• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2005년도 춘계학술발표회
• /
• pp.309-310
• /
• 2005

Some minor elements(Al, B, Ba, Ca, Cd, Co, Cr, Cu, Gd, Mg, Mn, Mo, Nd, Ni, P, Pb, Si, Sn, Sr, Ti, V, Yb, Zn and Zr) in iron compounds such as the S/G sludge of a power plant were separated from iron by anionic and cationic exchange methods. If a ICP-AES or AAS determination follows this method, minor elements of more than 2 or 20 ppm of Fe can be determined with an error less than 20% except Sn and Mo. Alkaline elements were excluded from this study since they can be easily recovered from an anionic exchange. Application to real sludge samples is ongoing.

• 한국주조공학회지
• /
• 제24권5호
• /
• pp.295-303
• /
• 2004

The effects of three minor elements, S, Ce and Bi, on the inoculation ability and fading behavior of 1.0 wt%Ba-Fe-Si were investigated through thermal analysis. The performance of 1.0 wt%Ba-Fe-Si inoculant was better and more consistant at the high temperature range of $1,450{\sim}1,500^{\circ}C$ than that of low one of $1,300{\sim}1,400^{\circ}C$. That was improved with individual addition of three minor elements. The optimum amount of addition was 1.0% of the weight of inoculant added, respectively. That was improved also by the simultaneous addition of two or three kinds of minor elements. Even though worse with the addition of two kinds of them simultaneously than with individual addition, that was improved with the simultaneous addition of all three kinds over that with the individual one.

• 분석과학
• /
• 제16권5호
• /
• pp.358-367
• /
• 2003

이 연구는 먼저 침전물 속에 major 원소 (Al, Ca, K, Fe, Mg)를 측정하기위해 ICP-MS를 이용하여 분석방법을 개발하였다. Cool ICP-MS로 major원소를 분석한 결과 Normal ICP-MS보다 더 좋은 분석 결과를 얻었다. 또한 그 결과를 NAA의한 분석 결과와 비교해 보았다. NAA는 고체시료의 비파괴 미량분석법이며 침전물 속에 major원소들에 대한 측정 결과는 ICP-MS보다 더 좋은 결과를 얻었다. 또한 침전물 속에 minor 원소 (Cr, Ce, U, Co, Pb, As, Se)를 측정하기 위해 ICP-MS를 이용하여 분석방법을 개발하였다. 표준 검정곡선으로 분석한 결과 모체방해효과 때문에 정확도가 좋지 않았다. 그래서 ICP-MS를 이용하여 내부표준물법으로 minor 원소들을 분석했을 때 결과값이 향상됨을 알 수 있었다. 그 결과를 NAA분석법과 비교해도 ICP-MS를 이용한 방법이 더 좋은 결과였음을 알 수 있었다. 두 가지의 분석방법은 침전물 속에 존재하는 minor 원소를 충분히 측정할 수 있다. 그러므로 NAA 분석법이 모체가 복잡한 환경시료를 분석하는데 중요한 역할을 하며, ICP-MS 또한 NAA 분석법으로는 분석 할 수 없는 납을 검출할 수 있기 때문에 환경시료를 분석하는데 두 분석법은 상호 보완할 수 있는 중요한 분석법이다.

• 보존과학회지
• /
• 제16권
• /
• pp.89-103
• /
• 2004

우리나라 구석기 및 신석기 유적에서 출토된 흑요석 그리고 백두산과 일본 Kyushu지방에서 입수된 흑요석 원석 등 총 64점에 대하여 주요성분, 미량성분 및 자기적 특성을 이용하여 산지별로 분류하였다. 주요성분 중 $Al_2O_3,\;CaO,\;Na_2O+K_2O$의 농도값을 사용하여 흑요석을 분류한 결과 대부분의 흑요석이 Subalkaline 계열이었다. 또한 흑요석을 주요성분 및 미량성분 함량을 사용한 통계적 분류 결과 세 개의 그룹을 형성하였다. 이러한 결과는 각 그룹간의 상관관계가 없으며 산지가 다름을 의미한다. 자기적 특성을 이용한 산지분류에서는 각 지역별로 정확하게 그룹을 이루지 않았으나, 대자율과 포화등온잔류자화의 이 변량분석에서는 주요성분 및 미량성분을 이용한 산지분류와 유사한 결과를 얻었다.

• 자원환경지질
• /
• 제30권6호
• /
• pp.553-566
• /
• 1997

Origin, behavior and enrichment of environmental toxic elements from the Deokpyeong area were investigated on the basis of major, trace and rare earth element geochemistry. Coaly metapelites of the Deokpyeong area are subdivided into grey phyllite, dark grey phyllite, coaly slate and black slate, which are interbedded along the Ogcheon Supergroup. The coaly slate had been mined for coal, but mining is closed. The coaly and black slates are lower contents of $SiO_2$ and $Al_2O_3$, and higher contents of LOI, CaO, $Na_2O$ and BaO as compared with the phyllitic rocks. Rare earth elements are highly enriched in the coaly and black slate. Average compositions (ppm) of minor and/or environmental toxic elements in the coaly and black slate are revealed as As=127, Ba=30,163, Cd=18, Cr=740, Cu=84, Mo=378, Pb=43, Sb=12, Se=44, U=144, V=8,147 and Zn=292, which are extremely high concentrations than those in the NASC compositions. Major elements (average enrichment index; 5.34) in the coaly metapelites are mostly depleted, excepting $P_2O_5$ and BaO, normalized by NASC. Rare earth elements (average enrichment index; 1.48) are enriched in the coaly slate. On the basis of NASC, minor and/or environmental toxic elements in the coaly metapelites were strongly enriched of all the elements with the exception of Co, Cs, Ni and Sr. Average enrichment index of trace elements in coaly metapelite is 31.51 (coaly slate; 51.94 and black slate; 15.46). Especially, enrichment index of potentially toxic elements (As, Ba, Cr, Cu, Mo, Ni, Sb, Se, U, V and Zn) of the rock is 46.10 (grey phyllite; 7.15, dark grey phyllite; 4.77, coaly slate; 88.96 and black slate; 22.11). These coal formations were deposited in basin of boundary between terrestrial and marine environments deduced to carbon, sulfur (C/S=2.2 to 275.7), trace and rare earth elements characteristics. Irregular behavior and dispersion between major, minor and rare earth elements of those metapelites indicates a variable source materials, incomplete mixing of differential source and/or reequilibrium of diagenesis and metamorphism.

• 자원환경지질
• /
• 제31권2호
• /
• pp.111-125
• /
• 1998

Dispersion, migration and enrichment of environmental toxic elements from the Samkwang Au-Ag mine area were investigated based upon major, minor and rare earth element geochemistry. The Samkwang mine area composed mainly of Precambrian granitic gneiss. The mine had been mined for gold and silver, but closed in 1996. According to the X-ray powder diffraction, mineral composition of stream sediments and soils were partly variable mineralogy, which are composed of quartz, orthoclase, plagioclase, amphibole, muscovite, biotite and chlorite, respectively. Major element variations of the host granitic gneiss, stream sediments and soils of mining and non-mining drainage, indicate that those compositions are decrese $Al_2O_3$, $Fe_2O_3$, MgO, $TiO_2$, $P_2O_5$ and LOI with increasing $SiO_2$ respectively. Average compositional ranges (ppm) of minor and/or environmental toxic elements within those samples are revealed as As=<2-4500, Cd=<1-24, Cu=6-117, Sb=1-29, Pb=17-1377 and Zn=32-938, which are extremely high concentrations of sediments from the mining drainage (As=2006, Cd=l1, Cu=71, Pb=587 and Zn=481 ppm, respectively) than concentrations of the other samples and host granitic gneiss. Major elements (average enrichment index=6.53) in all samples are mostly enriched, excepting $SiO_2$, $Na_2O$ and $K_2O$, normalized by composition of host granitic gneiss. Rare earth element (average enrichment index=2.34) are enriched with the sediments from the mining drainage. Minor and/or environmental toxic elements within all samples on the basis of host rock were strongly enriched of all elements (especially As, Br, Cu, Pb and Zn), excepting Ba, Cr, Rb and Sr. Average enrichment index of trace elements in all samples is 15.55 (sediments of mining drainage=37.33). Potentially toxic elements (As, Cd, Cr, Cu, Ni, Pb, and Zn) of the samples revealed that average enrichment index is 46.10 (sediments of mining drainage=80.20, sediments of nonmining drainage=5.35, sediments of confluent drainage=20.22, subsurface soils of mining drainage=7.97 and subsurface soils of non-mining drainage=4.15). Sediments and soils of highly concentrated toxic elements are contained some pyrite, arsenopyrite, sphalerite, galena and goethite.

• 한국문화재보존과학회:학술대회논문집
• /
• 한국문화재보존과학회 2005년도 제22회 학술대회 발표 논문집
• /
• pp.268-271
• /
• 2005

Sixty-four obsidian artifacts found in the Korean Peninsula have been characterised by a study of their minor elements and Sr isotope ratio. The artifacts are from the following locations: Yondaedo Island; Yokjido Island; Sangnodaedo Island, Tongyeong, Gyeongnam; Dongsamdong, Busan; Songdo Island, Yeosu, Jeonnam; Suyanggae, Danyang, Chungbuk; Sangmuyongri, Yanggu, Gangwondo; Paektusan Mountain; Kyushu region, Japan. The study of minor elements and Sr isotope ratio recognised three distinct major groups. This result suggests that there are no correlations among the three groups whose provenances are different. But as a result of classification using Sr isotope ratio, obsidian artifacts found in the southern part of the Korean Peninsula classified two groups within C group. This research will furnish scientific datum to be able to mutual comparison of obsidians excavated from other site.

• 기술혁신학회지
• /
• 제8권3호
• /
• pp.1175-1198
• /
• 2005

The objective of the study is to verify the relationship between technology valuation indexes and corporate's performance in ventures by business operating periods. The result of the study is expected to be useful in loan evaluation, investment decision, internal management decision making and business improvement. The results of study is as follows. First, in early stage ventures, we find that three major valuation index(technology feasibility, economic efficiency, productivity) are significant ex-ante variables which are discriminating between firms' going concern and firms' failure. Second, in growth stage ventures, we find that three major valuation index(business feasibility, general marketability, technology marketability) are significant ex-ante variables which are discriminating between firms' going concern and firms' failure. Third, in early stage ventures, we find that at least thirty-eight minor valuation index elements are significant ex-ante variables which are discriminating between firms' going concern and firms' failure and in growth stage ventures, thirty-one minor valuation index elements are significant in various analysis' results.

• 생물환경조절학회지
• /
• 제5권1호
• /
• pp.71-78
• /
• 1996

좀부추의 생육에 적합한 광환경을 구명하기 위하여 여러 가지 칼라 필름을 이용하여 광투과특성, 생장특성, 무기성분과 엽록소 함량을 조사하였던 바 그 결과를 요약하면 다음과 같다- 칼라 필름의 종류에 따른 광투과 특성에서 광질은 대조구와 투명 필름의 경우 광의 파장 별 선택적인 차단은 없었지만 기타 필름은 선택적으로 감소 또는 차단되었으며, 광량은 대조구의 광투과량을 100으로 볼 때 투명 필름이 76.5%로써 가장 높았고, 녹색 필름은 13.5%로써 가장 낮았다. 생육특성은 투명색, 황색, 핑크색 필름이 양호한 반면 녹색과 청색 필름은 저조하였다. 엽록소 함량은 청색 필름에서 0.27mg/g으로써 가장 높았지만, 황색필름은 0.16mg/g으로써 가장 낮았고, 무기 성분 함량은 녹색 필름이 질소, 인산 칼리, 칼슘, 마그네슘에서 가장 높았지만, 주황색 필름은 인산, 칼륨, 핑크색 필름은 질소, 칼리, 마그네슘에서 가장 낮았다.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
• /
• pp.752-756
• /
• 2002

Variable weld bead penetrations related to the base metal chemistry of stainless steels in GTA welding have been under constant investigations due to their industrial implications. It has been proposed that among other elements, the sulfur content of steels determines the weld pool geometry, particularly its penetration. It is suggested that the surface tension temperature gradient of steels becomes positive with appropriate dosing in sulfur and results in inward melt flow, propitious for deeper welds. However, the chemistry of industrial steels is complex due to the presence of multiple minor elements either deliberately added or remnant impurity traces. With this in view, investigations on 41 austenitic and nine martensitic stainless steels were carried to see if there existed any possible relation between the weld profile and some of the designated elements. The results suggest no direct correlation between sulfur or any other major or trace element and weld penetration. At first glance the results are contradictory to what is often asserted.