• Title/Summary/Keyword: metal melting

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Electrodeposition Characteristics of Corrosion Resistant Tantalum Coating Layer for Hydrogen Production Sulfide-Iodine Process (수소생산을 위한 Sulfide-Iodine 공정장치용 초내식 탄탈코팅층 전착특성)

  • Lee, Youngjun;Kim, Daeyoung;Han, Moonhee;Kang, Keangsoo;Bae, Gigwang;Lee, Jonghyeon
    • Journal of Hydrogen and New Energy
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    • v.23 no.6
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    • pp.573-580
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    • 2012
  • Corrosion resistance and basic physical properties of solid tantalum are not comparable to most of the structural metallic materials. The relative high cost and melting temperature of tantalum are obstacles to be widely applied to general engineering processes. Electrodeposition in molten salt enables compact and uniform tantalum coating. In this study, Ta was coated onto base metal (SUS316L) with different current densities (0.5, 5, $20mA/cm^2$) by using MSE (Molten Salt Electrodeposition). In this study, it showed that deposition efficiency and microstructure of Ta coating layer were strongly depended on current density. In the case of the current density of $5mA/cm^2$, densest microstructure was obtained. The current density above $5mA/cm^2$ caused non-uniform microstructure due to rapid deposition rate. Dense microstructure and intact coating layer contributed to significant corrosion resistance enhancement.

Isothermal Characteristics of a Rectangular Parallelepiped Sodium Heat Pipe

  • Boo Joon Hong;Park Soo Yong
    • Journal of Mechanical Science and Technology
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    • v.19 no.4
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    • pp.1044-1051
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    • 2005
  • The isothermal characteristics of a rectangular parallelepiped sodium heat pipe were inves­tigated for high-temperature applications. The heat pipes was made of stainless steel of which the dimension was $140\;m\;(L)\;{\times}\;95m\;(W)\;{\times}\;46 m\;(H)$ and the thickness of the container was 5 mm. Both inner surfaces of evaporator and condenser were covered with screen meshes to help spread the liquid state working fluid. To provide additional path for the working fluid, a lattice structure covered with screen mesh wick was inserted in the heat pipe. The bottom surface of the heat pipe was heated by an electric heater and the top surface was cooled by circulating coolant. The concern in this study was to enhance the temperature uniformity at the bottom surface of the heat pipe while an uneven heat source up to 900 W was in contact. The temperature distribution over the bottom surface was monitored at more than twenty six locations. It was found that the operating performance of the sodium heat pipe was critically affected by the inner wall temperature of the condenser region where the working fluid may be changed to a solid phase unless the temperature was higher than its melting point. The maximum temperature difference across the bottom surface was observed to be $114^{\circ}C$ for 850 W thermal load and $100^{\circ}C$ coolant inlet temperature. The effects of fill charge ratio, coolant inlet temperature and operating temperature on thermal performance of heat pipe were analyzed and discussed.

Prismatic-core advanced high temperature reactor and thermal energy storage coupled system - A preliminary design

  • Alameri, Saeed A.;King, Jeffrey C.;Alkaabi, Ahmed K.;Addad, Yacine
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.248-257
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    • 2020
  • This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MWth. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO2 TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

Study on the Optimization Field Welding Conditions of Low Heat-Input Pluse MIG Welding Process for 5052 Aluminum Alloy Sheets (Al 5052 합금의 저입열 Pulse MIG 최적 현장 용접조건 산정에 관한 실험적 연구)

  • Kim, Jae-Seong;Lee, Young-Gi;An, Ju-Sun;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.29 no.1
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    • pp.80-84
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    • 2011
  • The weight reduction of the transportations has become an important technical subject Al and Al alloys, especially Al 5052 alloys have been being applied as door materials for automobile. One of the most widely known car weight-reduction methods is to use light and corrosion-resistant aluminum alloys. However, because of high electrical and thermal conductivity and a low melting point, it is difficult to obtain good weld quality when working with the aluminum alloys. Also, Pulse MIG welding is the typical aluminum welding process, but it is difficult to apply to the thin plate, because of melt-through and humping-bead. In order to enhance weld quality, welding parameters should be considered in optimizing the welding process. In this experiment, Al 5052 sheets were used as specimens, and these materials were welded by adopting new Cold Metal Transfer (CMT) pulse process. The proper welding conditions such as welding current, welding speed, torch angle $50^{\circ}$ and gap 0~1mm are determined by tensile test and bead shape. Through this study, range of welding current are confirmed from 100A to 120A. And, the range of welding speed is confirmed from 1.2m/min to 1.5m/min.

Solidification Cracking in Welds and its Control (용접부 응고균열 발생 및 제어)

  • Yoon, Jong-Won
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.22-22
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    • 2010
  • Eutectic composition phase with low melting point which solidifies at the final stage affects the solidification cracking at the intercellular or interdendritic area of welds and castings. If sufficient amount of eutectic composition liquid does not exist between the solidifying phases, the discontinuities remain as cracks. However, abundant amount of liquid eutectic composition existing in the final stage can flow into the discontinuities easily and heal the cracks. By flowing of liquid eutectic and healing of discontinuities, the possibility of cracking can be reduced when the amount of eutectic liquid is sufficient. For the solidification of pure metals, liquid eutectic does not exist and the interlocking of growing solid phases can be realized without interruption of liquid film. Therefore there is little possibility of solidification cracking in the case of welds and castings of pure metal. In a practical sense, the effective way to reduce or prevent the solidification cracking is making the composition of molten pool or melts near to the eutectic composition.

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Modeling of surface roughness in electro-discharge machining using artificial neural networks

  • Cavaleri, Liborio;Chatzarakis, George E.;Trapani, Fabio Di;Douvika, Maria G.;Roinos, Konstantinos;Vaxevanidis, Nikolaos M.;Asteris, Panagiotis G.
    • Advances in materials Research
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    • v.6 no.2
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    • pp.169-184
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    • 2017
  • Electro-Discharge machining (EDM) is a thermal process comprising a complex metal removal mechanism. This method works by forming of a plasma channel between the tool and the workpiece electrodes leading to the melting and evaporation of the material to be removed. EDM is considered especially suitable for machining complex contours with high accuracy, as well as for materials that are not amenable to conventional removal methods. However, several phenomena can arise and adversely affect the surface integrity of EDMed workpieces. These have to be taken into account and studied in order to optimize the process. Recently, artificial neural networks (ANN) have emerged as a novel modeling technique that can provide reliable results and readily, be integrated into several technological areas. In this paper, we use an ANN, namely, the multi-layer perceptron and the back propagation network (BPNN) to predict the mean surface roughness of electro-discharge machined surfaces. The comparison of the derived results with experimental findings demonstrates the promising potential of using back propagation neural networks (BPNNs) for getting a reliable and robust approximation of the Surface Roughness of Electro-discharge Machined Components.

Estimation of Directional Solidification Ingot with Heating Position (발열 위치에 따른 잉곳의 방향성 응고 평가)

  • Jun, Ho-Ik;Cho, Hyun-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.1915-1920
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    • 2013
  • This paper is the study for the directional solidification of the ingot through the thermal analysis simulation and structural change of casting furnace. With the results of thermal analysis simulation, the silicon as a whole has reached the melting temperature as the retention time 80 min. The best cooling conditions showed at the upper cooling temperature $1,400^{\circ}C$ and cooling time 60min. The fabricated wafers showed the superior etching result at the grain boundary than that of existing commercial wafers. The FTIR measurements of oxygen and carbon impurities were not in the critical value for solar conversion efficiency. The NAA analysis of metal impurities were also detected the total number of 18 different metals, but the concentration distribution showed no significant positional deviations in the same position from the top to the bottom.

Study of the Structure Change on Ion-Beam-Mixed CoPt Alloys.

  • Son, J.H.;Lee, Y.S.;Lim, K.Y.;Kim, T.G.;Chang, G.S.;Woo, J.J.;Whang, C.N.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.135-136
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    • 1998
  • By the ion bombardment the original discrete layered structure is damaged and a uniformly mixed layer is formed by the intermixing of the films. Immediately after this dynamic cascade mixing a structure of this mixed layer is likely to be a mixture of randomly distributed atoms. Subsequently the mixed layered structure becomes a non-equilibrium structure such as the metastable pphase because the kinetic energies of the incident ions rappidly dissippate and host atoms within the collision cascade region are quenched from a highly energetic state. The formation of the metastable transition metal alloys using ion-beam-mixing has been extensively studied for many years because of their sppecific ppropperties that differ from those of bulk materials. in ion-beam-mixing the alloy or comppound is formed due to the atomic interaction between different sppecies during ion bombardment. in this study the metastable pphase formed by ion-beam-mixing pprocess is comppared with equilibrium one by arc-melting method by GXRD and XAS. Therfore we studied the fundamental characteristics of charge redistribution uppon alloying and formation of intermetallic comppounds. The multi-layer films were depposited on a wet-oxidized Si(100) substrate by sequential electron beam evapporation at a ppressure of less than 5$\times$10-7 Torr during depposition. These compprise 4 ppairs of Co and ppt layers where thicknesses of each layer were varied in order to change the alloy compposition.

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The Effect of Internal Chills on the Solidified Structure and Chemical Segregation (응고조직 및 성분편석에 미치는 내부냉금의 효과)

  • Kim, Myeong-Han;Jo, Hyeon-Nam;Kim, Jeong-Gyeom;Jo, Hyeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.883-889
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    • 1999
  • The pure Al or-(1,2,3wt%)Cu alloy internal chill with 4,6,8,12 and 15mm ø, respectively, was inserted at the center of a graphite mold with the size of 95mm ø$\times$200mm H. The molten metal with the same composition as the internal chill was poured into the mold at the pouring temperature of $750^{\circ}C$ and the cooling rates, solidified structures and chemical segregation were analyzed. The results represented that there was remarkable increased in cooling rate as well as decrease in grain size, secondary dendrite arm spacing and chemical segregation as the ratio of ingot to internal chill diameter was increased to 8. However there was a considerable drop of the internal chill effect when this ratio exceeded 8, resulting from incomplete melting of internal chills. The optimum ratio for the maximum internal chill effect of pure Al and-(1,2,3wt%)Cu allolys was 8 at the given pouring temperature.

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Formation of Al3Ti From Mechanically Alloyed Hyper-Peritectic Al-Ti Powder (기계적 합금화법으로 제조된 과포정 Al-Ti 합금에서 Al3Ti 형성에 관한 연구)

  • Kim, Hye-Sung;Suhr, Dong-Soo;Kim, Gyeung-Ho;Kum, Dong-Wha
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.1
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    • pp.1-11
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    • 1996
  • Mechanical alloying is an effective process to finely distribute inert dispersoids in an Al-TM(TM is a transition metal) system. It has been considered that high melting point aluminides are formed by precipitation from supersaturated Al(Ti) powder. This analysis is based on the fact that much higher content of TM than the solubioity can be dissolved in alpha aluminum during the high energy ball milling. Thus, decomposition behavior of Ti in the Al(Ti) was considered very important. But it is confirmed that the higher portion of Ti than Al(Ti) solid solution is existed as nano-sized Ti particles in the MA powders by high energy ball nilling from the XRD spectrum and TEM analysis in this study. Therefore, the role of undissolved TM particles affect the formation of aluminides should be suitably considered. In this study, we present experimental observation on the formation of $Al_3Ti$ fron mechanical alloyed Al-Ti alloys in the hyperperitectic region. This study showed that, in the mechanically alloyed Al-20wt%Ti specimen, intermediate phase of cubic $Al_3Ti$ and tetragonal $Al_{24}Ti_8$ formed at $300{\sim}400^{\circ}C$ and $400{\sim}500^{\circ}C$, respectively, before the MA state reaches to equilibrium at higher temperatures. The formation behavior of $Ll_2-Al_3Ti$ is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiation the formation of $Al_3Ti$ phase during annealing.

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