• 제목/요약/키워드: metallurgical technology

검색결과 690건 처리시간 0.022초

Cut Edge Corrosion of Painted Zn and 55%Al-Zn Coated Steels under Alternate Wetting and Drying

  • Nishikata, A.;Tsuda, T.;Tsuru, T.
    • Corrosion Science and Technology
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    • 제9권1호
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    • pp.34-38
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    • 2010
  • Electrochemical study on cut edge corrosion of prepainted Zn coated (GI) and 55%Al-Zn coated (GL) steels has been performed in wet-dry cyclic conditions. Maximum width of delaminated polymer coating from the cut edge for GI and GL specimens was evaluated under wet-dry cyclic conditions. The cyclic tests were carried out for 1000 h by changing of relative humidity, where the salt of NaCl was deposited on the specimen every 48 h. The cut edge corrosion test under NaCl deposit indicated that the delamination of the GL specimen progresses at a higher rate than the GI. The electrochemical corrosion monitoring was also performed under condition of alternate exposure to immersion in NaCl solution and drying at 60%RH and $25^{\circ}C$. On the basis of the results of the delamination tests and electrochemical measurements, the mechanism of cut edge corrosion for GI and GL were discussed.

텅스텐이 첨가된 슈퍼 2상 스테인리스강의 내식성에 미치는 시효처리의 영향 (The Effect of Aging Treatment on the Corrosion Resistance in Super Duplex Stainless Steel with Added W)

  • 김수천;최한글;김윤규;박영태;이종문;박진환;강창룡
    • 한국해양공학회지
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    • 제23권6호
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    • pp.87-92
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    • 2009
  • The effect of aging on the precipitation of the $\sigma$ phase and the corrosion resistance in tungsten substituted super duplex stainless steels was investigated. The volume fraction of the $\sigma$ phase and the current density increased with aging at temperatures up to $750^{\circ}C$ and then decreased. With an increase in aging time, the volume fraction of the $\sigma$ phase and the current density also increased. The $\sigma$ phase hardly influenced the corrosion resistance. With the substitution of tungsten for molybdenum in super duplex stainless steel, the volume fraction of the $\sigma$ phase and the current density decreased remarkably.

Present State and Prospect on Reutilization of Metal - Bearing Solid Wastes in China

  • Chai, Liyuan;Chen, Weiliang;Min, Xiaobo;He, Dewen;Zhang, Chuanfu
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.183-187
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    • 2001
  • Present states on reutilization of metal-bearing solid wastes in China including metal-containing gangue, red mud, nonferrous metallurgical slag or residue, arsenical slag, steel - iron slag, waste batteries, were described in detail. The wastes pile up at a large quantity, resulting in seriously potential harm to environment. Most of these wastes, however, contain valuable metals, which are regarded as important secondary resources for extracting metals. Waste slag and batteries with a high grade of metals are treated by a hydro-based and / or pyre-based method for extracting valuable metals. While gangue and waste slag with a low grade are as a raw material in architecture field. In the future, a novel technology, such as high-grads magnetization separation technique and biological technique, will be designed to treat these wastes for protecting environment and recycling valuable components. These wastes, furthermore, are synthetically reutilized to produce various architectural materials, including glass and ceramics.

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Electrochemistry and Leaching Kinetics of Gold-Silver Alloys in Cyanide Solutions

  • Guan, Y.Charles;Sun, Xiaowei;Han, Kenneth N.
    • 자원리싸이클링
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    • 제10권1호
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    • pp.42-48
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    • 2001
  • The dissolution behavior of gold and silver from gold-silver alloys in aerated cyanide solutions has been investigated by an electrochemical means as well as a direct measurement of gold and silver ions reported in the bulk solution as a function of time using rotating disc electrodes. The variables studied included oxygen partial pressure, rotating speed of the disc, concentration of cyanide, temperature and composition of the allyos. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of the mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was controlled partially by chemical reaction. but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

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Influence of Retrogression and Re-aging on the Exfoliation Corrosion Behavior of AA 7085 Sheets

  • Krishnan, Ajay;Raja, V.S.;Mukhopadhyay, A.K.
    • Corrosion Science and Technology
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    • 제15권4호
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    • pp.159-165
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    • 2016
  • An attempt has been made to understand the influence of retrogression and re-aging (RRA) on the exfoliation corrosion behaviour of AA 7085 alloy in comparison with the peak aged condition (PA). Immersion tests using ASTM G34 and studies involving electrochemical impedance spectroscopy showed that the RRA treated alloy provided higher resistance to exfoliation corrosion than the PA treated alloy. The improved resistance was attributed to the enhanced Cu content and the discontinuous nature of the grain boundary precipitate, which was revealed through transmission electron microscopy.

Effect of Sintering Temperature, Heat Treatment and Tempering on Hardness of SH737-2Cu-0.9C Sintered Samples

  • Anand, S.;Verma, N.;Upadhyaya, A.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.555-556
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    • 2006
  • The study examines hardness pattern of SH737-2Cu-.9C samples transient liquid phase sintered at different temperatures viz. $1120^{\circ}C$, $1180^{\circ}C$ and $1250^{\circ}C$, heat treated by various methods and then tempered at different temperatures. Sintered samples were characterized for density and densification parameter, and austenitized at $900^{\circ}C$, subsequently cooled by four different methods viz. annealing, normalizing, oil and brine quenching. Hardness pattern was found minimum for air cooled and maximum for brine quenched, and samples sintered at $1250^{\circ}C$ had relatively higher hardness. The O.Q and B.Q samples were then tempered at $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$ and $700^{\circ}C$. Hardness pattern typically showed secondary hardness taking place, with maximum around $600^{\circ}C$.

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Effect of Carbon Addition and Sintering Temperature on Densification and Microstructural Evolution of Sinter-Hardening Alloys Steels

  • Verma, N.;Anand, S.;Upadhyaya, A.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.557-558
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    • 2006
  • In all conventional sintered PM products, the pores present are of two types, primary and secondary. Primary pores forming during compaction and latter during sintering, due to penetration of formed liquid through the matrix grain boundary. Effect of carbon addition on diffusion of Cu in SH737-2Cu system was investigated. After compaction and transient liquid phase sintering at $1120^{\circ}C$ and $1180^{\circ}C$, samples were characterized for densification, showing rise in sintering density and reduction in swelling on carbon addition. Quantitative microstructural characterization (shape factor and pore size) revealed bimodal distribution for 0% carbon, more rounded pores for 0.9% carbon and higher sintering temperature, and pore coarsening at higher sintering temperature.

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인쇄회로기판 제조공정 중 발생한 슬러지 내 건식환원 처리를 통한 구리 회수를 위한 슬러지 분석 및 열역학적 계산 (Phase Analysis and Thermodynamic Simulation for Recovery of Copper Metal in Sludge Originated from Printed Circuit Board Manufacturing Process by Pyro-metallurgical Process)

  • 한철웅;김영민;김용환;손성호;이만승;이기웅
    • 자원리싸이클링
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    • 제26권5호
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    • pp.85-96
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    • 2017
  • 본 연구에서는 PCB 도금 및 에칭 공정 중 발생한 슬러지의 분석을 통해 건식환원처리가 가능한 슬래그 시스템을 선정하고자 하였으며 이를 바탕으로 슬러지 내에 존재하는 유가금속의 회수 가능성에 대하여 실험적 및 열역학적 검토를 하였다. 슬러지는 $100{\sim}500^{\circ}C$의 온도구간에서 건조한 후 슬러지의 형상과 화학성분 및 상을 분석하였다. 슬러지의 건식환원처리 가능성은 FactSage를 이용한 열역학적 계산을 통해 조사하였다.