• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.54-57
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• 2006

Structure H formation experiments were conducted in a semi-batch stirred vessel using methane as the small guest substance and neohexane(NH), tert-butylmethylether(TBME) and methylcyclohexane(MCH) as the large molecule guest substance (LMGS). The results indicate that the rates of gas uptake and induction times are generally dependent on the magnitude of the driving force. When tert-butyl methyl ether is used as the LMGS rapid hydrate formation, much smaller induct ion time and rapid decomposition can be achieved. Liquid-liquid equilibrium (LLE) data for the above LMGS with water have been measured under atmospheric pressure at 275.5, 283.15K, and 298.15K. It was found that TBME is the most water soluble followed by NM and MCH. The solubility of water in the non-aqueous liquid was found to increase in the following order: MCH

• Journal of the Korean Applied Science and Technology
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• v.27 no.1
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• pp.87-92
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• 2010

Silicone surfactants are widely used in many industrial area because of its thermal stability and lower foaming property. But it has limitation to expand the application because of migration and bubble generation issues when it is mixed with organic surfactant. In this study, epoxy functionalized fluoro-silicone surfactant, perfluoro glycidoxypropyl polyether siloxane(PFGES), was synthesized using hydrosilylation reaction among perfluoro methyl hydrogen siloxane, allyl glycidyl ether, and allyl ployether in order to get lower surface tension, better thermal stability than conventional silicone surfactant, and reactivity with anhydride function.

• Journal of the Korean Solar Energy Society
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• v.21 no.2
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• pp.55-67
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• 2001

This study contains the photocatalytic degradation of methyl-tert-butyl ether(MTBE), one of water-contaminating substances, into $CO_2$. Herein was investigated factors, kinetics, and reaction pathways related with MTBE degradation. This works is possible to be applied in the field of environmental remediation such as undergroundwater purification with optimized system configuration in the near future.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.328-328
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• 2006

On mixing of 1,3-dehydroadamantane, 1, with electron-deficient vinyl monomers such as acrylonitrile and methyl acrylate in THF at r.t. in the absence of any initiator, the copolymerization spontaneously proceeded to give alternating copolymers in 28-88 % yield. By contrast, no reaction of 1 occurred, when isobutyl vinyl ether or styrene was mixed under the similar conditions. These contrastive results indicate the high electron density of a central s-bond in a strained [3.3.1]propellane derivative, 1. Alternating sequences of the resulting copolymers were characterized by NMR and MALDI-TOF-MS measurements. DSC and TGA measurements revealed the high thermal stability of the alternating copolymers containing bulky and stiff adamantane skeletons.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.53-60
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• 1997

1. 서론 : 촉매막기술은 반응과 분리공정을 동시에 하나의 장치에서 수행할 수 있기 때문에 한 개의 공정을 줄일 수 있는 효과적인 에너지 절약형 기술이다. 생성물중의 적어도 하나가 선택적으로 막을 통해 투과되기 때문에 가역반응의 경우에는 비가역반응에 가까운 거동을 보이게 된다[1-5]. 본 연구는 12-텅스토인산($H_3PW_{12}O_{40}$)를 촉매로 사용하고 막반응시를 비활성촉매막반응기(IMRCF, Inert membrane reactor with catalyst in the feed side)형태, 막으로는 PSF(Polysulfone), PPO(Polyphenylene Oxide)를 사용하여 MTBE(Methyl tert-butyl ether)분해반응을 모사하였다. 막반응기에서 생성된 생성물을 선택적으로 분리해냄으로 인하여 전환율은 고정층보다 증가하였는데 반응온도가 증가할수록, 반응물의 분압은 낮을수록 증가하였다. 반응온도가 높아짐에 따라 막반응기에서의 전환율은 고정층반응에서 나타나는 전환율과의 차이가 줄어드는 것을 볼 수 있었다. 위와같은 결과에 따라서 MTBE 반응물의 분해로 생성되는Isobutene의 수율이 90$\circ$C 이상의 반응온도에서 촉매/반응물비에 대한 최적조건이 나타나는 것을 알 수 있었다.

• Archives of Pharmacal Research
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• v.28 no.1
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• pp.111-114
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• 2005

The antihistamine effects of the triprolidine were studied in rats to determine the feasibility of their enhanced transdermal delivery from the poly (4-methyl-1-pentene) (TPX) matrix system containing penetration enhancer and plasticizer. The antihistamine effects were determined by the Evans blue dye procedure by comparing the changes in vascular permeability increase following the transdermal administration. The vascular permeability increase was significantly reduced by transdermal administration of the triprolidine-TPX system containing triethyl citrate (TEC) and polyoxyethylene-2-oleyl ether (POE). Both the plasticizer and penetration enhancer played an important role in the skin permeation of triprolidine and increased the antihistamine effects. These results showed that the triprolidine-TPX matrix system containing plasticizer and penetration enhancer could be a transdermal delivery system providing the increased antihistamine effects.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.533-536
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• 2006

PC-type copolymers were synthesized using MPEG(Polyethylene glycol methyl ether methacrylate, Mn=2080) to different mole ratios of mono-carboxylic acid(AA : Acylic acid). The mole ratios of AA were 2, 3, 4. To investigate effects of PC-type co-polymers on the hydration of cement, experiments involving FT-IR, XRD, SEM have been analysed with cement paste specimens to 1, 3, 28 day. The hydration reaction rate of cement paste was slightly delayed at 1 day, due to increase in molar ratio of [AA] / [MPEG], it was recovered in the days after.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.77-80
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• 2006

Graft copolymerized polycarboxylate(PC)-type superplasticizers(PCs) which have carboxylic acid with $\pi$ bond among the molecular structure and polyethyleneglycol methyl ether methacrylate(PMEM) were synthesized by free radical reaction and investigated the chemical structure, polymerization condition, and physical and chemical properties. Also, the effects of PCs in the dispersion, adsorption and hydration of cement were evaluated. As the molecular weight of graft chain decreases, the adsorption amount on cement particles increased. It was advantageous for the flow to reduce molar ratio, the lower the side bone molecular weight, and increase the molar ratio, the larger the side bone molecular weight. The hydration reaction speed was highly delayed at day 1, due to increase in molar ratio and reduction in side bone molecular weight, but it was recovered in the days after.

• Fashion & Textile Research Journal
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• v.5 no.5
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• pp.545-549
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• 2003

Dyeing properties such as migration of disperse dye and color fastness of 4 types of the carrier[Carrier-I(methyl napthalene). Carrier-II(chloro benzene). Carrier-III(aromatic ether) and Carrier-IV(o-phenyl phenol)] were evaluated for the study. For the results, the optimum dyeing time and concentration of the carrier was 30min at $110^{\circ}C$ and 2g/l, respectively. The redyeing ratio of the fabric samples treated with Carrier-II and III was higher than that treated with Carrier-I and IV, thus, if was conclude that the redyeing ratio of the samples treated with Carrier-II and III was excellent. The light fastness of the samples treated with Carrier-III and IV was higher than that of Carrier-I and II in order of 2-4 grades. However, there were little changes in terms of washing and sublimation and rubbing fastness for the samples.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.207-208
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• 2006

Earthworms have been widely used as bioindicators for soil ecotoxicity assessment. Ecotoxicity of methyl tert-butyl ether(MTBE) to terrestrial organisms were evaluated by- earthworm assay. Test earthworm species were Perionyx excavatus and Eisenia andrei. The. toxicity test was performed based on a OECD guideline No. 207 with slight modification. Mortality and abnormal morphology of earthworms exposed to different concentrations of MTBE were measured. Toxic levels of MTBE were determined by measuring the median lethal concentration (LC5O) after 72 hours. The toxicity data was statistically analyzed by Trimmed Spearman-Harbor method. This study showed that, P. excavatus is more sensitive to E. andrei, and that earthworm assay can be a good protocol to evaluate the soils contaminated gasoline components.