• Title/Summary/Keyword: mineral source

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Geochemical Exploration for Tri Le REE Occurrence in Nghe An Province within Northern Vietnam (베트남 북부 네안성 칠레 희토류 산출지의 지구화학탐사)

  • Heo, Chul-Ho;Ho, Tien Chung;Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.47 no.2
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    • pp.147-168
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    • 2014
  • The soil geochemical exploration was carried out targeting around Tri Le area far from about 30 km with northwestern direction from Que Phong within Nghe An province. The interval of sampling are horizontal 200 m interval with 23 line and longitudinal 300 m with 10 line, resulting in 228 soil samples. Based on the result of the soil geochemical exploration, the detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 75 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and granitic gneiss intruding Ban Khang formation comprising of quartz schist and marble. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite and xenotime to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.5 times). As a analysis result with ICP-MS on the soil samples from the soil detailed pit survey, we only identified outcrop considering as economic weathered granite body at the grid point 1-10 pit among 7 pits. As a synthetic consideration on the soil geochemical exploration and detailed pit survey, we tentatively designated Tri Le area as no promising target for REE. In 2014, we have the plan to carry out the soil geochemical exploration targeting the extended economic REE ore body in Quy Chau as project area from 2011 to 2012.

The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea (한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.18 no.1
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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Hydrochemical and Isotopic Properties of the Thermal Spring Water from Chonju Jukrim District, Korea (전주 죽림지역 온천수의 화학적 및 동위원소적 특성)

  • Na, Choon-Ki;Lee, Mu-Seong;Lee, In-Sung;Park, Hee-Youl;Kim, Oak-Bae
    • Economic and Environmental Geology
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    • v.30 no.1
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    • pp.25-33
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    • 1997
  • The purpose of this study is to examine the feasibility of using stable isotopes as a hydrologic tracer, and to elucidate the groundwater circulation system and the source of S component dissolved in thermal water of the Chonju Jukrim thermal spring district based on the O, H and S isotopic variabilities of environmental materials including bedrock, rainwater, surface water, shallow subsurface water and thermal spring water. The ${\delta}^{18}O$ and ${\delta}D$ of subsurface waters and surface water show highly restricted range and plotted on the same meteoric water line as a ${\delta}D=8{\delta}^{18}O+19$ line, and derivate from the mean annual isotopic composition of the rain water but are analogous to those of rain waters precipitated during winter season, indicating that ground waters are originated from the meteoric water and are strongly affected by the seasonal variation of air mass. Thermal spring waters are more depleted in ${\delta}^{18}O$ and ${\delta}D$ than those of shallow ground water and surface water. It can be explained by the difference of recharge area. The hydrochemical properties of subsurface waters and surface water devide into two groups: $Ca(HCO_3)_2$ type including shallow subsurface water and surface water, and $Na(HCO_3)$ type of thermal spring waters. The ${\delta}^{34}S$ values of thermal spring water show very high positive and quitely distinct from those of shallow subsurface water and surface water that are similar to those of bed rocks, indicating that sulfate dissolved in thermal spring water has not only a terrigenic origin, but also originates partially from the foreign source containing very heavy ${\delta}^{34}S$ component such as an ancient sea water. However, the presence of $H_2S$ can not be ignore the affact of the isotopic fractionation to explaine the heavy ${\delta}^{34}S$ of thermal spring water. Overall, the Oxygen and Hydrogen stable isotopes can identify the source and the circulation system of the natural waters and the S-isotopes can provide a crucial clue on tracing the dissolved material transports in the circulation system of the natural water.

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Thermal Conductivity Measurement of Rock Cores from Ulleung Island Using PEDB System at Room Temperature (상온 환경에서 PEDB를 이용한 울릉도 시추코어의 열전도도 예비 측정)

  • Lee, Sang Kyu;Lee, Tae Jong
    • Geophysics and Geophysical Exploration
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    • v.19 no.3
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    • pp.121-130
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    • 2016
  • Several factors are discussed that should be considered in measuring thermal conductivity of rock cores with a PEDB (potable electronic divided bar) system, which is relatively accurate and easy to operate, and can measure the thermal conductivity of rock cores for various diameters. Then the system is applied to measure thermal conductivity of 70 rock cores from Ulleung Island. Air temperature affects most on the thermal conductivity measurements, so that it is very important to minimize the temperature change during the measurement. Other factors such as the temperature of heat source, averaging time window on the thermal conductivity measurements do not affect much compared to air temperature. Slightly higher thermal conductivity is measured when using the thermal contact paste between the sample and heat source or heat sink. Especially, rock cores with irregular surface showed bigger difference. Repeatability showed less than ${\pm}0.3%$ for standard samples and less than ${\pm}4%$ for rock samples, respectively, when the room temperature changes within $1^{\circ}C$ during the measurements. Thermal conductivity of the rock cores from Ulleung Island roughly increases as depth increases but does not show any dependency on the rock types.

Analysis on Characteristics of Pigments Manufactured with Various Neorok Produced from Mt. Gwangjeongsan, Pohang (포항 광정산 일대 산출 뇌록으로 제조한 안료의 특성 분석)

  • Mun, Seong Woo;Kang, Young Seok;Kim, Ji Sun;Hwang, Ga-Hyun;Park, Ju Hyun;Lee, Sun Myung;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.533-540
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    • 2020
  • Mt. Neoseongsan (NSS) is the only natural Neorok source in Korea. The geological, historical, and cultural values of NSS were recognized in 2013, and NSS has since been designated and maintained as a natural monument (No. 547), which has restricted the research and utilization of NSS Neorok. The limited NSS Neorok supply has hindered the restoration research of traditional pigments. Recently, a large amount of Neorok has been mined from Mt. Gwangeongsan (GJS) and is expected to be the main supply source of Neorok for restoring traditional pigments. Therefore, this study analyzed the characteristics of NSS- and GJS-Neorok-based pigments to evaluate the feasibility of substituting GJS Neorok for NSS Neorok in pigments. The NSS Neorok was mostly comprised of celadonite, whereas the GJS Neorok included minerals containing glassy phases such as celadonite, cristobalite, tridymite, etc. Because both Neorok samples were vitrified under identical conditions, the GJS Neorok grains were larger than the NSS Neorok ones. The GJS Neorok pigment showed that the chromaticity, grain size, oil absorption, and stability varied depending on the mineral types and contents. In particular, GJS-2 and NSS Neorok showed similar mineral compositions, physical properties, and stabilities, suggesting that GJS-2 can be substituted for NSS Neorok, which has been difficult to source and utilize ever since NSS was designated as a natural monument.

A brief review on Oyster shells origin and sedimentary evolution for the formation of limestone

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • Journal of Energy Engineering
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    • v.27 no.3
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    • pp.48-56
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    • 2018
  • The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.

The Development Prospect for Gas Hydrate as an Energy Source (에너지원으로서의 가스 하이드레이트 개발 전망)

  • Baek Youngsoon;Lee Jeonghwan;Choi Yangmi;Park Seoungmin
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.652-655
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    • 2005
  • Considering the fact that more than $97\%$ of fossil energy resources such as oil and natural gas needed in Korea rely on import, primary concern of the national economy is to secure future energy sources. Gas hydrates. which is non-conventional types of natural gas, distribute worldwide, especially in marine and permafrost Gas hydrates draw great attention recently as a new clean energy resources substituting conventional oil gas due to its presumed huge amount of volume reaching 10 trillion tons of gas and environmentally friendly characteristics. Results of preliminary survey by Korea Gas Corporation (KOGAS) and Korea Institute of Geoscience and Mineral Resources (KIGAM) showed that gas hydrates can be present in deep sea over 1,000m water depth in the East Sea. Gas hydrates can contribute to the rapidly increasing consumption of natural gas in Korea and achieve the self-support target by 2010 with $30\%$ of total natural gas demand. This study presents the potentialities and development prospects of gas hydrate as a future energy source.

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Isolation and Identificatioh~ of a Phthalate Ester Degrading Bacterium and the Optimal Culture Conditions for Production of One Degrading Enzyme (프탈레이트 에스터 분해세균의 분리 및 분해효소의 최적 생성조건)

  • Kim, Byung-O;Kim, Ran-Sug;Jin, Ing-Nyol;Park, Wan
    • Microbiology and Biotechnology Letters
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    • v.18 no.6
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    • pp.553-559
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    • 1990
  • A strain degrading phthalate ester was isolated from a sludge of Taegu area and identified as a strain of Klebsiella. The optimum culture conditions for the protocatechuate dioxygenase production were also investigated. This strain produced the enzyme in question under the shaking cultivation at $30^{\circ}C$for the 48 hrs in the medium containing 0.1% protocatechuate as the sole carbon source, 0.1% ammonium sulfate and 0.1% yeast extract as the nitrogen source and mineral salt mixture of magnesium sulfate, sodium chloride, calcium chloride, ferric chloride, manganese sulfate, zinc sulfate and cupric sulfate. This enzyme was intracellularl j localized and probably linked to cell membrane, and induced by protocatechuate.

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Nutritional Evaluation of Imported Organic Feeds and Locally Produced Agricultural By-products for Organic Ruminant Farming (유기 반추동물 전용 수입산 유기사료 및 국내산 유기 부산물의 사료적 가치 평가)

  • Park, Joong-Kook;Kim, Chang-Hyun
    • Korean Journal of Organic Agriculture
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    • v.19 no.4
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    • pp.513-528
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    • 2011
  • This study was conducted to evaluate the nutritional value of locally produced organic agricultural by-products to substitute imported organic feeds for organic ruminant farming. Imported organic feeds (corn grain, soybean meal, soybean seed, oat grain, barley grain, wheat grain, buckwheat, sunflower seed meal) and byproducts (rice bran, grape seed meal, rice straw, soybean hull, soybean curd, rice hull, green kernel rice, and crushed rice grain) were analyzed for chemical composition and NDF, ADF, mineral, and amino acid contents and anti-nutritional factors. Dry matter, NDF and ADF contents in organic feeds were higher than those in conventional feeds. Especially, the 9.65% fat content of organic soybean meal was 6 times higher than the 1.95% fat content of conventional soybean meal. Fat contents of rice bran, grape seed meal, green kernel rice, and crushed rice grain were 25.66, 6.09, 3.57 and 1.59%, respectively. Protein contents of soybean hull and soybean curd were 14.68 and 19.87%, respectively, which are highest among organic by-products. Levels of aflatoxin in all feeds were below the safety level. Therefore, organic rice bran, green kernel rice and crushed rice as energy source, and soybean hull and soybean curd as protein source could partial replace imported feeds for organic ruminant farming.

Influence of Diet Induced Changes in Rumen Microbial Characteristics on Gas Production Kinetics of Straw Substrates In vitro

  • Srinivas, Bandla;Krishnamoorthy, U.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.7
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    • pp.990-996
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    • 2005
  • The effect of diets varying in level and source of nitrogen (N) and fermentable organic matter on dynamic characteristics of microbial populations in rumen liquor and their impact on substrate fermentation in vitro was studied. The diets tested were straw alone, straw+concentrate mixture and straw+urea molasses mineral block (UMMB) lick. The same diets were taken as substrates and tested on each inoculum collected from the diets. Diet had no effect on the amino acid (AA) composition of either bacteria or protozoa. Differences among the diets in intake, source of N and OM affected bacterial and protozoal characteristics in the rumen. Upper asymptote of gas production (Y$\alpha$) had a higher correlation with bacterial pool size and production rate than with protozoal pool size and production rate. Among the parameters of the gas production model, Y$\alpha$ and lag time in total gas has showed significant (p<0.01) correlation with bacterial characteristics. Though the rate constant of gas production significantly differed (p<0.01) between diet and type of straw, it was least influenced by the microbial characteristics. The regression coefficient of diet and type of straw for Y$\alpha$ indicated that the effect of diet on Y$\alpha$ was threefold higher than that of the straw. As microbial characteristics showed higher correlation with Y$\alpha$, and diet had more influence on the microbial characteristics, gas production on a straw diet could be used effectively to understand the microbial characteristics.