• 대한화학회지
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• 제55권3호
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• pp.364-372
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• 2011

다양한 억제제의 농도, 온도, 유속에서 중량 분석과 변전위 분극법을 이용하여 0.25 M 황산 용액상에 있는 연강철에 대한 imatinib mesylate (IMT)의 부식 억제를 연구하였다. 억제제의 농도가 증가함에 따라 억제 효과가 증가한다는 결과를 얻었다. 연강철 표면 위의 흡착 과정은 Langmuir 흡착 등온선을 따른다. 얻어진 흡착 깁스 자유 에너지의 값은 연강철 위의 IMT의 흡착 과정이 화학흡착이라는 것을 보여준다. 열역학 변수들이 계산되고, 논의되었다. IMT의 HOMO와 LUMO의 전자궤도 밀도 분포는 억제 메커니즘을 논의하는데 이용되었다. FT-IR 분광학과 SEM 이미지는 필름에 흡착된 표면을 분석하기 위해 사용되었다.

• Corrosion Science and Technology
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• 제18권5호
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• pp.155-167
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• 2019

In this study, two novel Schiff base compounds including (3-(4-Chlorophenyl isoxazole-5-yl) methanol and (3-(2,4 dichlorophenol isoxazole-5-yl) methanol as corrosion inhibitors for mild steel in 1 M hydrochloric acid solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and density functional theory (DFT) computations. The results showed that the corrosion inhibition efficiency (IE) is remarkably enhanced with the growing concentration of the Schiff base inhibitors. The results from Tafel polarization and EIS methods showed that IE decreases with gradual increments of temperature. This process can be attributed to the displacement of the adsorption/desorption balance and hence to the diminution of the level of a surface coating. Also, the adsorption of two inhibitors over mild steel followed the Langmuir adsorption isotherm. Too, the results of the scanning electron microscope (SEM) images showed that the Schiff base inhibitors form an excellent protective film over mild steel and verified the results by electrochemical techniques. Additionally, the results from the experimental and those from DFT computations are in excellent accordance.

• Corrosion Science and Technology
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• 제18권5호
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• pp.168-174
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• 2019

The sol-gel methodology has been applied successfully in the synthesis of a novel hybrid coating based on dimethoxymethyl-n-octadecylsilane precursor. The newly synthesized parent coating was functionalized further with two commercially-available corrosion-inhibitive pigments Moly-$white^{(R)}$ 101-ED and Hfucophos $Zapp^{(R)}$, applied to mild steel panels, and immersed continuously in 3.5% NaCl electrolytic solution for 288 h. The corrosion protection performance of the prepared functional coatings was evaluated using electrochemical impedance spectroscopy (EIS) and DC polarization techniques. An enhancement in the barrier properties has been revealed from the electrochemical characterization data of the hybrid films, in comparison with untreated mild steel substrates following long-term immersion in 3.5% NaCl. The corrosion resistance properties of the newly developed coatings over mild steel substrates found to be largely dependent on the type of the loaded inhibitive pigment in which the Moly-white inhibitor has a positive impact on the corrosion protection performance of the parent coating, while an opposite behavior was observed upon mixing the base polymeric matrix with the commercially-available Zapp corrosion inhibitor.

• Journal of Electrochemical Science and Technology
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• 제10권2호
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• pp.231-243
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• 2019

The methanolic extracts of the leaves and stem of the plant Lepidagathis keralensis were evaluated for anticorrosion behavior against mild steel in 1M HCl. Corrosion inhibition studies were done by gravimetric method, electrochemical impedance spectroscopy and potentiodynamic polarization methods. Surface morphology of mild steel in the presence and absence of inhibitors were studied using SEM analysis. UV-Vis studies were also done to evaluate the mechanism of inhibition. Both the extracts showed good inhibition efficiency which increased with increase in concentration of the inhibitor and decreased with increase in temperature. The mechanism of inhibition was explained by adsorption which obeyed Langmuir adsorption isotherm. Thermodynamic calculations revealed a combination of both physisorption and chemisorption of the inhibitor on the surface of mild steel. The extracts behaved as mixed type inhibitors as determined by polarization studies. Quantum chemical studies on Phenoxyethene, one of the major components in the leaf extract of the plant was also carried out to support the experimental results.

• Tribology and Lubricants
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• 제36권3호
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• pp.117-123
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• 2020

In this study, the effect of the pre-mild wear mode test condition on the subsequent severe wear behavior of carbon steel has been investigated when the wear mode is varied according to the sliding speed change during sliding contact. Two sliding speeds of 0.3 m/s and 3 m/s for the mild wear mode test have been chosen and a sliding speed of 1 m/s for the severe wear mode test. A mild wear mode test at two different sliding speeds has been carried out during the severe wear mode test and total sliding distance of the mild wear mode test has been changed at this time. As a result, it could be found that the wear rate of carbon steel under the severe wear mode test after performing a pre-mild wear mode test is significantly reduced, compared with that before performing. However, its wear rate was slightly higher than that under the mild wear mode test. Oxides produced during the pre-mild wear mode test have been found to play a significant role in reducing the wear rate under the subsequent severe wear mode test. In particular, it was found that the effect of a pre-mild wear mode test performed at the sliding speed of 3 m/s has more rapid and the reduction in the wear rate was greater than thst at the sliding speed of 0.3 m/s.

• Journal of Welding and Joining
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• 제9권4호
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• pp.69-74
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• 1991

The Plasma Arc Cutting Method using high density and hight temperature beam is well applicable to the cutting of the nonferrous metal (Al alloy ) and stainless steel which are unable to be cut by the use of the oxy-fuel gas. This study focalizes on the cutting phenomena of the plate of (mm) thickness, since the cutting phenomena of thick plates have been rather thoroughly studied. In this study the cutting groove, adhesive phenomena of dross, surface roughness were measured according to the variation of cutting speed and compared with the case of mild steel plates. The result showed that the kerf width variation of Al alloy was similar to the case of mild steel, while that of the stainless steel differed from the mild steel. In the adhesive phenomena of dross, 6(mm) thick plates of Al alloy showed a difference from those of thick plates, but the stainless steel was similar to thick plates. The surface roughness variation of Al alloy wias minimum at 67 cm/min, while that of stainless steel was at 30cm/min.

• 한국표면공학회지
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• 제25권4호
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• pp.161-164
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• 1992

Thermodynamic calculations were made to find an optimum condition of simultaneous chromizing and aluminizing of mild steel. Results of calculations showed that Cr-Al alloy powder should be used and the optimum composition was 90~95wt% Cr and 5~10wt% Al. Simultaneous chromizing and aluminizing of a mild steel was achieved using 95Cr-5Al wt% alloy powders as a masteralloy, NH4Cl as an activator at $1273^{\circ}$K under Ar atmosphere.

• Corrosion Science and Technology
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• 제4권6호
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• pp.231-235
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• 2005

The inhibitive effect of extracts of tamarind seeds and jackfruit seeds, curry leaves and henna leaves on corrosion of mild steel in 1M HCl solution have been studied by weight loss, potentiodynamic polarization and impedance measurements. Results obtained from the electrochemical techniques were in good agreement with weight loss results. From the weight loss data, the values of surface coverage ($\Theta$) and corrosion rate were calculated. The inhibition efficiency (IE) increased with increasing inhibitor concentration in 1M HCl solution. In all the cases the adsorption of the natural product extracts on the mild steel surface from 1M HCl follows the Langmuir adsorption isotherm relationship. Potentiodynamic polarization studies reveal the fact that all the four natural product extracts act as mixed type inhibitors. The decrease in the inhibition efficiency follows the order: Extracts of jackfruit seed>henna leaves>curry leaves>tamarind seed.

• Smart Structures and Systems
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• 제20권1호
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• pp.53-60
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• 2017

Reinforced concrete shear wall is one of the most common structural forms for high-rise buildings, and seismic energy dissipation techniques, which are effective means to control structural vibration response, are being increasingly used in engineering. Reinforced concrete-mild steel damper stiffness-tandem energy dissipation coupling beams are a new technology being gradually adopted by more construction projects since being proposed. Research on this technology is somewhat deficient, and this paper investigates design principles and methods for two types of mild steel dampers commonly used for energy dissipation coupling beams. Based on the conception design of R.C. shear wall structure and mechanics principle, the basic design theories and analytic expressions for the related optimization parameters of dampers at elastic stage, yield stage, and limit state are derived. The outcomes provide technical support and reference for application and promotion of reinforced concrete-mild steel damper stiffness-tandem energy dissipation coupling beam in engineering practice.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.377-382
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• 2004

The dynamic material characteristics on some mild steel sheets were observed. The dynamic tests were conducted on the ESH servo-hydraulic test machine. It was observed that the mechanical properties of mild steel are highly sensitive to the value of strain rate. The well known Cowper-Symonds constitutive equation was used to generalize the strain rate sensitivity effect. Modified constitutive equations were suggested to couple the strain hardening to the strain rate sensitivity. The dynamic stress-strain relationships for the mild steel sheets used in the present study were reasonably predicted using these modified constitutive equations.