• Title/Summary/Keyword: mixing mechanism

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Mashup Web of Visual Structure using the Mechanism of GPIS Tracking (GPIS Tracking 메커니즘의 시각구조 Mashup Web)

  • An, Sung-Eun;Kim, Jung-Joong
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.2 no.4
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    • pp.65-71
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    • 2009
  • Web Contents have been evolved from statics, dynamics contents to Mashup service. In recent years, Mashup which can creates new contents by mixing different services is topic on the web service. But, Mashup is only concentrate on making new contents to provide for client. In this paper, we propose the policy of composing services and client-friendly UI.

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Etch Characteristics of (Pb,Sr) TiO3 Thin films using Inductively Coupled Plasma (유도결합 플라즈마를 이용한 PST 박막의 식각 특성)

  • 김관하;김경태;김동표;김창일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.4
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    • pp.286-291
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    • 2003
  • (Pb,Sr)TiO$_3$(PST) thin films have attracted great interest as new dielectric materials of capacitors for Gbit dynamic random access memories. In this study, inductively coupled CF$_4$/Ar plasma was used to etch PST thin films. The maximum etch rate of PST thin films was 740 $\AA$/min at a CF$_4$(20 %)/Ar(80 %) 9as mixing ratio, an RF power of 800 W, a DC bias voltage of -200 V, a total gas flow of 20 sccm, and a chamber pressure of 15 mTorr. To clarify the etching mechanism, the residue on the surface of the etched PST thin films was investigated by X-ray photoelectron spectroscopy. It was found that Pb was mainly removed by physically assisted chemical etching. Sputter etching was effective in the etching of Sr than the chemical reaction of F with Sr, while Ti can almost removed by chemical reaction.

Prediction Modeling of Unburned Hydrocarbon Oxidation in the Exhaust Port of a Propane-Fueled SI Engine (프로판 엔진의 배기 포트에서 탄화수소 산화 예측을 위한 모델링)

  • 이형승;박종범;최회명;민경덕;김응서
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.33-40
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    • 2000
  • In order to investigate the exhaust structure and secondary oxidation of unburned hydrocarbon (HC) in the exhaust port, a numerical simulation was performed with 3-dimensional flow model and oxidation mechanism optimized for port oxidation. To predict the exhaust and oxidation process with consideration of flow, mixing, and temperature, 3-dimensional flow model and HC oxidation model were used with a commercial computational program, STAR-CD. The flow model were with moving grid for valve motion, which could predict the change of flow field with respect to valve lift. Optimization was performed to predict the HC oxidation with temperature range of 1200~1500K, low HC and oxygen concentration, existence of intermediate species, as typical in port oxidation. The constructed model could predict the port oxidation process with oxidation degree of 14~48% according to the engine operation conditions.

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Dry Etching Characteristics of ZnO Thin Films for the Optoelectronic Device by Using Inductively Coupled Plasma

  • Joo, Young-Hee;Woo, Jong-Chang;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.1
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    • pp.6-9
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    • 2012
  • In this study, we carried out an investigation of the etching characteristics (etch rate, selectivity to $SiO_2$) of ZnO thin films in $N_2/Cl_2$/Ar inductivity coupled plasma. A maximum etch rate and selectivity of 108.8 nm/min and, 3.21, respectively, was obtained for ZnO thin film at a $N_2/Cl_2$/Ar gas mixing ratio of 15:16:4 sccm. The plasmas were characterized by optical emission spectroscopy. The x-ray photoelectron spectroscopy analysis showed the efficient destruction of oxide bonds by ion bombardment. An accumulation of low volatile reaction products on the etched surface was also shown. Based on this data, an ion-assisted chemical reaction is proposed as the main etch mechanism for plasmas containing $Cl_2$.

Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel (저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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Etching characteristics of PST thin films for tunable device application (Tunable 소자 응용을 위한 PST 박막의 식각특성)

  • Kim, Jong-Shik;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.726-729
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    • 2004
  • Etching characteristics of (Pb,Sr)$TiO_3$(PST) thin films were investigated using inductively coupled chlorine based plasma system as functions of gas mixing ratio, RF power and DC bias voltage. It was found that increasing of hi content in gas mixture lead to sufficient increasing of etch rate and selectivity of PST to Pt. The maximum etch rate of PST film is $562{\AA}/min$ and the selectivity of PST film to Pt is 0.8 at $Cl_2/(Cl_2+Ar)$ of 20 %. It was Proposed that sputter etching is dominant etching mechanism while the contribution of chemical reaction is relatively low due to low volatility of etching products.

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Transglycosylation of Permethylated Methyl D-Glycopyranosides in the Presence of Trimethylsilyl Trifluoromethanesulfonate

  • 이창귀;전정호;서영환
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1233-1238
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    • 1998
  • Transglycosylation reactions among methyl 2,3,4,6-tetra-O-methyl-D-glycopyranosides and isomeric butyl alcohols or cyclohexanol took place in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) in dichloromethane. The extent of the reaction after 1 h and 24 h from mixing was determined by gas chromatography (GC). Anomerization of the substrate took place during the course of transglycosylation, which favors α anomer regardless of the anomeric configurations of the starting glycosides. Transglycosylation also favors the a anomer regardless of the steric bulkiness of the alcohol. tert-Butyl alcohol did not give any transglycosylation, suggesting the steric hindrance of approaching the bulky alcohol to the oxonium intermediate. A mechanism for the transglycosylation have been proposed.

Mechanistic Change-Over in Nucleophilic Solvent Assisted Reactions

  • Sung, Dae Dong;Kim Yang Hee;Park Yoo-Mee;Ryu Zoon Ha;Lee Ickchoon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.599-605
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    • 1992
  • Rate constants of methanolyses of para-Z-substituted benzenesulfonyl chlorides have been determined in various isodielectric solvent mixtures. A third-order kinetic behavior has been observed in the methanolysis of p-nitrobenzenesulfonyl chloride in methanol-nitromethane mixture from the correlation figure of logarithms of rate constants were plotted against Y-values based on solvolyses of 1-adamantyl tosylate. $S_N1$-$S_N2$ mixing mechanisms are favored by neutral or weak electron-donating and weak electron-withdrawing substituents of p-Z-substituted benzenesulfonyl chlorides in methanol-nitrobenzene mixture. While the methanolyses of para-Z-substituted benzenesulfonyl chlorides in methanol-ethylene glycol solvent mixture are appropriate for $S_N2$ mechanism from the mechanistic criterion by means of m-values.

Combustion stability assessment of muti-injector using simulant propellant in LRE (모의 추진제를 이용한 액체로켓엔진용 다중 분사기의 연소안정성 평가 방법)

  • Seo Seonghyeon;Song Joo-Young;Seol Woo-Seok;Lee Kwang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.10a
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    • pp.229-234
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    • 2004
  • The objective of the present study is to conduct model combustion tests for double swirl coaxial injectors to identify their combustion stability characteristics. Gaseous oxygen and mixture of methane and propane have been used as simulant propellants. Two model chambers tuned to the If acoustic resonance mode of a full-scale thrust chamber were manufactured to be used as a combustion cylinder. The main idea of the experiment is that the mixing mechanism is considered as a dominant factor significantly affecting combustion instability in a full-scale thrust chamber. Self-excited dynamic pressure values in a model chamber show different combustion stability zones with respect to a recess number. Upon test results, couplings between combustion conditions and the IT acoustic resonance mode become strengthened with the increase of a recess length.

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A study on Improving the Durability of the Base Concrete Using Blast Furnace Slag (고로슬래그를 활용한 바탕콘크리트 내구성 향상에 대한 연구)

  • Jang, Yong;Kang, Ye-Jin;Lee, Dong-Oun;Kim, Dae-Geon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.36-37
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    • 2021
  • When the final finish of a building is designed with base concrete, complex deterioration occurs due to the harsh environment such as shrinkage and expansion due to external temperature changes, freezing and thawing, and the use of calcium chloride due to snow accumulation. Therefore, the pozzolanic reaction mechanism of blast furnace slag is clearly identified, and the causal relationship between the material properties and performance of the blast furnace slag is identified to present guidelines for mixing high-durability concrete.

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