• 한국포장학회지
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• 제8권2호
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• pp.18-26
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• 2002

Films of methylcellulose(MC), chitosan and their blends were prepared using water and acid solution as a solvent. The transition behavior and miscibility of polymers and their blends were characterized by dynamic mechanical analysis(DMA) and thermogravimetric analysis(TGA). The DMA analysis of PEG400/MC blends has shown that PEG400 was compatible with MC and was effective plasticizer since the curves of $tan{\delta}$ against temperature exhibited single peak, corresponding to single glass transition temperature, which were displaced to lower values with increasing PEG400 content. Results of DMA analysis and TGA analysis of MC/chitosan blends indicate that there are some miscibility between MC and chitosan in the blends, attributed to the similarities between two polysaccharides and interactions of two polymers in the blends. The inclusion of PEG400 in the blends increase the miscibility between two components in the blends.

• 설비공학논문집
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• 제14권4호
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• pp.285-292
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• 2002

The vapor pressure and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor pressure and miscibility data for R-404A/32 ISO VG polyol ester (POE) oil mixture and R-404A/46 ISO VG polyol ester oil mixture are obtained over the temperature range from -20 to $60^{\circ}$ with at $10^{\circ}$ intervals and the oil concentration range from 0 to 70 wt%. Using the experimental data, an empirical model was developed to predict the temperature vapor pressure-concentration relations for R-404A/46 ISO VG polyol ester oil mixtures at equilibrium. In the R-404A/32 ISO VG polyol ester oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 1.24% and in the R-404A/46 ISO VG polyol ester oil mixture, that is 1.37%. Miscibility for R-404A/32 ISO VG polyol ester oil mixture was observed all over the experimental conditions. Immiscibility for R-404A/So1est 46 oil mixture was observed at the low oil concentrations (20~30 wt%) over the high experimental temperature range (50~$60^{\circ}$).

• 대한화학회지
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• 제58권6호
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• pp.528-534
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• 2014

어떤 이성분계용액에서는 상한임계용액온도와 하한임계용액온도가 동시에 나타나는 원형모양의 온도-조성 상도를 보인다. 이러한 현상은 분자간 특정상호작용이 존재하는 경우 나타나는 것으로 알려져 있다. 특정상호작용을 묘사하는 방법에는 여러 가지가 있다. 본 연구에서는 특정상호작용의 총수가 이항분포에 따라 분포한다고 가정하였다. 이 경우 특정상호작용을 Regular 용액이론, Quasichemical 이론 그리고 Flory-Huggins 격자이론에 적용하였을 때 원형모양의 온도-조성 상도를 보이는 경우에 대한 정확한 수학적인 조건을 유도하였다. 그리고 매개변수들이 온도-조성상도에 미치는 영향을 조사하였고, 물-니코틴에 대한 온도-조성상도를 계산하여 실험값과 비교하여 보았다.

• 설비공학논문집
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• 제12권6호
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• pp.589-598
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• 2000

The vapor-liquid equilibrium and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor-liquid equilibrium and miscibility data for R-410a/POE32 and R-410A/POE46 oil mixtures are obtained over the temperature range from -20 to $60^{\circ}C\;with\;10^{\circ}C$ intervals and the oil concentration range from 0 to 90 wt%. Using the experimental data, an empirical model is developed to predict the temperature-pressure-concentration relations for R-410A/POE oil mixtures at equilibrium. In the R-410A/POE32 oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 2.00% and in the R-410a/POE46 oil mixture, that is 3.69%. Flory-Huggins theory is also used to predict refrigerant/oil mixture behavior. Miscibility for R-410A/POE32 oil mixture was observed all over the experimental conditions. Immiscibility for R-410A/POE46 oil mixture was observed at the low oil concentrations(10~30 wt%).

• 폴리머
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• 제24권4호
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• pp.469-476
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• 2000

아크릴 공중합체와 점착부여제와의 상용성을 점착제의 물성에 영향을 주었다. 특히 높은 분자량과 좁은 분자량 분포를 가진 아크릴 공중합체가 혼합된 점착제는 상용계에 한해서만 점착 부여제의 함량증가에 따른 체계적인 물성 향상을 보였으며 이들 두 성분간의 상용성을 확인하는 것은 점착제의 물성에 매우 중요하다는 것을 알게 되었다.

• 설비공학논문집
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• 제11권4호
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• pp.518-527
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• 1999

The solubility and miscibility measurement apparatus has been developed and used to obtain data for refrigerant/oil mixture. The solubility and miscibility data for R-134a/46 ISO VG Polyalkylen Glycol(PAG) oil mixture are obtained over the temperature range from -20 to 6$0^{\circ}C$ with a 1$0^{\circ}C$ interval and the oil concentration range from 0 to 90wt%. Using the experimental data, an empirical model is developed to predict the solubility relations for R-134a/PAG oil mixture at equilibrium. The average root-mean-square deviation between measured data and calculated results from the empirical model is 4.2%. Raoult's rule and Flory-Noggins theory are also used to predict mixture behavior. Immiscibility is observed for R-134a/46 ISO VG PAG oil mixture at low oil concentrations of 4.6, 10.1, and 20.4wt%.

• 폴리머
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• 제24권3호
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• pp.358-365
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• 2000

Miscibility itnd thermal behavior of blends of synthetic biodegradable aliphatic polyester (Bionolle) with poly(epichlorohydrin) (PECH) were investigated by a differential scanning calorimetry (DSC), a dynamic mechanical thermal analyzer (DMTA) and a rotational rheometer. Observed both single glass transition temperatures from the DSC in agreement with the Fox equation and single T$_{g}$ changes as a function of composition from the DMTA indicate that these blend mixtures are miscible. In addition, the miscibility of this blend system was also observed from the single curve of the Cole-Cole Plot of log G′($\omega$) vs. log C"($\omega$) from the dynamic test using a rotational rheometer. This was further verified from the cryogenically fractured surface of BDP/PECH blends by scanning electron microscopy.

• 대한화학회지
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• 제49권2호
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• pp.182-188
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• 2005

• Elastomers and Composites
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• 제46권2호
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• pp.152-157
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• 2011

NR/CR 블렌드에서 CR 함량이 가황 동력학과 혼용성에 미치는 영향을 물성은 물론이고 dynamic DSC와 TGA를 이용하여 연구하였다. 가황반응 시의 생성 활성화 에너지는 모든 시험편에 대하여 $77.5{\pm}2.5$ kcal/mol로써 일정한 값을 보여 주었으나 CR 조성비가 증가함에 따라 반응속도는 늦어지는 것으로 나타났다. DTG를 이용한 열분해 연구의 결과로서 NR과 CR 두 성분은 3%정도의 낮은 CR 조성비에서는 부분적인 상용성을 보이지만 21%정도의 높은 CR 조성비에서는 상용성이 없는 것으로 판단되었다. 이러한 상용성의 변화에 의한 결과로서 시험편의 영구압축줄음률은 CR 조성비에 비례하여 증가하는 것이 관찰되었으나, 인장강도에 대하여서는 CR 조성비가 증가할수록 인장강도는 직선적으로 떨어지는 현상을 나타내 었다.

• 폴리머
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• 제24권1호
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• pp.128-132
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• 2000

Polycaprolactone (PCL) 블록의 함량이 62.7 wt%인 PCL-폴리아미드 블록공중합체와 poly(vinyl chloride) (PVC)의 상용거동을 시차주사열량계로 열적 성질을 관찰하여 조사하고, 블렌드물의 인장물성을 측정하였다. PCL과 PVC 세그먼트는 상용성을 가졌으며, PVC의 함량이 많은 경우 PCL의 결정화가 방해받아 PCL과 PVC 세그먼트로 구성된 비결정성 균일상이 형성됨을 알 수 있었다. PCL/PVC 균일 비결정상과 폴리아미드의 결정상이 병존하는 경우 균일 비결정상의 유리전이온도와 결정상의 녹는점 사이의 온도 영역에서 블렌드물은 고무탄성을 가졌다.