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Effects of Light-Curing on the Immediate and Delayed Micro-Shear Bond Strength between Yttria-Tetragonal Zirconia Polycrystal Ceramics and Universal Adhesive

  • Lee, Yoon;Woo, Jung-Soo;Eo, Soo-Heang;Seo, Deog-Gyu
    • Journal of Korean Dental Science
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    • v.8 no.2
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    • pp.82-88
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    • 2015
  • Purpose: To evaluate the effect of light-curing on the immediate and delayed micro-shear bond strength (${\mu}SBS$) between yttria-tetragonal zirconia polycrystal (Y-TZP) ceramics and RelyX Ultimate when using Single Bond Universal (SBU). Materials and Methods: Y-TZP ceramic specimens were ground with #600-grit SiC paper. SBU was applied and RelyX Ultimate was mixed and placed on the Y-TZP surface. The specimens were divided into three groups depending on whether light curing was done after adhesive (SBU) and resin cement application: uncured after adhesive and uncured after resin cement application (UU); uncured after adhesive, but light cured after resin cement (UC); and light cured after adhesive and light cured resin cement (CC). The three groups were further divided depending on the timing of ${\mu}SBS$ testing: immediate at 24 hours (UUI, UCI, CCI) and delayed at 4 weeks (UUD, UCD, CCD). ${\mu}SBS$ was statistically analyzed using one-way ANOVA and Student-Newman-Keuls multiple comparison test (P<0.05). The surface of the fractured Y-TZP specimens was analyzed under a scanning electron microscope (SEM). Result: At 24 hours, ${\mu}SBS$ of UUI group ($8.60{\pm}2.06MPa$) was significantly lower than UCI group ($25.71{\pm}4.48MPa$) and CCI group ($29.54{\pm}3.62MPa$) (P<0.05). There was not any significant difference between UCI and CCI group (P>0.05). At 4 weeks, ${\mu}SBS$ of UUD group ($24.43{\pm}2.88MPa$) had significantly increased over time compared to UUI group (P<0.05). The SEM results showed mixed failure in UCI and CCI group, while UUI group showed adhesive failure. Conclusion: Light-curing of universal adhesive before or after application of RelyX Ultimate resin cement significantly improved the immediate ${\mu}SBS$ of resin cement to air-abrasion treated Y-TZP surface. After 4 weeks, the delayed ${\mu}SBS$ of the non-light curing group significantly improved to the level of light-cured groups.

Characteristics and Improvement of Potential Acid Sulfate Soil Derived from Continental Materials on Alluvial Fan (선상지(扇床地) 육성(陸成) 잠재특이산성토(潛在特異酸性土)의 특성과 개량)

  • Jung, Yeun-Tae;Yun, Eul-Soo;Son, Il-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.3
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    • pp.195-201
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    • 1992
  • A Potential acid sulfate soil derived from continental Holocene deposits on the fan-base was found and it was characterized with improvement practices. Artesian wells were scattered in the area, and the imperfectly drained soils were featured by having fine loamy with 7~30% of gravels. The potential acid sulfate soil layers were typified by having darkness in color with around 3.3~3.8% of O.M. and 0.34~0.41% of total sulfur. Soil pH ranged from 3.4 to 3.8 but it was decreased to 1.9~2.5 after oxidation with $H_2O_2$. Ground water sprang out from an artesian well contained a high amount of minerals such as Na, Ca, Mg, K, etc. and about 80ppm of sulfate which seemed to be responsible for pyrite formation. The soil was classified to member of "Fine loamy, mixed, acid, mesic, sulfic Haplaquepts" in taxonomically, and "weak potential acid sulfate soils" in interpretatively. The installation of tile drains with adding fine earth and liming were effective. However, the pH goes down to 4.8 again after 3 years of improvement practices.

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Effects of Supplementary Levels of Deep-stacked Broiler Litter on Digestibility, Dry Matter Intake, and Nitrogen Balance by Male Spotted Deer(Cervus Nippon) (육계분 발효사료의 첨가수준이 숫꽃사슴의 소화율, 건물채식량 및 질소출납에 미치는 영향)

  • Jeon, B. T.;Kwak, W. S.;Kang, S. K.;Lee, S. M.;Moon, S. H.
    • Journal of Animal Science and Technology
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    • v.45 no.1
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    • pp.79-86
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    • 2003
  • To determine nutritive value and suitability of deep-stacked broiler litter for deer, the influence of supplementary levels of broiler litter on digestibility, dry matter intake, and nitrogen balance was investigated in male spotted deer (Cervus nippon) fed a commercial mixed(complete) ration. The deep-stacked and ground broiler litter was supplemented at the level of 0%(Control), 15%(T1) and 30%(T2) on the basis of fresh matter to the mixed ration. All treatments had similar palatability at about 3% body weight of dry matter intake. Dry matter digestibility was highest in Control and lowest in T2(P<0.05). Digestibility of crude protein was lowest(P<0.05) in T2. Dry matter and digestible dry matter intake was similar in all treatments. Daily body weight gain was not affected by treatments. Feeding 15 or 30% of broiler litter to male deer resulted in similar nitrogen intake, fecal nitrogen excretion and daily nitrogen retention(g/d), compared with feeding Control. These results suggest that up to 30% of broiler litter may be fed to male deer without deleterious effects on deer performance.

Effect of N Application Rate on Fixation and Transfer from Vetch to Barley in Mixed Stands. (질소시용수준이 베치-보리 혼파 사초의 질소고정 및 베치에서 보리로 질소이동에 미치는 영향)

  • Lee Hyo Won;Kim Won Ho;Park Hyung Soo;Ko Han Jong;Kim Su Gon
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.25 no.1
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    • pp.1-6
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    • 2005
  • With recent interest organic farming the use of legumes including vetch and clover to provide N to adjacent crops is increasing in Korea. In the present studies, we conducted a trial to investigate the effects of the application of N rate on nitrogen fixation and transfer from vetch to barley in mixed stands. The experiment was arranged in a randomized complete block design with three replications. Four different N rates(0, 75, 113 and 150/ha) was used and vetch+barley was broadcasted manually on 1.5 $\times$2 m plot in Oct. 2001. Half of urea and K$_{2}O, 200 Phosphate and 75 kg potash per ha were applied as basal dressing md half of N md 75 potash were used for topdressing to soil surface on MarctL 2002. The equivalent of 1kg ha$^{-1}$ at($^{15}$NH$_{4}$)$_{2}$SO$_{4}$ solution at 99.8 atom $\%$$^{15}$N excess was applied to the microplot in mid April. Forage was harvested from each plot at ground level and separated into barley and vetch. Total N content and It values of samples were determined using a continuous flow stable isotope ratio mass spectrometry(IsoPrime-EA. Micromass, UK.). The percentage of legume H fixed from atmospheric N2 were 95.0, 93.8, 94.4 and $84.8\%$ with increment of N levels. The percentage of N transfer from vetch to barley by N-difference method with increment of N fertilizer were from 58 to$49\%$ while 39 to $23\%$ in $^{15}$N-dilution method. The amount of transfer from vetch to barley were 87 to 68 kg/ ha with N level by N-difference moth여 and 58 to -56/ha with N application levels by $^{15}$N dilution method. The amount of nitrogen fixation per ha were from 150 kg / ha to 219 kg / ha by different method, but on the other side 49 to 105kg/ha by N$^{15}$-dilution.

Improving of land-cover map using IKONOS image data (IKONOS 영상자료를 이용한 토지피복도 개선)

  • 장동호;김만규
    • Spatial Information Research
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    • v.11 no.2
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    • pp.101-117
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    • 2003
  • High resolution satellite image analysis has been recognized as an effective technique for monitoring local land-cover and atmospheric changes. In this study, a new high resolution map for land-cover was generated using both high-resolution IKONOS image and conventional land-use mapping. Fuzzy classification method was applied to classify land-cover, with minimum operator used as a tool for joint membership functions. In separateness analysis, the values were not great for all bands due to discrepancies in spectral reflectance by seasonal variation. The land-cover map generated in this study revealed that conifer forests and farm land in the ground and tidal flat and beach in the ocean were highly changeable. The kappa coefficient was 0.94% and the overall accuracy of classification was 95.0%, thus suggesting a overall high classification accuracy. Accuracy of classification in each class was generally over 90%, whereas low classification accuracy was obtained for classes of mixed forest, river and reservoir. This may be a result of the changes in classification, e.g. reclassification of paddy field as water area after water storage or mixed use of several classification class due to similar spectral patterns. Seasonal factors should be considered to achieve higher accuracy in classification class. In conclusion, firstly, IKONOS image are used to generated a new improved high resolution land-cover map. Secondly, IKONOS image could serve as useful complementary data for decision making when combined with GIS spatial data to produce land-use map.

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The Feasibility Study for Utilization of Blended Cement as a Activator of Bottom Ash from Circulating Fluidized Bed Combuster Boiler (순환유동층 보일러 바텀애시의 혼합시멘트 자극제 활용을 위한 타당성 연구)

  • Park, JongTak;Jung, Gwon Soo;Kang, Chang Ho;Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.255-262
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    • 2020
  • Blended cement with fly ash and bottom ash from Circulating Fluidized Bed Combustor boiler(CFBC) burned at a low temperature, can be high heat of hydration and abnormal setting caused by higher volumn contents of Fe2O3, free-CaO, SO3. In this study, the ground CFBC bottom ash powder mixed with blast furnace slag was used as substitute activator of gypsum and recycled iron slag was produced from mix and pulverized by ball mill to increase the recycling rate. The effect on compressive strength of cements with the mixture of original and hydrated bottom ash mixtures with BFS with small water, respectively, was analyzed, and it was found that the hydrated bottom ash activator was more effective in initial strength development. To improve the initial strength of blended cement, an activator mixed with a blast furnace slag and bottom ash mixing ratio of 5:95 and 10:90, respectively, the slag cement by about 6%, and it was analyzed to develop an initial strength similar to gypsum as a conventional activator.

Unconfined Compressive Strength of Reduced Slag-Mixed Clay (환원슬래그 혼합점토의 일축압축강도 특성)

  • Cho, Minjae;Yoon, Yeowon;Kim, Jaeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.6
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    • pp.33-39
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    • 2012
  • With the increase of steel production research interest on the recycling of slag as a by-product also increases steadily. Currently in Korea a lot of researches on blast-furnace slag have been made. However, the researches on the steel slag have been rarely made. Also, a research of steel slag, especially the use of oxidation furnace slag as aggregates for concrete progress, is performing actively, but the research results on the furnace slag are almost nothing. Recently, the research about the furnace slag as backfill material and embankment material confirmed the possibility of the clay soil amendment. Therefore, the object of this study is to review the possibility as civil engineering materials for soil improvement and to find the optimum mixture ratio of furnace slag. This research analyzed the ingredient component of the reduced slag by SEM, XRF, XRD tests and examined the strength increase using unconfined compression tests when the clay and reduced slag are mixed each other. Through this test, the definite strength increase is confirmed according to the mixture of the reduced slag and the possibility of soil improvement is also confirmed based on this result. The object of the study is both utilizing the by-product for civil engineering purpose and effective recycling by the application of the furnace slag for soil improvement.

Use of N-alkanes to Estimate Intake and Digestibility by Beef Steers

  • Premaratne, S.;Fontenot, J.P.;Shanklin, R.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.11
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    • pp.1564-1568
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    • 2005
  • The objective of the study was to evaluate the use of n-alkanes to estimate DM intake and digestibility by beef cattle. Six steers were blocked (3 blocks, 2 animals/block) according to the body weight (279${\pm}$19 kg) and randomly allotted within blocks to two diets (3 steers/diet). A second trial was conducted with the same animals (321${\pm}$18 kg) after 36 days (d), using a switch back design. The diets consisted of two types of chopped sun-cured hay, alfalfa (Medicago sativa L) hay, or fescue (Festuca arundinacea Schreb) and alfalfa mixture, which were fed in equal amounts to steers. Animals were dosed with $C_{32}$ and $C_{36}$ alkanes, employing an intra-ruminal controlled-release device at the beginning of each trial. Hay intake per animal was measured from d 6 to 12 and sub samples were taken for chemical analysis. Rectal samples of feces were taken from each animal once/daily from d 8 to 14, freeze dried, and ground prior to alkane analysis. Alkanes were extracted from ground hay and feces. Feed intake was calculated from the dose rate of $C_{32}$ alkane and, the herbage and fecal concentrations of adjacent odd ($C_{33}$ or $C_{31}$) and even ($C_{32}$) chain length alkanes. Crude Protein, NDF, ADF, ash concentrations and In vitro dry matter digestibility (IVDMD) were 17.7, 42.2, 28.4, 7.9 and 71.7 for alfalfa, and 12.4, 56.5, 30.4, 6.9 and 69.1% for fescue/alfalfa mixture, respectively. For both diets, intake estimated from $C_{33}$:$C_{32}$ ratio was not different from the measured intake, but intake estimated from $C_{31}$:$C_{32}$ ratio was lower (p<0.05), than the measured intake for both diets. The average estimated forage intake from $C_{33}$:$C_{32}$ ratio was 4.86 and 0.69% below than the measured intake for alfalfa and, fescue/alfalfa mixed diets, respectively. The respective estimates with $C_{31}$:$C_{32}$ ratio were 9.59 and 11.33% below than the measured intake. According to these results, alkane $C_{33}$:$C_{32}$ ratio is better than alkane $C_{31}$:$C_{32}$ ratio for the estimation of intake by beef steers.

Effect of Exogenous Fibrolytic Enzyme Application on the Microbial Attachment and Digestion of Barley Straw In vitro

  • Wang, Y.;Ramirez-Bribiesca, J.E.;Yanke, L.J.;Tsang, A.;McAllister, T.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.1
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    • pp.66-74
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    • 2012
  • The effects of exogenous fibrolytic enzymes (EFE; a mixture of two preparations from Trichoderma spp., with predominant xylanase and ${\beta}$-glucanase activities, respectively) on colonization and digestion of ground barley straw and alfalfa hay by Fibrobacter succinogenes S85 and Ruminococcus flavefaciens FD1 were studied in vitro. The two levels (28 and 280 ${\mu}g$/ml) of EFE tested and both bacteria were effective at digesting NDF of hay and straw. With both substrates, more NDF hydrolysis (p<0.01) was achieved with EFE alone at 280 than at 28 ${\mu}g$/ml. A synergistic effect (p<0.01) of F. succinogenes S85 and EFE on straw digestion was observed at 28 but not 280 ${\mu}g$/ml of EFE. Strain R. flavefaciens FD1 digested more (p<0.01) hay and straw with higher EFE than with lower or no EFE, but the effect was additive rather than synergistic. Included in the incubation medium, EFE showed potential to improve fibre digestion by cellulolytic ruminal bacteria. In a second batch culture experiment using mixed rumen microbes, DM disappearance (DMD), gas production and incorporation of $^{15}N$ into particle-associated microbial N ($^{15}N$-PAMN) were higher (p<0.001) with ammoniated (5% w/w; AS) than with native (S) ground barley straw. Application of EFE to the straws increased (p<0.001) DMD and gas production at 4 and 12 h, but not at 48 h of the incubation. EFE applied onto S increased (p<0.01) $^{15}N$-PAMN at 4 h only, but EFE on AS increased (p<0.001) $^{15}N$-PAMN at all time points. Prehydrolysis increased (p<0.01) DMD from both S and AS at 4 and 12 h, but reduced (p<0.01) $^{15}N$-PAMN in the early stage (4 h) of the incubation, as compared to non-prehydrolyzed samples. Application of EFE to barley straw increased rumen bacterial colonization of the substrate, but excessive hydrolytic action of EFE prior to incubation decreased it.

Study on the Manufacturing Technology of Mural Tomb in Goa-dong of Daegaya Period (대가야 고아동 고분벽화 제작기술에 관한 연구)

  • Lee, Hwa Soo;Lee, Han Hyeong;Lee, Kyeong Min;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.457-466
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    • 2014
  • Rigorous analysis was performed to identify the structure and materials of the murals to study techniques used on mural tombs of ancient Daegaya era(6th century). The murals were painted by applying mortar on the walls and the ceiling after building a stone chamber and creating ground layers on mortar layers. Mud was applied on most of the mortar layers on four sides of the walls except the ceiling. Sand was not used in mortar but was made of materials with pure calcium substances. In addition, shells in irregular sizes with incomplete calcination were mixed; and the mortar's white powder was inferred as lime obtained by calcination of oyster shells. Kaolinite($Al_2Si_2O_5(OH)_4$) was used in the ground layer, Cinnabar(HgS) was used for red pigment, Malachite($Cu_2CO_3(OH)_2$) for green and Lead white($PbCO_3{\cdot}Pb(OH)_2$) for white. Mud plaster was applied on the mortar and was composed thinly and densely using clayey of particle size smaller than that of medium sand. It was assumed that the finishing was for repair after long time had passed since the mortar layer came off. Using lime made with oyster shells as mortar is unprecedented in ancient Korean mural tombs and its durability was very poor, suggesting that Gaya's mortar production technique was relatively behind compared to that of Koguryo's in the same era.