• 제목/요약/키워드: metalloid

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Effects of Metalloid Elements on the Mechanical Properties of Fe-Based Bulk Amorphous Alloys

  • Kim, Yongchan;Hwang, Byoungchul
    • 한국재료학회지
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    • 제26권12호
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    • pp.671-675
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    • 2016
  • In this study, the glass-forming ability and mechanical properties of newly developed Fe-Mn-Cr-Mo-B-C-P-Si-Al bulk amorphous alloys were investigated, and metalloid elements such as B, C, and P were found to have a strong influence on the properties of the Fe-based amorphous alloys. When the total metalloid content (B, C, and P) is less than 5 %, only the crystal phase is formed, but the addition of more than 10 % metalloid elements enhances the glass forming ability. In particular, the alloys with 10 % metalloid content exhibit the best combination of very high compressive strength (~2.8 GPa) and superior fracture elongation (~30 %) because they consist of crystal/amorphous composite phases.

Comparison of Trace Element, Metal, and Metalloid Contents in North and South Korean Plants

  • Park, Jeong-Soo;Chung, Ha-Sook;Lee, Eun-Ju
    • 한국환경과학회지
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    • 제23권6호
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    • pp.995-1001
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    • 2014
  • When relations improve between North and South Korea, there will be demand for North Korean edible plants because of the low labor cost and similar environmental conditions. However, there is no reliable information about trace elements, metals, and metalloids in edible plants from North Korea. Selenium (Se) and germanium (Ge) have positive effects on basic human health and are therapeutical in diverse illnesses. Metal and metalloid (Cd, Pb) poisoning, on the other hand, can cause many health problems. Plants collected from North Korea had higher selenium content than those from South Korea. Although none of the collected species exceeded the permissible levels of cadmium and lead, their content in plants was significantly higher in North Korea than in South Korea. The high metal contents in plants collected from North Korea may be associated with the soil physicochemical properties as well as the accumulated amounts of elements in the soil.

ANTIMUTAGENIC STUDY OF SELENIUM COMPOUNDS

  • Bronzetti, Giorgio;Leonardo Caltavuturo, Marco Cini;Croce, Clara Della
    • 한국독성학회:학술대회논문집
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    • 한국독성학회 2001년도 International Symposium on Dietary and Medicinal Antimutgens and Anticarcinogens
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    • pp.10-10
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    • 2001
  • Selenium is an essential nutritional element for several animal species and human. It has been also seen, that low levels of selenium in the diet can cause many diseases. This metalloid was defined like a "double face" element because it possesses antioxidant, antimutagen, anticarcinogen but also mutagenic and carcinogenic effects. The most important metabolic role of selenium in the animal species is its presence in the Glutathione Peroxidase(GSH-Px). (omitted)

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Effects of Metal and Metalloid Contamination on Microbial Diversity and Activity in Agricultural Soils

  • Tipayno, Sherlyn C.;Chauhan, Puneet S.;Woo, Sung-Man;Hong, Bo-Hee;Park, Kee-Woong;Chung, Jong-Bae;Sa, Tong-Min
    • 한국토양비료학회지
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    • 제44권1호
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    • pp.146-159
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    • 2011
  • The continuous increase in the production of metals and their subsequent release into the environment has lead to increased concentration of these elements in agricultural soils. Because microbes are involved in almost every chemical transformations taking place in the soil, considerable attention has been given to assessing their responses to metal contaminants. Short-term and long-term exposures to toxic metals have been shown to reduce microbial diversity, biomass and activities in the soil. Several studies show that microbial parameters like basal respiration, metabolic quotient, and enzymatic activities, including those of oxidoreductases and those involved in the cycle of C, N, P and other elements, exhibit sensitivity to soil metal concentrations. These have been therefore, regarded as good indices for assessing the impact of metal contaminants to the soil. Metal contamination has also been extensively shown to decrease species diversity and cause shifts in microbial community structure. Biochemical and molecular techniques that are currently being employed to detect these changes are continuously challenged by several limiting factors, although showing some degree of sensitivity and efficiency. Variations and inconsistencies in the responses of bioindicators to metal stress in the soil can also be explained by differences in bioavailability of the metal to the microorganisms. This, in turn, is influenced by soil characteristics such as CEC, pH, soil particles and other factors. Therefore, aside from selecting the appropriate techniques to better understand microbial responses to metals, it is also important to understand the prevalent environmental conditions that interplay to bring about observed changes in any given soil parameter.

A Mathematical Model Development for Microbial Arsenic Transformation and Transport

  • Lim, Mi-Sun;Yeo, In-Wook;Lee, Kang-Kun
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.318-322
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    • 2004
  • Arsenic is a toxic and carcinogenic metalloid, whose sources in nature include mineral dissolution and volcanic eruption. Abandoned mines and hazardous waste disposal sites are another major source of arsenic contamination of soil and aquatic systems. To predict concentrations of the toxic inorganic arsenic in aqueous phase. the biogeochemical redox processes and transport behavior need to be studied together and be coupled in a reactive transport model. A new reaction module describing the fate and transport of inorganic arsenic species (As(II)), dissolved oxygen, nitrate, ferrous iron, sulfate, and dissolved organic carbon are developed and incorporated into the RT3D code.

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도금공정에서의 세척수 제어기법에 관한 연구 (A Study on the Rinsing Control Method in the Gilding Process)

  • 김기준
    • 한국산업정보학회논문지
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    • 제9권4호
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    • pp.8-15
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    • 2004
  • 금속의 표면이나 비금속표면에 다른 금속을 사용하여 피막을 만드는 도금 공정은 산과 알칼리를 사용함에 따라 세척 작업으로서 수소 이온 농도(H+)와 수산이온농도(OH+)를 제어하게 된다 따라서, 본 연구에서는 세척수 투입에 따른 수소 이온 농도(H+)와 수산이온농도 (OH+)를 제어하기 위한 여러 가지 제어 기법을 적용하여 최적의 제어기를 설계하고자 하였으며, 이 결과는 세척수를 효율적으로 투입하여 귀중한 수자원을 절약하고, 산과 알칼리의 일정제어로 인하여 제품의 균등한 생산이 가능할 뿐만 아니라 생산 단가를 낮추어 경쟁력에 기여할 것으로 사료된다. 특히, 개발하고자하는 기법은 수학적 모델을 구하기 어려운 공정에서도 적용이 가능하도록 설계하고자 하였으며, 제어 대상의 변화에도 다른 제어 방법 보다 쉽게 알고리즘을 변화시킬 수 있다는 장점이 있도록 하였다.

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Membrane-Associated Hexavalent Chromium Reductase of Bacillus megaterium TKW3 with Induced Expression

  • Cheung K.H.;Lai H.Y.;Gu Ji-Dong
    • Journal of Microbiology and Biotechnology
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    • 제16권6호
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    • pp.855-862
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    • 2006
  • Hexavalent chromium ($Cr^{6+}$) is a highly harmful pollutant, which can be detoxified and precipitated through reduction to $Cr^{3+}$. Bacillus megaterium TKW3 previously isolated from chromium-contaminated marine sediments was capable of reducing $Cr^{6+}$ in concomitance with metalloids ($Se^{4+}$, $Se^{6+}$, and $As^{5+}$). Notwithstanding approximately 50% inhibition, it was the first report of simultaneous bacterial reduction of $Cr^{6+}$ and $Se^{4+}$ (to elemental Se). No significant difference was observed among electron donors (glucose, maltose, and mannitol) on $Cr^{6+}$ reduction by B. megaterium TKW3. The reduction was constitutive and determined to be non-plasmid mediated. Peptide mass fingerprints (PMF) revealed a novel aerobic membrane-associated reductase with $Cr^{6+}$-induced expression and specific reductive activity (in nmol $Cr^{6+}$/mg protein/min) of 0.220 as compared with 0.087 of the soluble protein fraction. Respiratory inhibitor $NaN_3$ did not interfere with the reductase activity. Transmission electron microscopy with energy dispersive X-ray (TEM-EDX) analysis confirmed the aggregation of reduced chromium along the intracellular membrane region. Future identification of the N-terminal amino acid sequence of this reductase will facilitate purification and understanding of its enzymatic action.