• Title/Summary/Keyword: mixing layer

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Improving current and luminous efficacy of red phosphorescent Organic Light Emitting Diodes (OLEDs) by introducing graded-layer device designs enabled by Organic Vapor Phase Deposition (OVPD)

  • Schwambera, Markus;Keiper, Dietmar;Meyer, Nico;Heuken, Michael;Lindla, Florian;Bosing, Manuel;Zimmermann, Christoph;Jessen, Frank;Kalisch, Holger;Jansen, Rolf H.;Gemmern, Philipp Van;Bertram, Dietrich
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1140-1143
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    • 2009
  • Organic Vapor Phase Deposition (OVPD) equipment enables the accurate and simultaneous control of deposition rates of multiple materials as well as their homogenous mixing in the gas phase. Graded or even cross-faded layers by varying carrier gas flow are options to improve OLED performances. As example, we will show how the efficacies of standard red phosphorescent OLEDs with sharp interfaces can be increased from 18.8 cd/A and 14.1 lm/W (1,000 cd/$m^2$) to 36.5 cd/A (+94 %, 18 % EQE) and 33.7 lm/W (+139 %) by the introduction of cross-fading, which is a controlled composition variation in the organic film.

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An Evaluation on the Properties of the Hardened Lightweight Cement Using the Polyethylene Tube (폴리에틸렌 튜브를 혼입한 경량 시멘트 경화체의 기초물성 평가)

  • Kim, Sae-Young;Jeon, Bong-Min;Kim, Hyo-Youl;Oh, Sang-Gyun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.57-60
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    • 2006
  • This study proposes the physical properties of the hardened lightweight cement using the polyethylene tube and to make the fundamental data regarding a new lightweight concrete development. The aerated concrete is displaying various effects such as lightweight, insulation characteristic and it is coming to be widely applied the slab layer of apartment as an insulating material but currently the aerated concrete has many problems. Therefore, demonstrating similar property of former aerated concrete and improving the defects, developing new hardened cement is needed. In this study, we predict adopting possibility of hollow core polyethylene tube, as a material to make cement hardening containing a lot of void. So we changed the mixing ratio, a diameter and length of the polyethylene tube and improved the compressive strength and unit capacity weight of the lightweight cement hardening body. From the test results, we judge that the aerated concrete is a developmental possibility.

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Computational Study of Intermetallic Reaction Propagation in Nanoscale Boron/Titanium Metallic Multilayers (보론/티타늄 나노박막다층 내 이종금속간 화학반응 전파특성 해석연구)

  • Kim, Kyoungjin;Park, Joong-Youn
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.10-17
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    • 2017
  • The analytical modeling has been established on the self-propagation of intermetallic reaction in the spanwise direction of highly reactive boron and titanium nanoscale multilayers. Assuming that the reaction obeys Arrhenius kinetics, two-dimensional computations are carried out for heat and atomic species diffusion with exothermic reaction model in order to simulate the self-propagation of intermetallic reaction. The effects of bimetallic layer thickness and thickness ratio on the reaction propagation speed are tested and discussed in addition to the assessment of pre-mixing zone effects.

An Experimental Study on Flame Structure and Combustion Characteristics of Turbulent Diffusion Flame(I) (난류확산화염의 화염구조와 연소특성에 관한 실험적 연구)

  • Choe, Byeong-Ryun;Jang, In-Gap;Choe, Gyeong-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.3
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    • pp.1028-1039
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    • 1996
  • This study was focused on the examination of the flame structure and the combustion characteristics of diffusion flame which was formed the turbulent shear flow of a double coaxial air jet system. The shear flow was formed by the difference velocity of surrounding air jet(U$\_$s/) and center air jet (U$\_$c/). So experimental condition was divided S-type flame (.lambda. > 1) and C-type flame (.lambda. < 1) by velocity ratio .lambda. (=U$\_$s//U$\_$c/). For examination of the flame structure and the combustion characteristics in diffusion flame, coherent structure was observed in flame by schlieren photograph method. We measured fluctuating temperature and ion current simultaneously and accomplished the statistical analysis of its. According to schlieren photograph, the flame was stabilized in the rim of the direction of lower velocity air jet, coherent eddy was produced and developed by higher velocity air jet. The statistical data of fluctuating temperature and ion current was indicated that reaction was dominated by higher velocity air jet. The mixing state of burnt gas and non-burnt gas was distributed the wide area at Z = 100 mm of C-type flame.

Preparation of SiO2-Coated TiO2 Composite Materials with Enhanced Photocatalytic Activity Under UV Light

  • Hu, Shaozheng;Li, Fayun;Fan, Zhiping
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1895-1899
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    • 2012
  • $SiO_2$-coated $TiO_2$ composite materials with enhanced photocatalytic activity under UV light was prepared by a simple catalytic hydrolysis method. XRD, TEM, UV-vis spectroscopy, Photoluminescence, FT-IR and XP spectra were used to characterize the prepared samples. The obvious shell-core structure was shown for obtained $SiO_2$@$TiO_2$ sample. The average thickness of the $SiO_2$ coating layer was 2-3 nm. The interaction between $SiO_2$ and $TiO_2$ restrained the recombination of excited electrons and holes. The photocatalytic activities were tested in the degradation of an aqueous solution of a reactive dyestuff, methylene blue, under UV light. The photocatalytic activity of $SiO_2$@$TiO_2$ was much higher than that of P25 and mechanical mixing sample $SiO_2/TiO_2$. The possible mechanism for the photocatalysis was proposed.

A Review on the Photochemical Oxidant Modeling as Applied to Air Quality Studies in Complex Terrain

  • Hwa-Woon Lee;Yoo
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.19-33
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    • 1992
  • The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorolog ital processecs . In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification Process through observation is emphasized.

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A Study on the Etching Characteristics of $CeO_2$ Thin Films using inductively coupled $Cl_2$/Ar Plasma (유도 결합 플라즈마($Cl_2$/Ar)를 이용한 $CeO_2$ 박막의 식각 특성 연구)

  • 오창석;김창일;권광호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.29-32
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    • 2000
  • Cerium oxide thin film has been proposed as a buffer layer between the ferroelectric film and the Si substrate in Metal-Ferroelectric-Insulator-Silicon (MFIS ) structures for ferroelectric random access memory (FRAM) applications. In this study, CeO$_2$ thin films were etched with Cl$_2$/Ar gas combination in an inductively coupled plasma (ICP). The highest etch rate of CeO$_2$ film is 230 $\AA$/min at Cl$_2$/(Cl$_2$+Ar) gas mixing ratio of 0.2. This result confirms that CeO$_2$ thin film is dominantly etched by Ar ions bombardment and is assisted by chemical reaction of Cl radicals. The selectivity of CeO$_2$ to YMnO$_3$ was 1.83. As a XPS analysis, the surface of etched CeO$_2$ thin films was existed in Ce-Cl bond by chemical reaction between Ce and Cl. The results of XPS analysis were confirmed by SIMS analysis. The existence of Ce-Cl bonding was proven at 176.15 (a.m.u.).

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Electrochemical behavior of Calcium Titanate Coated Ti-6Al-4V Substrate in Artificial Saliva

  • Lee, Byoung-Cheon;Balakrishnan, A.;Ko, Myung-Won;Choi, Je-Woo;Park, Joong-Keun;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.18 no.1
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    • pp.22-25
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    • 2008
  • In this study, calcium titanate $(CaTiO_3)$ gel was prepared by mixing calcium nitrate and titanium isopropoxide in 2-methoxy-ethanol. $CaTiO_3$ gel was single-layer coated on Ti-6Al-4V using a sol-gel dip-coating technique. The coating was calcined at $750^{\circ}C$ in air by utilizing a very slow heating rate of $2^{\circ}C/min$. The crystalline phases of the coating were characterized by x-ray diffraction using a slow scan rate of $1^{\circ}/min$. The morphology of the coating was analyzed by scanning electron microscopy. The corrosion behavior of Ti-6Al-4V samples coated with $CaTiO_3$ films were tested in an artificial saliva solution by potentiodynamic polarization and were quantified by the Tafel extrapolation method. The electrochemical parameters showed a considerable increase in the corrosion resistance for the $CaTiO_3$-coated Ti-6Al-4V samples compared to bare substrates.

Flood Risk Analysis Considering the Sediment Transport in a River (하천에서의 유사이동의 영향을 고려한 홍수위험도 분석)

  • Son, In Ho;Kim, Byung Hyun;Han, Kun Yeun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.302-302
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    • 2015
  • 본 연구에서는 PMP 조건하에서 농업용 목적의 시례저수지의 가상붕괴에 따른 홍수파 해석을 통해서 하류부에 대한 수리학적 분석을 실시하였다. 그리고, 사력댐으로 구성된 댐 제체의 붕괴로 인한 유사 이송을 모의하고 이로 인한 하류부에서의 영향을 분석하였다. 이를 위하여 경상남도 김해에 위치한 시례저수지 유역을 대상으로 수리 수문자료 및 하천현황을 상세히 조사하고 댐의 가상 붕괴로 인한 하류부 홍수파 해석 및 댐 본체의 유실에 따른 유사의 이송으로 인해 발생 가능한 하류부에서의 영향을 분석하였다. 시례저수지의 댐 형식은 흙댐으로써, 구성방식은 침하량이 적은 중심코아형이며 댐 높이는 34.3 m, 유역면적은 3.13 km이다. 본 연구에서는 하천에서의 흐름과 유사이송 계산이 가능한 1차원 수치 모형인 CCHE1D를 이용하였다. 적용 모형은 확산파 및 동역학적 방정식을 모두 고려한다. 또한, 비평형 이송 모형을 사용하여 유사의 발생과 퇴적을 산정하고 비균질 상태의 유사 이송을 계산 하는데 있어서 하천 단면형의 변화와 하상물질의 구성 상태, 제방침식, 수로 확폭의 과정과 함께 산정된다. CCHE1D는 하상물질의 공극률과 non-equilibrium adaptation length, mixing layer thickness 등의 여러 변수들을 현재까지 개발된 식들을 제공하며, 토사이동해석을 위한 공식은 SEDTRA 모듈, Wu et al(2000) 공식, 수정 Ackers and White(1973) 공식, 수정 Engelund and Hansen(1967)이 사용된다. 비균질 유사이송과 bed deformation, bed-material sorting은 완전연계과정(coupling)로, 유사와 흐름방정식의 계산은 반연계과정(semi coupling)을 적용하여 계산하였다.

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Influence of the Vertical Flame holder on Heat Transfer Characteristics of Ramjet Combustor (세로축 화염안정기 형상이 램제트 연소실에서의 열전달 특성에 미치는 영향)

  • Yang, Kang-Mo;Lee, Keon-Woo;Song, Ji-Woon;Cho, Hyung-Hee;Hwang, Ki-Young
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.305-309
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    • 2008
  • This experimental study has been conducted to investigate the installation of the vertical flame holder shape in ramjet combustor, which affects on the film cooling effectiveness. All slot position, the film cooling effectiveness decreases because of the shear layer and high turbulence intensity between separated flows and coolant flows. When the flame holder is installed, film cooling effectiveness decreases abruptly on the beginning of the slot exit region due to the mixing effect. As the blowing rate increases, the film cooling effectiveness is increased for all cases due to the augmented momentum of injected coolant from the slot.

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