• Title/Summary/Keyword: method validation #5

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The Validation Study of Auto Anlysis Method Combined with Aqua Regia Digestion for Fluorine of Soil (왕수분해와 결합한 자동분석법의 토양 중 불소시험 유효성 연구)

  • Na, Kyung-Ho;Yun, In-Chul;Lee, Jung-Bok
    • Journal of Soil and Groundwater Environment
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    • v.15 no.5
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    • pp.8-15
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    • 2010
  • The purpose of this research is to check the validation of an auto-analysis method combined with aqua regia digestion apparatus for improvement of water distillation method used as a fluorine test of soil. Fluorine contents of CaO used in the pretreatment course of water distillation method were 120 mg/kg ~ 5,064 mg/kg at the blank test, which was exceeded up to maximum 12.5 times of the soil standard, so it was estimated due to a effect of fluorine existing as impurities of CaO. The recovery test of the same samples indicated that water distillation method and auto-analysis method were 134.5mg/kg and 161.7mg/kg respectively, the recovery ratio of the latter was 16.8% higher than the formal. The validation test of two methods satisfied the standard, but auto analysis method was excellent more than distillation method. Also, auto analysis method could save a analysis time up to maximum 4.7 times by comparison with water distillation method.

Smoothing Parameter Selection Using Multifold Cross-Validation in Smoothing Spline Regressions

  • Hong, Changkon;Kim, Choongrak;Yoon, Misuk
    • Communications for Statistical Applications and Methods
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    • v.5 no.2
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    • pp.277-285
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    • 1998
  • The smoothing parameter $\lambda$ in smoothing spline regression is usually selected by minimizing cross-validation (CV) or generalized cross-validation (GCV). But, simple CV or GCV is poor candidate for estimating prediction error. We defined MGCV (Multifold Generalized Cross-validation) as a criterion for selecting smoothing parameter in smoothing spline regression. This is a version of cross-validation using $leave-\kappa-out$ method. Some numerical results comparing MGCV and GCV are done.

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Method Development and Cross Validation of Analysis of Hydroxylated Polycyclic Aromatic Hydrocarbons (OH-PAHs) in Human Urine (소변 중 다환방향족탄화수소 대사체의 분석법 확립 및 교차분석)

  • Park, Na-Youn;Jeon, Jung-Dae;Koo, Hyeryeong;Kim, Jung Hoan;Lee, Eun-Hee;Lee, Kyungmu;Mun, Cheoljin;Kho, Younglim
    • Journal of Environmental Health Sciences
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    • v.41 no.5
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    • pp.358-367
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    • 2015
  • Objectives: This study was performed to evaluate the analytical method for PAH metabolites in human urine using enzyme hydrolysis and solid-phase extraction coupled with LC-(ESI)-MS/MS technique. Methods: We employed HPLC tandem mass spectrometry techniques with appropriate pre-treatment for analysis of 16 OH-PAHs in human urine. Samples were hydrolysis by ${\beta}$-flucuronidase/Aryl sulfatase, and target compounds were extracted by solid-phase extraction with a strata-x cartridge. Cross-validation was performed between Eulji University and Green Cross laboratories with 200 human urine samples. Results: The accuracies were between 90.3% and 118.8%, and precisions (relative standard deviations) were lower than 10%. The linearity obtained was satisfying for the 16 OH-PAH compounds, with a coefficient of determination ($r^2$) higher than 0.99. The results of cross-validation at the two organizations were compared by ICC (interclass correlation coefficient) values. The cross-validation results were excellent or good for all compounds. Conclusion: An analytical method was validated for low nanogram levels of 16 OH-PAHs in human urine. Also, satisfying results were obtained for method validation such as accuracy, precision and ICC of cross-validation.

Cross-Validation method for Science and Technology Research Paper considering Interdisciplinary Approach (다학제적 접근을 고려한 과학기술논문 상호검증 방법)

  • Han, Young-shin
    • Journal of Engineering Education Research
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    • v.18 no.5
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    • pp.3-10
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    • 2015
  • Researchers in science and technology has broadened the scope of research in order to solve complex problems, academic exchange has also been actively carried out. If the paper which is a mean of interdisciplinary approach has a limited term and the formula, it can act as barriers to access for many researchers in various fields. This paper proposes a cross-validation method for eliminating documentary barriers based on discrete event system formalism. We expect that our proposed method will improve a cross-validation considering researchers in another fields.

Field Validation of alternative extraction method for the determination of airborne MWFs (대체용매를 이용한 금속가공유 측정방법 타당성에 대한 현장평가)

  • Jeong, Jee Yeon;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.2
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    • pp.96-101
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    • 2009
  • The purpose of this study was to conduct the field validation of alternative method(ETM method) by using non-carcinogenic, and less toxic solvents than NIOSH (National Institute for Occupational Safety and Health) analytical method 5524 for measuring the airborne metalworking fluids in workplaces. We carried out the field validation test by using the exposure chamber, guaranteeing the air sampling homogeneously in a machining environment. The ETM mixed solvent presented the complete solubility of MWFs used in test field. Based on the field test data, the bias of the ETM method from reference method, NIOSH analytical method 5524, was from -7.0% to 5.1%. The overall uncertainty of the ETM nethod was 21.6%, which satisfied the NIOSH criteria for the sampling and analytical criteria.

Estimation of daily maximum air temperature using NOAA/AVHRR data (NOAA/AVHRR 자료를 이용한 일 최고기온 추정에 관한 연구)

  • 변민정;한영호;김영섭
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2003.04a
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    • pp.291-296
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    • 2003
  • This study estimated surface temperature by using split-window technique and NOAA/AVHRR data was used. For surface monitoring, cloud masking procedure was carried out using threshold algorithm. The daily maximum air temperature is estimated by multiple regression method using independent variables such as satellite-derived surface temperature, EDD, and latitude. When the EDD data added, the highest correlation shown. This indicates that EDD data is the necessary element for estimation of the daily maximum air temperature. We derived correlation and experience equation by three approaching method to estimate daily maximum air temperature. 1) non-considering landcover method as season, 2) considering landcover method as season, and 3) just method as landcover. The last approaching method shows the highest correlation. So cross-validation procedure was used in third method for validation of the estimated value. For all landcover type 5, the results using the cross-validation procedure show reasonable agreement with measured values(slope=0.97, intercept=-0.30, R$^2$=0.84, RMSE=4.24$^{\circ}C$). Also, for all landcover type 7, the results using the cross-validation procedure show reasonable agreement with measured values(slope=0.993, Intercept=0.062, R$^2$=0.84, RMSE=4.43$^{\circ}C$).

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Kernel method for autoregressive data

  • Shim, Joo-Yong;Lee, Jang-Taek
    • Journal of the Korean Data and Information Science Society
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    • v.20 no.5
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    • pp.949-954
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    • 2009
  • The autoregressive process is applied in this paper to kernel regression in order to infer nonlinear models for predicting responses. We propose a kernel method for the autoregressive data which estimates the mean function by kernel machines. We also present the model selection method which employs the cross validation techniques for choosing the hyper-parameters which affect the performance of kernel regression. Artificial and real examples are provided to indicate the usefulness of the proposed method for the estimation of mean function in the presence of autocorrelation between data.

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Geomechanical and hydrogeological validation of hydro-mechanical two-way sequential coupling in TOUGH2-FLAC3D linking algorithm with insights into the Mandel, Noordbergum, and Rhade effects

  • Lee, Sungho;Park, Jai-Yong;Kihm, Jung-Hwi;Kim, Jun-Mo
    • Geomechanics and Engineering
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    • v.28 no.5
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    • pp.437-454
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    • 2022
  • The hydro-mechanical (HM) two-way sequential coupling in the TOUGH2-FLAC3D linking algorithm is validated completely and successfully in both M to H and H to M directions, which are initiated by mechanical surface loading for geomechanical validation and hydrological groundwater pumping for hydrogeological validation, respectively. For such complete and successful validation, a TOUGH2-FLAC3D linked numerical model is developed first by adopting the TOUGH2-FLAC3D linking algorithm, which uses the two-way (fixed-stress split) sequential coupling scheme and the implicit backward time stepping method. Two geomechanical and two hydrogeological validation problems are then simulated using the linked numerical model together with basic validation strategies and prerequisites. The second geomechanical and second hydrogeological validation problems are also associated with the Mandel effect and the Noordbergum and Rhade effects, respectively, which are three phenomenally well-known but numerically challenging HM effects. Finally, sequentially coupled numerical solutions are compared with either analytical solutions (verification) or fully coupled numerical solutions (benchmarking). In all the four validation problems, they show almost perfect to extremely or very good agreement. In addition, the second geomechanical validation problem clearly displays the Mandel effect and suggests a proper or minimum geometrical ratio of the height to the width for the rectangular domain to maximize agreement between the numerical and analytical solutions. In the meantime, the second hydrogeological validation problem clearly displays the Noordbergum and Rhade effects and implies that the HM two-way sequential coupling scheme used in the linked numerical model is as rigorous as the HM two-way full coupling scheme used in a fully coupled numerical model.

Assessment and Reliability Validation of Lane Departure Assistance System Based on DGPS-GIS Using Camera Vision (카메라영상에 의한 DGPS-GIS기반 차선변경 지원시스템의 평가 및 신뢰성 검증)

  • Moon, Sangchan;Lee, Soon-Geul;Kim, Minwoo;Joo, Dani
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.6
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    • pp.49-58
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    • 2014
  • This paper proposes a new assessment and reliability validation method of Lane Departure Assistance System based on DGPS-GIS by measuring lanes with camera vision. Assessment of lane departure is performed with yaw speed measurement and determination method for false alarm of ISO 17361 and performance validation is executed after generating departure warning boundary line by considering deviation error of LDAS using DGPS. Distance between the wheel and the lane is obtained through line abstraction using Hough transformation of the lane image with camera vision. Evaluation validation is obtained by comparing this value with the distance obtained with LDAS. The experimental result shows that the error of the extracted distance of the LDAS is within 5 cm. Also it proves performance of LDAS based on DGPS-GIS and assures effectiveness of the proposed validation method for system reliability using camera vision.

A Study on the Realtime Cert-Validation of Certification based on DARC (DARC 기반에서의 실시간 인증서 유효성 검증에 관한 연구)

  • Jang, Heung-Jong;Lee, Seong-Eun;Lee, Jeong-Hyeon
    • The KIPS Transactions:PartC
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    • v.8C no.5
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    • pp.517-524
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    • 2001
  • There are cases that revoke the certification because of disclosure of private key, deprivation of qualification and the expiration of a term of validity based on PKI. So, a user have to confirm the public key whether valid or invalid in the certification. There are many method such as CRL, Delta-CRL, OCSP for the cert-validation of certification. But these method many problems which are overload traffic on network and the CRL server because of processing for cert-validation of certification. In this paper we proposed the realtime cert-validation of certification method which solved problems that are data integrity by different time between transmission and receiving for CRL, and overload traffic on network and the CRL server based on DARC.

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