• Title/Summary/Keyword: metal removal rate

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Effect of processing Conditions on $3,400cm^{-1}$ -OH Peak in IR Transmitting Heavy Metal Fluoride Glasses (적외선 투과성 플루오르화 중금속 유리의 $3,400cm^{-1}$ -OH 흡수에 미치는 가공조건의 영향)

  • ;C. T Moynihan
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.231-238
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    • 1984
  • Heavy metal fluoride glasses exhibit considerable promise as high transparency materials from the UV to the IR. These glasses are prepared by fusion of the mixture of metal fulorides($ZrF_4$, $BaF_2$, $LaF_3$ etc) at 800-1, 00$0^{\circ}C$ under the inert$(N_2)$ or reactive ($CCl_4$, $Cl_2$) atmosphere following the casting into glass on cooling. Infrared absorption at the 3, 400 cm-1 -OH peak has been measured as a function of thickness for several ZrF-$BaF_2$-LaF and $HfF_4$-$BaF_2$-$LaF_3$ glasses to separate contributions from bulk and surface -OH. For glasses melted under $CCl_4$ reactive atmosphere the peak is due almost entirely to surface-OH. and melting in a closed reactor was best for removing -OH. In ambient atmosphere the -OH peak exhibited no time dependence over a 30 d period indicating a very small rate of surface attack by atmospheric H2O. Removal of -OH absorption processing was generally easier and more complete for the $BaF_2$/ThF4-glasses than for the $ZrF_4$-or $HfF_4$-based glasses.

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Repeat analysis of intraoral digital imaging performed by undergraduate students using a complementary metal oxide semiconductor sensor: An institutional case study

  • Yusof, Mohd Yusmiaidil Putera Mohd;Rahman, Nur Liyana Abdul;Asri, Amiza Aqiela Ahmad;Othman, Noor Ilyani;Mokhtar, Ilham Wan
    • Imaging Science in Dentistry
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    • v.47 no.4
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    • pp.233-239
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    • 2017
  • Purpose: This study was performed to quantify the repeat rate of imaging acquisitions based on different clinical examinations, and to assess the prevalence of error types in intraoral bitewing and periapical imaging using a digital complementary metal-oxide-semiconductor(CMOS) intraoral sensor. Materials and Methods: A total of 8,030 intraoral images were retrospectively collected from 3 groups of undergraduate clinical dental students. The type of examination, stage of the procedure, and reasons for repetition were analysed and recorded. The repeat rate was calculated as the total number of repeated images divided by the total number of examinations. The weighted Cohen's kappa for inter- and intra-observer agreement was used after calibration and prior to image analysis. Results: The overall repeat rate on intraoral periapical images was 34.4%. A total of 1,978 repeated periapical images were from endodontic assessment, which included working length estimation (WLE), trial gutta-percha (tGP), obturation, and removal of gutta-percha (rGP). In the endodontic imaging, the highest repeat rate was from WLE (51.9%) followed by tGP (48.5%), obturation (42.2%), and rGP (35.6%). In bitewing images, the repeat rate was 15.1% and poor angulation was identified as the most common cause of error. A substantial level of intra- and inter-observer agreement was achieved. Conclusion: The repeat rates in this study were relatively high, especially for certain clinical procedures, warranting training in optimization techniques and radiation protection. Repeat analysis should be performed from time to time to enhance quality assurance and hence deliver high-quality health services to patients

In-Process Measurement of Insulating Layer in ELID-Grinding (ELID 연삭에서 부도체 피막의 실시간 계측)

  • Kim, Hwa-Young;Ahn, Jung-Hwan;Seo, Young-Ho
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.71-76
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    • 2001
  • In general, it is known that the wear rate of the abrasive and the removal rate of the metal bond of the grinding wheel should be balanced to maintain the depth of the insulating surface layer to an appropriate level. In order to accomplish, the high quality ELID grinding, therefore, it is necessary to measure the depth of the insulating layer in real-time and then to control the electrolytic conditions to keep the depth to a certain level. In this study, an in-process measurement system of the insulated layer using two gap sensors - a capacitor type and an eddy current type - developed and the change of the status of the insulated layer during ELID grinding is detected. And from the experimental data, we have chosen the best mathematical model to predict the depth of the insulating layer.

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Electrolytic Treatment of Emulsified Oily Wastewater Using DSA Electrode (I) - Batch Treatment - (DSA 전극을 사용한 에멀젼 함유폐수의 전해처리 (I) -회분식 전해처리-)

  • 김인수;송영채
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.1
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    • pp.67-75
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    • 1996
  • An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

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Etch characteristics of ITO(Indium Tin Oxide)using ${SF_6}/{O_2}$-gas ECR(Electron Cyclotron Resonance) plasmas (ECR을 이용한 ${SF_6}/{O_2}$ 가스 플라즈마에 의한 ITO의 식각 특성연구)

  • 권광호;강승열;김곤호;염근영
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.7
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    • pp.563-567
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    • 2000
  • We presented the etch results of indium-tin oxide thin films by using SF$_{6}$/O$_2$gas electron cyclotron resonance plasma and conducted X-ray phtoelectron spectroscopy and quadrupole mass spectrometer analyses for the etch characteristics. The etch rate of the films was greatly dependent on that of oxygen which was the major constituent element of the films. The oxygen was removed by the forms like $O_2$or SOF$_2$. We examined the ratio of atomic content of O and In and the change of this ratio was related to the removal rate of InF$_{x}$ and the S-metal bonding.ing.

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Application of a Membrane Desolvator to the Analysis of Organic Solvents in Inductively Coupled Plasma Atomic Emission Spectrometry

  • Lee, J. S.;Lim, H. B.
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1040-1044
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    • 1999
  • A micro porous PTFE membrane desolvator (MMD) was built and evaluated for the on-line removal of organic solvents to facilitate the determination of trace metal contaminants in the solvents by ICP-AES. Three organic solvents, isopropyl alcohol (IPA), methanol, and dimethy sulfoxide (DMSO) were studied. The MMD reduced organic solvent concentration in the sample aerosol stream by 82% to 89%, as indicated by monitoring C(I) emission. Net signal intensity of Fe, Al, and Cu was increasing with higher organic solvent concentration, with the rate of increase being solvent dependent. The signal intensities for Mg and Pb followed the trend with the C(I) signal. Changing the sweep gas flow rate affected the optimum signal intensity. Wine samples were analyzed by the method of standard addition. The concentrations of B, Al, and Mg were determined with a relative precision of less than 2.3%.

Characteristics of MEK Degradation using TiO2 Photocatalyst in the Batch-type Reactor-Metal Doping Effect (회분식 반응기에서 TiO2 광촉매의 MEK 분해특성-금속담지영향)

  • Jang, Hyun Tae;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.1579-1584
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    • 2015
  • In photocatalytic reaction, the doping of metal matter can alter the titania surface properties. As such the metal matter can increase the rate of the reaction. The influence of metal doping and calcination condition of $TiO_2$ photocatalyst was investigated at the batch-type photoreactor. Several metal matters were doped to the $TiO_2$ catalyst to improve photodegradation efficiency. During the experiments, water content was 3wt%, and reactor temperature was $40^{\circ}C$. Palladium-doped $TiO_2$ was found to be the best, where as platinum or tungsten-added also showed good results. Additional doping of platinum or tungsten on Pd/$TiO_2$ had no increase on the removal efficiency. To obtain proper calcination condition, various experiments about calcination temperature and time were carried out. As a result, the optimum calcination condition was temperature of $400^{\circ}C$, time of 1 hour.

Adsorption Characteristics Evaluation of Natural Zeolite for Heavy-metal Contaminated Material Remediation (중금속 오염물질 정화를 위한 천연제올라이트의 흡착특성)

  • Shin, Eun-Chul;Park, Jeong-Jun;Jeong, Cheol-Gyu;Kim, Sung-Hwan
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.2
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    • pp.59-67
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    • 2014
  • The amount of the contaminants that can be adsorbed on the drain was evaluated for the effective remediation of the contaminated soil, and the contaminants adsorptivity of the drain was evaluated by comparing the isothermal adsorption model after carrying out the contaminants adsorption test of the reactants coated on the surface of the drain. The reactant used in the experiment is a natural zeolite, and the contaminants are copper, lead and cadmium. The results that Freundlich and Langmuir adsorption isotherm model are compared to the adsorption amount according to the change of the initial concentration by the contaminants. As a result of the component analysis, because Si, Al and O are contained approximately 28%, 11% and 48%, respectively, it is identified that the material coated on the surface of the drain is the component of the zeolite which is the reactant for the adsorption of the heavy-metal (Cu, Pb, Cd) contaminants. The heavy-metal adsorption kinetic of the zeolite which is the reactant was decreased in order of lead, copper and cadmium. The important factor of the performance evaluation of the adsorbent is the reaction rate, and if zeolite is used as the reactant in the relationship between the maximum amount of adsorption and reaction rate, it can be utilized as the design factor that determine the removal order of the complex heavy-metal. In other words, because the maximum adsorption quantity of lead is smaller compared to copper but the reaction rate is relatively fast, it can be primarily removed, and copper can be removed after removing the lead. It was analyzed that Cadmium can be finally removed after that other heavy-metal is removed.

Evaluation of Characteristic for SS400 and STS304 steel by Weld Thermal Cycle Simulation - 2nd Report: Corrosion Characteristics (용접열사이클 재현에 의한 SS400강 및 STS304강의 특성 평가 -제2보: 부식특성)

  • Ahn, Seok-Hwan;Choi, Moon-Oh;Kim, Sung-Kwang;Son, Chang-Seok;Nam, Ki-Wook
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.33-38
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    • 2007
  • The welding methods have been applied in the most structural products from multi-field of automobile, ship construction and construction, and so on. The structure steel must have enough strength of structure. In this study, SS400 steel and STS304 steel were used to estimate the corrosion characteristics of the weld thermal cycle simulated HAZ. To evaluate the corrosion characteristics, also, the materials with two conditions were used in 3.5% NaCl. The one is to the drawing with diameter of ${\Phi}10$ and the other is to the residual stress removal treatment. The electrochemical polarization test and immersion test were carried out. From test results, corrosion potential, corrosion current density, weight loss ratio and corrosion rate were measured. In the kinds of SS400 steels, corrosion potential of weld thermal cycle simulated specimens after the heat treatment showed somewhat the direction of noble potential. And in the base metal to be drawing weight loss ratio and corrosion rate occurred higher than the other kinds. In the kinds of STS304 steels, the result of base metal to be drawing was similar to results of SS400 steels, too. Two kinds of $750^{\circ}C$ and $1300^{\circ}C$ of weld thermal cycle simulation after the heat treatment were rather higher than the other kinds in weight loss ratio and corrosion rate.

A Study of Causes for Removal of Fixed Prostheses and Fate of Abutment (고정성 치과보철물의 제거원인 및 지대치 재사용에 관한 연구)

  • Mok, Won-Kyun;Kim, Hee-Jung;Jeong, Chae-Heon;Oh, Sang-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.24 no.1
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    • pp.1-17
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    • 2008
  • The purpose of this study were to report the reasons for removal of fixed prostheses and survival rate of abutment teeth. A total 192 fixed prostheses removed at Chosun university Dental Hospital and 308 abutment were investigated. The most frequent reason of removal was periodontal problem(30.7%), followed by caries(29.7%), then periapical problem(18.8%) and defective margins(14%). In metal ceramic crown, periodontal problem was the most frequent reason of removal. In complete cast crown, caries was the most frequent reason of removal. Periapical and periodontal problem was the most frequent reason people under forties and over fifties, respectively. Of the 308 abutment teeth, vital and non-vital teeth were 135(43.8%) and 173(56.2%), respectively. Of 135 vital abutment teeth, 39(28.9%) were extracted and of 173 non-vital abutment teeth, 85(49.1%) were extracted. Each risk factor for removal of fixed prostheses and extraction of abutment should be evaluated more clearly for prediction of prognosis of final prostheses and abutment teeth.