO_4({\chi}=$ 0.00, 0.03, 0.07, 0.10, and 0.15) and electrochemically (or chemically) oxidized $La_2CuO_4$, the intensities of the transverse oxygen mode around 680cm $-^1$ which cor-responds mainly to Cu-O(1) stretching vibration in the basal plane of CuO6 octahedron, are decreased and dis-appeared depending on the Sr-substitution rate and the amount of excess oxygen, while the longitudinal oxygen mode around 510 cm $-^1$ corresponding to the Cu-O(2) stretching in the basal plane of CuO6 octahedron are near-ly invariable. In particular, after two cycles of cooling-heating between 10 K and 298 K for these sample, the phonons around 680 cm $-^1$ are blue shif 13-15 cm $-^1$, while the phonons around 510 cm $-^1$ are nearly constant. The introduction of the charge carrier by doping would give rise to the small contraction of CuO6 oc-tahedron as Cu $^3+$ requires a smaller site than Cu $^2+$, which results in the shortening of the Cu-O(1) bond length and Cu-O(2) bond length with the increased La-O(2) bond length. These results in the frequency shift of the characteristic phonons. The IR spectra of $La_2Li0.5Cu0.5O_4$ which exhibits an insulator behavior despite the $Cu^3+$ of nearly 100%, corroborate our IR interpretations. The mode around 710 cm $-^1$ corresponding to Cu-O(1) stretching vibration is still strongly remained even at low temperature (10 K). Thus, we conclude that the con-duction electrons formed within $CuO_2$ planes of $La_2CuO_4-related$ superconductors screen more effectively the transverse oxygen breathing mode around 680 $cm-^1$ depending on the concentration of the doped charge carrier in $La_2CuO_4-related$ compounds, which might use as a superconductivity probe.

Smoke Control Experiment of a Very Deep Underground Station Where Platform Screens Doors are Installed - Analysis on Smoke Control Performance by Fans equipped in Tunnel (스크린도어가 설치된 대심도 지하역사의 제연 실험 - 터널 송풍기에 의한 제연의 효과 분석)

  • Park, Won-Hee;Kim, Chang-Yong;Cho, Youngmin
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.9 no.9
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    • pp.721-736
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    • 2019
  • In this paper, the behavior of the fire smoke due to the operation of the ventilation systems when the fire occurred in the underground station (6 basement floors) and the tunnel at the great depth was measured. Fire smoke was generated by using a smoke generator which realized heat buoyancy effect by using hot air blower. The two locations of the fire were selected on the platform and on the platform of the tunnel located outside the screen door. A ventilation mode is generally used in which smoke is exhausted through a vent hole provided in a platform when a platform fire occurs. The tests were performed by operating the exhaust through the ventilation holes of the tunnel part located at both ends of the platform. The smoke density and the wind speed/velocity were measured at various positions, and the videos were taken to analyze the movement and smoke of the smoke. In both cases for fire inside the platform and in the railway tunnel, due to the ventilation mode operation of the fan for the platform and the exhaust of the fans in the tunnel smoke were well exhausted and the smoke propagation to the area near the smoke zone was suppressed. The smoke-control mode, which is applied to both fans for the platform and fans for in the tunnel at both ends of the platform, can provide a safer evacuation environment to the passengers from the fire smoke when the platform fire or fire train stops.

Simultaneous analysis method of 89Sr and 90Sr in liquid sample using automated separation system (자동핵종분리장치를 이용한 액체시료 중 89Sr, 90Sr 동시분석법 연구)

  • Kim, Heewon;Lee, Yong-Jin;Kim, Sun-Ha;Lee, Jin-Hong;Lim, Jong-Myoung;Kim, Hyuncheol
    • Analytical Science and Technology
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    • v.33 no.6
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    • pp.274-284
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    • 2020
  • This study described the analytical method for simultaneous determination of 89Sr and 90Sr in liquid sample using automated separation system. Radiostrontium in 0.5 kg of liquid sample was concentrated as SrCO3 to reduce the volume of sample, and purified from the sample using Sr-resin 2 mL (BV, Bed volume). The behavior of Sr and interferences such as Ba, Ca and Y were estimated with various flow rate ranging from 1 to 4 mL min-1. The detailed procedure for the purification of Sr on Sr-resin was presented. The purified radiostronitum was measured in Cerenkov mode and then measured in Scintillation mode by mixing scintillation cocktail. The measured value in both modes were used to calculate the activity of 89Sr and 90Sr. The performance tests were carried out the lab-control-sample having various activity ratio of between 89Sr and 90Sr. The recovery of Sr was ranged from 68 to 94 %. The relative bias of 89Sr activity was ranged from -5 to 20 %, and it was ranged from -10 to 10 % for 90Sr.

A Study on Robust Optimal Sensor Placement for Real-time Monitoring of Containment Buildings in Nuclear Power Plants (원전 격납 건물의 실시간 모니터링을 위한 강건한 최적 센서배치 연구)

  • Chanwoo Lee;Youjin Kim;Hyung-jo Jung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.3
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    • pp.155-163
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    • 2023
  • Real-time monitoring technology is critical for ensuring the safety and reliability of nuclear power plant structures. However, the current seismic monitoring system has limited system identification capabilities such as modal parameter estimation. To obtain global behavior data and dynamic characteristics, multiple sensors must be optimally placed. Although several studies on optimal sensor placement have been conducted, they have primarily focused on civil and mechanical structures. Nuclear power plant structures require robust signals, even at low signal-to-noise ratios, and the robustness of each mode must be assessed separately. This is because the mode contributions of nuclear power plant containment buildings are concentrated in low-order modes. Therefore, this study proposes an optimal sensor placement methodology that can evaluate robustness against noise and the effects of each mode. Indicators, such as auto modal assurance criterion (MAC), cross MAC, and mode shape distribution by node were analyzed, and the suitability of the methodology was verified through numerical analysis.

Depending on Mode and Tempo Cues for Musical Emotion Identification in Children With Cochlear Implants (조성 및 템포 단서에 따른 인공와우이식 아동의 음악 정서 지각)

  • Lee, Yoonji
    • Journal of Music and Human Behavior
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    • v.21 no.1
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    • pp.29-47
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    • 2024
  • The purpose of this study was to investigate how children with cochlear implants (CI) perceive emotion in music depending on mode and tempo cues, and to compare them to NH children. Participants in this study included 13 CI children who were implanted with either unilateral or bilateral cochlear implants aged between 7 and 13 years, 36 NH children, and 20 NH adults. The musical stimuli used in this study were piano recordings in either major or minor mode, with tempos of 130 bpm and 56 bpm. A comparison of the emotion perception levels of NH children and NH adults before the experiment showed that there was no significant difference between the two groups. Meanwhile, the way they perceive different emotions from each music condition varies, in that CI children perceived all music conditions except as happy, while NH children perceived music in a major key as happy and music in a minor key as sad. It supports that CI children tend to rely primarily on tempo cues to process and identify emotional information from music, which is contrary to NH children. It is important to note that this study enhanced and specified the understanding of how CI children perceive music emotion and use specific musical elements in the process. These findings indicate baseline data on emotion perception in music in CI children.

A Mechanical Model of the End Anchorage Zone of Prestressed Concrete Members

  • Kang, Won-Ho;You, Young-Min;Oh, Seung-Hyun;Lee, Sang-Woo
    • International Journal of Concrete Structures and Materials
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    • v.18 no.1E
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    • pp.35-41
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    • 2006
  • It is expected that recent development of mechanical models will soon supersede previous empirical methods of detailing. In this study, a mechanical model is proposed to analyze the behavior of the anchorage zone of prestressed concrete members. The main characteristics of the proposed model lies in its rational consideration of material properties such as concrete strength in biaxial stress state and that of local zone reinforced by spirals. The shear friction strength of concrete surrounding a spiral is also considered. The computational results of the proposed model as well as the existing Strut-and-Tie model(STM) and nonlinear finite element analysis are compared with experimental results. The results of the comparison revealed that the proposed model showed better prediction of the failure mode as well as the failure load. Additionally, the proposed model also explained the three-dimensional failure mechanism very well, while other methods based on two-dimensional analysis could not do so well.

Analysing Korean Residential House Tenure Choice by Mixed Logit Panel Model

  • Jeong, Ki-Ho;Lee, Sang-Ho
    • Journal of the Korean Data and Information Science Society
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    • v.19 no.2
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    • pp.559-568
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    • 2008
  • This paper analyzes Korean residential tenure choice for house which is the most important in Korean households' assets. Data used in the analysis is the data of Korean Labor and Income Panel Study for the period from 1998 to 2006 and with 2341 households. In this paper, a household chooses a housing tenure mode, either by renting or by owing house. We use a mixed-logit panel model as an estimation model to take into consideration household's heteroscedasticity of preference in tenure choice. It turns out that the heteroscedasticity is significant in households' tenure choice behavior, implying that Korean housing policy emphasizing supply side should consider the demand side.

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Experimental Study on Seismic Performance Evaluation of Piers in Seohae Grand Bridge (세해대교 PSM교 교각의 내진성능 평가에 관한 실험적 연구)

  • 손혁수
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2000.04a
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    • pp.319-326
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    • 2000
  • The purpose of this study is to evaluate seismic performance of reinforced concrete pier columns in Seohae Ground Bridge. Since the bridge was designed before preparing the seismic design specification the bridge columns of hollow hexagonal section were designed and constructed with insufficient seismic reinforcement details such as longitudinal and transverse reinforcement lap-splices. In order to take the necessary measures to improve its seismic performance experimental study was performed by small-scale test for the bridge columns, From the quasi-static test for small-scale column specimens the lap-splices were not critical for overall behavior of the column if sufficient lap-splice-length was provided. The test results of failure mode effective stiffness ductility and equivalent viscous damping ratio are presented.

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