• Title/Summary/Keyword: miscanthus ash

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Stabilization of Heavy Metal (Ni, Cr) in Soil Amended with Biomass Ash (바이오매스 회분 혼합에 따른 토양 내 중금속 (Ni, Cr) 안정화)

  • Kang, Ku;Park, Seong-Jik;Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.3
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    • pp.39-46
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    • 2016
  • This study investigated the potential use and the effectiveness of biomass ashes for the stabilization of heavy metals in soil through a series of experiments. The ashes used for the experiments were obtained from the gasification of biomass including miscanthus and woodchips. The amounts of nickel and chromium released from the soil and ash mixture were analyzed. Chemical analysis showed that the ash contained unburned carbon as well as silica and alkali metals. Miscanthus ashes have C (83.400 %) > Si (9.040 %) > K (3.180 %) > Ca (1.800 %), and woodchip ashes have C (93.800 %) > Ca (2.220 %) > Fe (1.370 %) > K (1.200 %). KSLT and TCLP test results implied that the heavy metal concentrations were below the environmental standards and would not impose the risks. The results also showed that Ni releases were more limited as more ashes were mixed with the soil due to the increases in exchangeable, carbonate, and oxide nikels. Both miscanthus and woodchip ahses were effective in stabilizing nickel and chromium through mixing with the soil. It could be seen that ashes produced from biomass gasification can be used to stabilize the heavy metals in soils.

Studies on the Relationship between Standing Crop of Miscanthus sinensis Grassland and Soil Morphological Characteristics (억새초지의 현존량과 토양의 형태적 특성에 관한 연구)

  • 박봉규
    • Journal of Plant Biology
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    • v.21 no.1_4
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    • pp.7-12
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    • 1978
  • The results of the relationship between standing crop of Miscanthus sinensis grassland and soil morphological characteristics are as follows. The Miscanthus sinensis grassland seems to grow well in volcainc ash soil. The depth of A layer was closely related to the standing crop of the Miscanthus sinensis grassland. The root systems of Miscanthus sinensis reached to its maximum in A layer. The root systems of Miscanthus sinensis showed its maximum at 20mm and below(soil hardness). The soil texture of A layer showed SL-SiL. The soil structure of A layer contained Massive-Small Granular. The soil colors of A layer expressed Dark Yellowish Orange-Brownish Black.

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Quality and Combustion Characteristics of Miscanthus Pellet for Bioenergy (바이오에너지용 억새 펠릿의 품질 및 연소 특성)

  • Moon, Youn-Ho;Lee, Ji-Eun;Yu, Gyeong-Dan;Cha, Young-Lok;Song, Yeon-Sang;Lee, Kyeong-Bo
    • Clean Technology
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    • v.22 no.4
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    • pp.286-291
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    • 2016
  • In this study we made fuel pellet from miscanthus biomass and investigated changes of physiological characteristics and electricity consumption of pelletizing process in comparison with fuel pellet made of pine sawdust. We also examined combustion characteristics including ash content and clinker forming ratio with fuel pellet made of mixing with micanthus biomass and lime powder. Bulk density of ground-miscanthus and pine sawdust were $158g\;L^{-1}$ and $187g\;L^{-1}$, respectively. Bulk density of ground miscanthus was lower than that of pine sawdust, but increased to $653g\;L^{-1}$ after pelletizing, which was similar to $656g\;L^{-1}$ of pine sawdust pellet. Moisture content in raw miscanthus and ground miscanthus were 17.0% and 11.8%, respectively. Moisture content in ground miscanthus was similar to that of pine saw dust and decreased to 6.73% after pelletizing, which was 7.7% lower than that of pine sawdust pellet. Although $27kWh\;ton^{-1}$ were required for compaction press that was an additional process in miscanthus pelleitizing, total required electricity was $193kWh\;ton^{-1}$ which was similar to $195kWh\;ton^{-1}$ of pine sawdust pellet pelleitizing. Pellet durability and pelletizing ratio of miscanthus were 98.0% and 99.7%, respectively, which were similar to 98.1% and 99.4% of pine sawdust pellet. When lime mixing ratio increased, ash melting degree and clinker forming ratio of miscanthus pellet increased. While higher heating value and clinker forming ratio of miscanthus pellet decreased.

Soil Neutralizer Selection for Phytostabilzation Using Miscanthus sinensis Anderss. in Heavy Metal Contaminated Soil of Abandoned Metal Mine (폐금속광산 중금속오염토양에서 억새를 이용한 식물안정화공법을 위한 토양개량제 선정)

  • Jung, Mun Ho;Ji, Won Hyun;Lee, Jin Soo;Yang, In Jae
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.517-528
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    • 2020
  • The objectives of this study were to select optimal soil amendments through analysis of heavy metal availability in soil and uptake to Miscanthus sinensis Anderss. for phytostablization in heavy metal contaminated soil of abandoned metal mine. M. sinensis was cultivated for 6 months at contaminated soil with several soil treatments (bottom ash 1 and 2%, fly ash 1 and 2%, waste lime+oyster 1 and 2%, acid mine drainage sludge (AMDS) 10 and 20%, compost 3.4%, and control). The analysis results of heavy metal concentrations in the soil by Mehlich-3 mehthod, growth and heavy metal concentrations of M. sinensis showed that AMDS 20% was more effective than other amendments for phytostablization, and AMDS 10% showed second effectiveness. Waste lime+oyster, bottom ash and fly ash were also improved compared to control. Mobility of some heavy metal was increased by treatments. Therefore, it is necessary of preparatory investigation of soil condition to select soil amendment to apply on-site phytostablization.

Combined Aqueous Ammonia-Dilute Sulfuric Acid Pretreatment of Miscanthus for Bioethanol Production (바이오에탄올 제조를 위한 억새의 암모니아-희황산 복합 전처리)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Ahn, Seung-Hyun;Cha, Young-Lok;Kim, Jung Kon;An, Gi Hong;Suh, Sae-Jung;Park, Don-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.179.1-179.1
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    • 2011
  • Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. The objective of this study was to evaluate the effect of combined aqueous ammonia-dilute sulfuric acid treatment on cellulosic biomass. Miscanthus was pretreated using aqueous ammonia and dilute sulfuric acid solution under high temperature and pressure conditions to be converted into bioethanol. Aqueous ammonia treatment was performed with 15 %(w/w) ammonia solution at $150^{\circ}C$ of reaction temperature and 20 minutes of reaction time. And then, dilute sulfuric acid treatment was performed with 1.0 %(w/w) sulfuric acid solution at $150^{\circ}C$ of reaction temperature and 10 minutes of reaction time. The compositional variations of this combined aqueous ammonia-dilute sulfuric acid treatment resulted in 68.0 % of cellulose recovery and 95.7 % of hemicellulose, 81.3 % of lignin, 89.1 % of ash removal respectively. The enzymatic digestibility of 90.5 % was recorded in the combined pretreated Miscanthus sample and it was 14.7 times higher than the untreated sample. The ethanol yield in the Simultaneous Saccharification and Fermentation was 90.4 % of maximum theoretical yield based on cellulose content of the combined pretreated sample and it was about 98 % compared to the ${\alpha}$-cellulose ethanol yield.

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The Energy Flow and Mineral Cycles In a Zoysia japonica and a Miscanthus sinensis Ecosystem on Mt. Kwanak 4. The Cycles of Phosphorus (관악산의 잔디와 억새 생태계에 있어서 에너지의 흐름과 무기물의 순환 4.인의 순환)

  • 장남기;김정석;강경미
    • Asian Journal of Turfgrass Science
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    • v.9 no.4
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    • pp.275-284
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    • 1995
  • In this investigation, the accumulation mineralization and annual cycle of organic P has been studied in grassland ecosysterns of a Z japonica grassland and a M sinensis grassland on Mt. Kwanak. The basic models of the accumulation and mineralization for ash components of a grass-litter have been presented as the equations (1), (2), and (3). The equations (7)~(10) for organic P are derived from these basic concepts. There was a highty significant relationship between organic matter and organic P. The estimates between organic matter and organic P correlated very high significance. The parameter factors k or k' of mineralization of organic P for the Z. japonica and M sinensis asslands were k=0.412 or k'=0.292 and k=0.224 or k'=0.183, respectively. The time required for a cycle to be completed from organic P to inorganic P of 50, 95 and 99 % are 3.9, 16.7 and 27.8 years in the Z. japonica grassland and 4.1, 17.7 and 29.4 years in the M sinensis grassland. The annual P cycle formulae for mineralization were based on the equations (5), (11) and (12). Annual yields of mineralization for organic P in the steady state grasslands of Z. japonica and M sinensis were 0.407 and 0.504g /$m^2$, respectively.

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Optimization of KOH pretreatment conditions from Miscanthus using high temperature and extrusion system (고온 압출식 반응시스템을 이용한 억새 바이오매스의 KOH 전처리조건 최적화)

  • Cha, Young-Lok;Park, Sung-Min;Moon, Youn-Ho;Kim, Kwang-Soo;Lee, Ji-Eun;Kwon, Da-Eun;Kang, Yong-Gu
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1243-1252
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    • 2019
  • The purpose of this study is to investigate the optimum conditions of biomass pretreatment with potassium hydroxide (KOH) for efficient utilization of cellulose, hemicellulose and lignin from Miscanthus. The optimization of variables was performed by response surface methodology (RSM). The variation ranges of the parameters for the RSM were potassium hydroxide 0.2~0.8 M, reaction temperature 110~190℃ and reaction time 10~90 min. The optimum conditions of alkali pretreatment from Miscanthus were determined as follows: concentration of KOH 0.47 M, reaction temperature 134℃ and reaction time 65 min. At the optimum conditions, the yield of cellulose from the solid fraction after pretreatment was predicted to be 95% by model prediction. Finally, 66.1 ± 1.1% of cellulose were obtained by verification experiment under the optimum conditions. The order contents of solid extraction were hemicellulose 26.4 ± 0.4%, lignin 3.7 ± 0.1% and ash 0.5 ± 0.04%. The yield of ethanol concentration of 96% was obtained using separated saccharification and fermentation.

Evaluation of Primary Thermal Degradation Feature of M. sacchariflorus After Removing Inorganic Compounds Using Distilled Water (증류수를 이용한 거대억새 내 무기성분 제거 효과 및 열분해 특성 변화 관찰)

  • Kim, Jae-Young;Oh, Shinyoung;Hwang, Hyewon;Moon, Yoonho;Choi, Joon Weon
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.276-286
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    • 2013
  • The goal of this study was to investigate change of thermal decomposition feature of miscanthus (Miscanthus sacchariflorus) after removal of inorganic constituents using distilled water (D.I-w; 30, 60 and $90^{\circ}C$). The carbon content was increased whereas the oxygen content was decreased with the temperature of D.I-w treatment. Moreover, ash content was slightly decreased from 4.6% of control to 3.2% of $90^{\circ}C$ D.I-w treated sample. Results of total monomeric sugar contents and X-ray diffraction (XRD) analysis showed that structural changes of cellulose/hemicellulose regions did not occurr during D.I-w treatment. Results of inductively coupled plasma emission spectrometer (ICP-ES) showed that miscanthus has the largest amount of inorganic constituents such as potassium (5,644 ppm), phosphorus (3,995 ppm), magnesium (1,403 ppm) and calcium (711 ppm). Thermogravimetric analysis (TGA) confirmed that the yield of char slightly decreased whereas the yield of volatiles increased with increasing D.I-w treatment temperature. In addition, differential thermogravimetric analysis (DTGA) indicated that the maximum decomposition rate ($V_M$) and temperature ($T_M$) corresponding to VM were varied from $0.82%/^{\circ}C$, $360.60^{\circ}C$ of control to $1.17%/^{\circ}C$, $362.62^{\circ}C$ of $90^{\circ}C$-D.I-w treated sample.

Reclamation of the Closed/Abandoned Coal Mine Overburden Using Lime wastes from Soda Ash Production (부산석회를 활용한 휴ㆍ폐 석탄광산 폐기물의 안정화 및 식생복원)

  • 김휘중;양재의;옥용식;유경열;박병길;이재영;전상호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.37-47
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    • 2004
  • In Korea, over three hundreds of the coal mines were closed or abandoned due to the depression of the mining industry since the late 1980s. Many of them locate in the steep mountain valleys and the coal mine wastes had been disposed without a proper treatment From these mines, enormous amounts of coal mine overburdens have been abandoned in the slopes and the ample amounts of acid mine drainage (AMD) from either portal or overburdens have been discharging directly to the streams, causing the detrimental effects on soil and water qualities. Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing the vegetation alleviate the environmental problems caused by the closed coal mines. The percentages of the grass distribution ratio (%) and the surface coverage ($\textrm{cm}^2$) in each treatment plot were determined during June to August after seed spraying grasses such as orchard grass (Dactylis glomerata L), Kentucky Bluegrass (Poa pratensis L.) and Eulalia (Miscanthus sinensis Anderss) at the end of May. The grasses covered only 15.5 % of the coal overburden plot at the early stage but the coverage was increased with time to 33% in August. Growth of such grasses was enhanced with the combined treatments of lime waste and topsoil resulting in the increased surface coverage by the grasses. The Increment of the surface coverage from June to August was higher with lime waste treatments. The distribution percentages and surface coverage were highest when the lime wastes were treated at 25 % of the lime requirement. This might be related with the high salt contents in the hire wastes. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden and introducing the re-vegetation. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The combined treatment of lime wastes and topsoil was recommended for re-vegetation in the coal overburden slopes. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

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The Effects of Burning on Composition and Productivity of Grasslands (초지의 구조 및 생산성에 미치는 산불의 영향)

  • 강상준
    • Journal of Plant Biology
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    • v.14 no.3
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    • pp.36-42
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    • 1971
  • The effects of irregular burning of vegetation by man were studied in relation to composition and productivity in a non-agricultural montane grassland in the Chongsun area, Kangwon-Do, Korea. The floristic composition in all study area includes 38 species. Three of the stations are dominated by Arundinella hirta and one is dominated by Miscanthus sinensis. The standing crop of the first station, which was fired in early spring, 1970, was 358.7g/$m^2$ to 497.5g/$m^2$; that of the second station, fired in late 1969 was 351. 5g/$m^2$; the third station, fired sometime in 1968, had a standing crop of 314.5g/$m^2$ to 397.1/$m^2$; the fourth station, having had no recent fires, had a standing crop of 370.0g/$m^2$ to 448.0g/$m^2$. The daily productivity shows a maximum of 6.03g/$m^2$ in the first station, and a minimum of 0.85g/$m^2$ in the fourth station. The productivity of grassland in the study area is at a maximum during July and August because of much precipitation, and decreases rapidly in the months to follow. The productive structure of the first and fourth stations is shown in Fig. 2 and 3. At the first station the maximum height attained by the plants was 180cm. In the height range of 50cm to 100cm there was a maximum of assimilative organs (5.6g/0.25$m^2$$\times$10cm), while in the height range below 50cm there was a maximum of non-assimilative organs (13.0g/0.25$m^2$$\times$10cm). At the fourth station, which has not been fired recently, the maximum height reached by the plants was commonly below 100cm. The assimilative organs showed a maximum abundance in the height range of 40cm to 50cm (4.5g/0.25$m^2$$\times$10cm). while the non-assimilative organs showed their greated abundance in the height range below 10cm (6.0g/0.25$m^2$$\times$10cm). There was a direct relationship between daily productivity and organic matter, available phosphorous, exchangeable calcium and potassium. It appears that the nutrients provided by the ash created in the firing of the study can be an important factor in the productivity of these grasslands.

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