• Title/Summary/Keyword: mixing condition

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CaCO3 Biomineralization in Microfluidic Crystallizer (미세유체 결정화기를 이용한 탄산칼슘 Biomineralization)

  • Seo, Seung Woo;Ko, Kwan Young;Lee, Chang Soo;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.151-156
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    • 2013
  • Crystallization of $CaCO_3$ is practiced on a polymethylsiloxane (PDMS) - based microfluidic system. Liquid- liquid reaction was investigated by mixing calcium chloride ($CaCl_2$) and sodium carbonate ($Na_2CO_3$) solution to crystallize $CaCO_3$. Aspartic acid (Asp) was added to investigate the morphology change such as vaterite and calcite. Suitable ratio of $Na_2CO_3$ and $CaCl_2$ was searched for initial seed formation. Christmas tree model was used as microfluidic device to form concentration gradient of $Na_2CO_3$ and $CaCl_2$. After observing microfluidic channel by using optical microscope, we found that seeds of $CaCO_3$ were formed under the condition that the ratio of $Na_2CO_3$ and $CaCl_2$ was 2:1. Morphology of crystals were also observed as $CaCO_3$ crystals grow. When Asp was added, vaterite crystal was more frequently found in two morphologies (vaterite and calcite) and seed formation and crystal growth were inhibited.

Structure and Oxidation Behavior of the $LaCrO_3$-dispersed Cr alloys ($LaCrO_3$가 분산된 Cr 합금의 구조 및 산화거동)

  • Jeon, Kwang-Sun;Song, Rak-Hyun;Shin, Dong-Ryul;Jo, J.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1303-1305
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    • 1998
  • In order to reduce or avoid oxidation problem at operation the interconnects in SOFCs have so far mostly been made of ceramic material. It has high chemical stability both under cathode and anode condition, relatively thermal expansion coefficient that matchs that of electrolyte material YSZ. But this material shown rather weak in the low oxygen atmosphere and thermal shock, and it has lower mechanical strength than alloys. To avoid these problems one may consider to use metals or alloys as materials for interconnects. Metallic interconnects are advantageous because of their high thermal and electronic conductivities. But it has some problems, Those are high thermal expansion and oxidation at high temperature in air. To solve these problems in the interconnection material in this study, $LaCrO_3$-dispersed Cr alloys for metallic interconnector of SOFC have been investigated as a fuction of $LaCrO_3$ content in the range of 5 to 25 vol.%. The Cr alloy were prepared by mixing Cr and $LaCrO_3$ powders in high-energy ball mill for 48h and by sintering under Ar atmosphere with 5vol.% $H_2$ for 10h at $1500^{\circ}C$. The alloys had a relative density of 95% and above. The Cr alloys in composed of two kind of small $LaCrO_3$ and large Cr particles. As the $LaCrO_3$ content increased, the Cr particle size decreased but the $LaCrO_3$ particle size remained contant. Also the oxidation tests show that the $LaCrO_3$-dispersed Cr is very resistant to oxidation in air. These results means that $LaCrO_3$-dispersed Cr is a useful material for metallic interconnect of planar SOFC.

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Development of Squash Sikhye Added with Retrograded Rice Flour Containing Resistant Starch Using Response Surface Methodology and Quality Comparison with Commercial Beverages (반응표면검사를 이용한 RS함유 노화쌀가루를 첨가한 단호박식혜 개발 및 시판음료와 품질비교)

  • Ha, Kyungae;Park, Boseock;Chang, Hyeja
    • Korean journal of food and cookery science
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    • v.30 no.2
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    • pp.129-138
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    • 2014
  • This research aimed to develope squash sikhye containing retrograded rice flour using response surface methodology. For this, nonlinear regression equation was calculated with the setting of independent variables as retrograded rice flour containing resistant starch and squash, and dependent variables as viscosity, sugar content, pH, color, and sensory attributes. Under the experimental condition, the quality characteristics of squash sikhye were found as 6.20~6.25 for pH, $14.00{\sim}17.33^{\circ}Brix$ for sweetness, 2.64~4.45 cP for viscosity, 57.51~60.18 for lightness, 4.94~7.52 for redness, and 50.98~60.29 for yellowness. It also was revealed overall acceptability in sensory evaluation rated as 9.67~10.83 out of 15 point. These results showed statistically significant differences in quality attributes with the increase of retrograded rice flour and squash(p<0.05). Thus, optimal mixing quantity of squash and retrograded rice flour for squash sikhye was identified as 114 g and 65 g, respectively. Comparison of sensory qualities of four samples, namely squash sikhye with and without retrograded rice, and two commercial products, showed that squash sikhye including retrograded rice flour had the best quality in terms of color, taste, mouth feeling, flavor and overall acceptability (p<0.05). Thus the squash sikhye with retrograded rice flour can be the potential products as a health benefit beverage for the old adult and the young generation.

Variation of Thermohaline Structure Around Ocean Area of Artificial Upwelling Structure (인공용승구조물 주변해역의 열염구조 변화)

  • Kim, Dong-Sun;Hwang, Suk-Bum;Kim, Sung-Hyun
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.1-7
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    • 2007
  • To illustrate the variation of oceanic condition around artificial upwelling structure which is located in the South Sea of Korea, cm observations were carried out on December, 2005, April, August and October, 2006. Temperature, salinity and density(sigma-t) was nearly homogeneous through the whole depth by mixing of the seawater in winter. Stratification was not clear in spring, and it was only formed weakly in the surface layer shallower than 10m. Stratification was formed about $10{\sim}20$ m depth in summer and about $30{\sim}40$ m depth in autumn. Vertical gradient of temperature was larger than that in the part of western area along the artificial seamount in summer and autumn. The variation of stratification was also occurred around near the artificial structure area after set up structure.

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On mixing the Rayleigh-Ritz formulation with Hankel's function for vibration of fluid-filled functionally graded cylindrical shell

  • Hussain, Muzamal;Naeem, Muhammad Nawaz;Shahzad, Aamir;Taj, Muhammad;Asghar, Sehar;Fatahi-Vajari, Alireza;Singh, Rahul;Tounsi, Abdelouahed
    • Advances in Computational Design
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    • v.5 no.4
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    • pp.363-380
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    • 2020
  • In this paper, a cylindrical shell is immersed in a non-viscous fluid using first order shell theory of Sander. These equations are partial differential equations which are solved by approximate technique. Robust and efficient techniques are favored to get precise results. Employment of the Rayleigh-Ritz procedure gives birth to the shell frequency equation. Use of acoustic wave equation is done to incorporate the sound pressure produced in a fluid. Hankel's functions of second kind designate the fluid influence. Mathematically the integral form of the Lagrange energy functional is converted into a set of three partial differential equations. Throughout the computation, simply supported edge condition is used. Expressions for modal displacement functions, the three unknown functions are supposed in such way that the axial, circumferential and time variables are separated by the product method. Comparison is made for empty and fluid-filled cylindrical shell with circumferential wave number, length- and height-radius ratios, it is found that the fluid-filled frequencies are lower than that of without fluid. To generate the fundamental natural frequencies and for better accuracy and effectiveness, the computer software MATLAB is used.

Spray Charateristics of Water/Oil Emulsified Fuel in Pressure-Swirl Nozzle (압력선회노즐에서 물-기름 유화연료의 분무특성)

  • Rhim, J.H.;No, S.Y.
    • Journal of ILASS-Korea
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    • v.5 no.1
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    • pp.5-12
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    • 2000
  • The beneficial aspects of applying emulsion fuels to combustion systems may be due to the changes of fuel properties which lead to the enhanced atomization characteristics. The spray characteristics of water/oil emulsified fuel injected from the pressure-swirl(simplex) atomizer using for oil burner were investigated. Four different water contents from 10 to 40 % by volume at 10% increment were prepared by mixing with the different contents of surfactants. Total amount of surfactant used was varied from 1 to 3 % by volume. This study demonstrates the influence of water and surfactant contents of emulsified fuel, injection pressure on the spray characteristics, i.e. Sauter mean diameter(SMD) and spray angle. The drop size distribution of the emulsified fuel spray was measured with a Malvem particle sizer. In order to measure the spray angle, the digital image processing was employed by capturing multiple images of the spray with 3-CCD digital video camera. It was evident that the addition of water and surfactant changes fuel properties which are the key parameters influencing the atomization of the spray. The increase in surfactant content results in the decrease of SMD and the increase in spray angle. The droplets decease with increase in injection pressure, but the influence of injection pressure in this experimental condition was less important than expected. The more viscous fuel with the increase of water content exhibits the larger droplets in the centerline of the spray, and the less viscous fuel in the outer edges of the spray. The increase in axial position from the nozzle causes the spray angle to decrease. The spray angle decreases with increase in water content. This is due to increase in viscosity with increase in water content.

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A Study on the Dry Cleaning of Aluminium Surfaces by Low Temperature Plasma Process (저온 플라스마 공정을 이용한 알루미늄 표면의 건식 세정에 관한 연구)

  • Lim, Gyeong-Taek;Kim, Kyung Hwan;Kim, Kyung Seok;Li, Hui Jie;Song, Sun Jung;Shon, Hokyong;Cho, Dong Lyun
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.640-644
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    • 2008
  • Lubricating oil on aluminium surfaces was cleaned by a low temperature plasma process. Oxygen plasma mixed with argon was used, and process parameters were the mixing ratio of argon in oxygen, discharge power, and negative DC potential. The aluminium surfaces were analyzed with FTIR and EDX after the cleaning. It was found that almost all of the oil was eliminated in 20 min. if the oil was pure. Elimination efficiency was highly dependent on operational conditions of the process. The highest efficiency was obtained when treated at 300 W with oxygen plasma mixed with 30% argon applying negative potential more than -500 V on the aluminium surfaces. However, efficiency higher that 60% cannot be obtained at any condition if the oil contained inorganic materials.

Numerical Study on a Hydrogen Recirculation Ejector for Fuel Cell Vehicle (연료전지 수소재순환 이젝터 시스템에 관한 수치해석적 연구)

  • NamKoung, Hyuck-Joon;Moon, Jong-Hoon;Jang, Seock-Young;Hong, Chang-Oug;Lee, Kyoung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.156-160
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    • 2007
  • Ejector system is a device to transport a low-pressure secondary flow by using a high-pressure primary flow. Ejector system is, in general, composed of a primary nozzle, a mixing section, a casing part for suction of secondary flow and a diffuser. It can induce the secondary flow or affect the secondary chamber pressure by both shear stress and pressure drop which are generated in the primary jet boundary. Ejector system is simple in construction and has no moving parts, so it can not only compress and transport a massive capacity of fluid without trouble, but also has little need for maintenance. Ejectors are widely used in a range of applications such as a turbine-based combined-cycle propulsion system and a high altitude test facility for rocket engine, pressure recovery system, desalination plant and ejector ramjet etc. The primary interest of this study is to set up an applicable model and operating conditions for an ejector in the condition of sonic and subsonic, which can be extended to the hydrogen fuel cell vehicle. Experimental and theoretical investigation on the sonic and subsonic ejectors with a converging-diverging diffuser was carried out. Optimization technique and numerical simulation was adopted for an optimal geometry design and satisfying the required performance at design point of ejector for hydrogen recirculation. Also, some sonic and subsonic ejectors with the function of changing nozzle position were manufactured precisely and tested for the comparison with the calculation results.

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A Study on the Volatilization of Ammonia from Flooded Soils Mixed with Rice Straw and Liming Materials (담수토양(湛水土壤)에서 볏짚과 석회물질(石灰物質) 시용(施用)이 암모니아 휘산(揮散)에 미치는 영향(影響))

  • Oh, Wang-Keun;Hwang, Kwang-Nam;Lee, Myong-Gu
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.3
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    • pp.166-171
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    • 1982
  • A laboratiory experiment incubated at about $30^{\circ}C$ for 34 days was conducted in order to learn the effect of liming materials and rice straw on the volatilization of ammonia from flooded soils applied with urea. 1. The application of calcium hydroxide and calcium silicate increased buffer action of flood soil, though it resulted in increase in the volatilization of ammonia through raising flooded soil pH containing bicarbonate. 2. The mixing of rice straw powder to soil lowered pH of flooded soil, and decreased the volatilization of ammonia. The effect was particulary large when noliming material was used. 3. Calcium hydroxide depressed the evolution of $CO_2$ in the early days of incubation after flooding, while calcium silicate promoted the ammonification of soil nitrogen from the begining of flooding giving slow change in soil chemical properties. The rice straw was also effective in providing a favorable soil condition for the ammonification rather quickly.

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A Performance Evaluation of the Highly Efficient Coagulation System for the Treatment of Overflows from Primary Clarifier in WWTP (강우시 하수처리장 일차침전지 월류수 처리를 위한 고효율응집시스템의 적용성 평가)

  • Gwon, Eun-Mi;Oh, Seok-Jin;Kim, Heung-Seup;Cho, Seung-Ju;Lee, Seung-Chl;Ha, Sung-Ryong;Lim, Chea-Hoan;Park, Ji-Hoon;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.391-398
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    • 2011
  • This study is to develop highly efficient coagulation system(HECS) that runs treatment with a short retention time to cover the overflow in the rain, which coagulation, mixing and settling are contacted in a single reactor and to estimate the applicability. Setting up 100ton/day-size pilot scale plant, the results of continuous operation in case of runoff, maintaining 20 minute-retention time at optimum chemical injection condition(Alum 100mg/L, Polymer 1.0mg/L) shows the highest removal efficiency(Turbidity 93.1%, TCODcr 80.6%, BOD 81.8%, SS 92.5%, TN 72.3% and T-P 87.3%). It was estimated that the large amount of cost for separate sewage system and the size of area for system instruction can be reduced if the HECS is applied for CSOs treatment because the HECS is so compact and quickly. When we see the results, HECS from this study could be able to treat the pollutant quickly within a short retention time only with coagulant and polymer, which could show high applicability.