• Title/Summary/Keyword: microstructure effect

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Development of slag based Shirasu geopolymer

  • Katpady, Dhruva Narayana;Takewaka, Koji;Yamaguchi, Toshinobu
    • Computers and Concrete
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    • v.20 no.1
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    • pp.77-84
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    • 2017
  • Shirasu, a pyroclastic flow deposit, showed considerable performance as aluminosilicate source in geopolymer, based on past research. However, the polymerization reactivity was somewhat lower compared to the traditional fly ash based geopolymer even though the long-term strength was fairly good. The present study concentrates on the development of higher initial strength performance of Shirasu based geopolymer by utilizing ground granulated blast furnace slag as an admixture. Mortars with various mix proportions were adopted to study the effect of parametric changes on strength development along with the addition of slag in different percentages. A combination of sodium hydroxide and sodium silicate was used as alkaline activators considering parameters like molar ratios of alkali to geopolymer water and silica to alkali molar ratio. The mortars were cured at elevated temperatures under different curing conditions to analyze the effect on strength development. Compressive strength test, mercury intrusion porosimetry and X-ray powder diffraction were carried out to assess the strength performance and microstructure of slag-Shirasu based geopolymer. Based on the experimental study, it was observed that the initial and long-term strength development of Slag-Shirasu geopolymer were improved by the addition of slag.

Fire resistance evaluation of fiber-reinforced cement composites using cellulose nanocrystals

  • Lee, Hyung-Joo;Kim, Seung-Ki;Lee, Heon-Seok;Kang, Yong-Hak;Kim, Woosuk;Kang, Thomas H.K.
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.311-320
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    • 2019
  • In this study, the effect of cellulose nanocrystals (CNCs) on the fire resistance properties of fiber-reinforced cement composites was investigated. The main variables were CNCs content (0.4, 0.8 and 1.2vol.% compared with cement), steel fiber ratio, and exposure temperature (100, 200, 400, 600 and 800℃). The fire resistance properties, i.e., residual compressive strength, flexural strength, and porosity, were evaluated in relation with the exposure temperature of the specimens. The CNCs suspensions were prepared to composited dispersion method of magnetic stirring and ultra-sonication. CNCs are effective for increasing the compressive strength at high temperatures but CNCs do not seem to have a significant effect on flexural reinforcement. Porosity test result showed CNCs reduce the non-hydration area inside the cement and promote hydration.

Effect of Rare Earth Elements on the Microstructures of Thin-Wall Ductile Iron Castings (희토류원소에 의한 박육구상흑연주철품의 조직변화)

  • Kim, Ji-Yeong;Choi, Jun-Oh;Park, Sung-Tak;Han, Yun-Sung;Choi, Chang-Ock
    • Journal of Korea Foundry Society
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    • v.23 no.4
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    • pp.187-194
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    • 2003
  • The effect of rare earth elements (R.E)(from 0.0 to 0.04%) on the microstructure formation and mechanical properties of thin-wall ductile iron castings were investigated. Tensile strength and hardness were decreased with an addition of up to 0.03% rare-earth elements. After addition of more than 0.03%, those were increased. Graphite nodule sizes were the finest, nodule count was the highst regardless of thickness and volume fraction of ferrite was the largest when that was 0.02%. However, the nodule count was decreased with increasing R.E. Futhermore. nodule size increased with increasing thickness and the volume fraction of ferrite decreased as that was increased. Nodularity was increased regardless of the thickness as that was increased. The castings of minium thickness up to 3 mm was possible without the formation of chill.

Highly Sensitive Flexible Organic Field-Effect Transistor Pressure Sensors Using Microstructured Ferroelectric Gate Dielectrics

  • Kim, Do-Il;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.277.2-277.2
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    • 2014
  • For next-generation electronic applications, human-machine interface devices have recently been demonstrated such as the wearable computer as well as the electronic skin (e-skin). For integration of those systems, it is essential to develop many kinds of components including displays, energy generators and sensors. In particular, flexible sensing devices to detect some stimuli like strain, pressure, light, temperature, gase and humidity have been investigated for last few decades. Among many condidates, a pressure sensing device based on organic field-effect transistors (OFETs) is one of interesting structure in flexible touch displays, bio-monitoring and e-skin because of their flexibility. In this study, we have investigated a flexible e-skin based on highly sensitive, pressure-responsive OFETs using microstructured ferroelectric gate dielectrics, which simulates both rapidly adapting (RA) and slowly adatping (SA) mechanoreceptors in human skin. In SA-type static pressure, furthermore, we also demonstrate that the FET array can detect thermal stimuli for thermoreception through decoupling of the input signals from simultaneously applied pressure. The microstructured highly crystalline poly(vinylidene fluoride-trifluoroethylene) possessing piezoelectric-pyroelectric properties in OFETs allowed monitoring RA- and SA-mode responses in dyanamic and static pressurizing conditions, which enables to apply the e-skin to bio-monitoring of human and robotics.

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Effect of Processing Method on Change of Water Soluble Dietary Fiber of Fagopyrum tataricum

  • Kim, Dong-Eun;Lee, Beom-Goo;Park, Cheol-Ho;Kang, Wie-Soo
    • Agricultural and Biosystems Engineering
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    • v.6 no.2
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    • pp.70-76
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    • 2005
  • Seed, stem and sprout of F. tataricum were separately milled using the ultra fine mill under the same condition to investigate the effect of roasting or extruding on the particle size, microstructure and water solubility of dietary fiber. The mean particle size of MR (roasting) is increased in stem and sprout, and that of ME (extruding) is increased in seed, compared to that of control. The microscopic views of seed show that control has the spherical shape but ME the larger and irregular shape, and those of stem and sprout show that control has the needle like shape but ME more rounded shape. Water solubility index of ME is much higher than that of control or MR in seed, stem and sprout. It shows that seed, stem and sprout are damaged more in extruding than in roasting, and the starch and cell wall structure must be destroyed to change the water insoluble dietary fiber into the water soluble dietary fiber.

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Effect of Heat Treatment on Superconducting Properties on Bi2212/Ag Wire (Bi2212/Ag 선재의 초전도 특성에 대한 열처리의 영향)

  • Kim, S.C.;Ha, D.W.;Song, K.J.;Oh, S.S.;Lee, N.J.;Han, I.Y.;Oh, J.G.;Sohn, H.S.
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.54-58
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    • 2006
  • We have fabricated double stacked 385 filamentary Bi2212/Ag round wires which have different Ag ratios. The wires have been heat-treated at the maximum temperature($T_{max}$) of $882{\sim}896^{\circ}C$ for 0.5 h. Effect of heat treatment on critical current density and critical temperature on Bi2212/Ag round wires has been studied. Critical current density of the wire heat -treated at $890^{\circ}C$ showed 206,250 $A/cm^2$ at 4.2 K, 0 T and critical temperature of the wire was 83 K. Microstructure of the wires also has been studied via optical microscopy and SEM.

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A Study on Properties of $MgF_2$ antireflection film for solar cell (태양전지용 $MgF_2$ 반사방지막 특성연구)

  • Park, Gye-Choon;Yang, Hyeon-Hun;Baek, Su-Ung;Na, Kil-Ju;So, Soon-Youl;Lee, Jin;Chung, Hae-Deok
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.378-380
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    • 2009
  • $MgF_2$ is a current material for the optical applications in the UV and deep UV range. Process variables for manufacturing the $MgF_2$ thin film were established in order to clarify optimum conditions for growth of the thin film depending upon process conditions, and then by changing a number of vapor deposition conditions and substrate temperature, Annealing conditions variously, structural and Optical characteristics were measured. Thereby, optimum process variables were derived. Nevertheless, modern applications still require improvement of the optical and structural quality of the deposited layers. In the present work, the composition and microstructure of $MgF_2$ single layers grown on slide glass substrate by Electro beam Evaporator(KV-660) processes, were analyzed and compared. The surface Substrate temperature having an effect on the quality of the thin film was changed from $200[^{\circ}C]$ to $350[^{\circ}C]$ at intervals of $50[^{\circ}C]$. and annealing temperature an effect on the thin film was changed from $200[^{\circ}C]$ to $400[^{\circ}C]$ at intervals of $50[^{\circ}C]$. Physical properties of the thin film were investigated at various fabrication conditions substrate temperature, annealing and temperature, annealing time by XRD, FE-SEM.

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The Effect of Tempering Temperature on Ultrasonic Velocity Property at the Quenched SCM 440 Steel (퀜칭한 SCM 440 강에서 초음파 전파특성에 미치는 템퍼링온도의 영향)

  • Lee, K.W.;Kim, M.I.;Park, U.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.3
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    • pp.54-62
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    • 1991
  • The effect of tempering temperature on the ultrasonic propagation velocity at SCM 440 steel quenched from $870^{\circ}C$ and $1000^{\circ}C$ has been studied by metallurgical and crystallographical observation. The measurements of ultrasonic velocity were made on the specimen by appling an immersion ultrasonic pulse-echo technique with a constant frequency of 10 MHz. The quenched microstructure of this steel was a lath martensite. As the tempering temperature was increased, the martensite was transformed into the tempered martensite composed of cementite and carbide. The ultrasonic velocity increased with increasing the tempering temperature. It was thought that these were resulted from the microstructural transformation. The change of ultrasonic propagation velocity with quenching and tempering heat treatment was resulted from microstrain due to the change of internal stress. Considering these results concerning to the change of ultrasonic propagation velocity. the phenomena of microstructural transformation were estimated. Consequently, it was thought that the degree of quenching and tempered heat treatment of steel could be nondestructively evaluated with the change of ultrasonic propagation velocity.

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Effect of Solution Treatment on Corrosion Behavior of AZ91-2%Ca Magnesium Casting Alloy (주조용 AZ91-2%Ca 마그네슘 합금의 부식 거동에 미치는 용체화처리의 영향)

  • Moon, Jung-Hyun;Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.4
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    • pp.190-199
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    • 2015
  • The study is intended to investigate the effect of solution treatment on microstructure and corrosion behavior of AZ91(Mg-9%Al-1%Zn-0.3%Mn)-2%Ca casting alloy. In as-cast state, the AZ91-2%Ca alloy consisted of intermetallic ${\beta}(Mg_{17}Al_{12})$, $Al_8Mn_5$ and $Al_2Ca$ phases in ${\alpha}-(Mg)$ matrix. After the solution treatment, Al within the ${\alpha}-(Mg)$ matrix was distributed more homogeneously, along with the slight decrease in the total amount of intermetallic compounds. The corrosion resistance of the AZ91-2%Ca alloy was improved after the solution treatment. The microstructural examinations for the solution-treated samples revealed that the better corrosion resistance may well be related to the incorporation of more oxides and hydroxides such as $Al_2O_3$, $Al(OH)_3$, CaO and $Ca(OH)_2$ into the surface corrosion product without dissolution of the intermetallic phases along the grain boundaries.

Effect of Hydrogen on Dezincification of Cu-Zn Brass (Cu-Zn 황동에서 수소가 탈아연 부식에 미치는 영향)

  • Choe, Byung Hak;Lee, Bum Gyu;Jang, Hyeon Su;Jeon, Woo Il;Park, Yong Sung;Lim, Jae Kyun;Lee, Jin Hee;Park, Chan Sung;Kim, Jin Pyo
    • Korean Journal of Materials Research
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    • v.27 no.3
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    • pp.172-178
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    • 2017
  • The aim of this study is to consider the effect hydrogen on dezincification behavior of Cu-Zn alloys. The investigations include microstructural observations with scanning electron microscope and chemical composition analysis with energy dispersive spectrometer. The dezincification layer was found to occur in high pressure hydrogen atmosphere, not in air atmosphere. In addition, the layers penetrated into the inner side along the grain boundaries in the case of hydrogen condition. The shape of the dezincification layers was porous because of Zn dissolution from the ${\alpha}$ or ${\beta}$ phase. In the case of stress corrosion cracks formed in the Cu-Zn microstructure, the dezincification phenomenon with porous voids was also accompanied by grain boundary cracking.