• 제목/요약/키워드: metal flow

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TiO2에 담지된 금속 산화물 촉매상에서 TCE 산화분해반응 (Oxidative Decomposition of TCE over TiO2-Supported Metal Oxide Catalysts)

  • 양원호;김문현
    • 한국환경과학회지
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    • 제15권3호
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    • pp.221-227
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    • 2006
  • Oxidative TCE decomposition over $TiO_2$-supported single and complex metal oxide catalysts has been conducted using a continuous flow type fixed-bed reactor system. Different types of commercial $TiO_2$ were used for obtaining the supported catalysts via an incipient wetness technique. Among a variety of titanias and metal oxides used, a DT51D $TiO_2\;and\;CrO_x$ would be the respective promising support and active ingredient for the oxidative TCE decomposition. The $TiO_2-based\;CrO_x$ catalyst gave a significant dependence of the catalytic activity in TCE oxidation reaction on the metal loadings. The use of high $CrO_x$ contents for preparing $CrO_x/TiO_2$ catalysts might produce $Cr_2O_3$ crystallites on the surface of $TiO_2$, thereby decreasing catalytic performance in the oxidative decomposition at low reaction temperatures. Supported $CrO_x$-based bimetallic oxide systems offered a very useful approach to lower the $CrO_x$ amounts without any loss in their catalytic activity for the catalytic TCE oxidation and to minimize the formation of Cl-containing organic products in the course of the catalytic reaction.

Recent Trends in the Biosorption of Heavy Metals: A Review

  • Sag, Yesim;Kutsal, Tulin
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제6권6호
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    • pp.376-385
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    • 2001
  • Considerable attention has been focused in recent years upon the field of biosorption for the removal of metal ions from aqeous effluents. Compared to other technologies, the advan-tages of biosortption are the high purity of the treated waste water and the cheap raw material. Really, the first major challenge for the biosorption field is to select the most promising types of biomass. Abundant biomass types either generated as a waste by-product of large-scale industrial fermentations particularly fungi or certain metal-binding seaweeds have gained importance in re-cent years due to their natural occurrence, low cost and, of course good performance in metal biosorption. Industrial solutions commonly contain multimetal systems or several organic and in organic substances that form complexes with metals at relatively high stability forming a very complex environment. When several components are present, interference and competition phe-nomena for sorption sites occur and lead to a more complex mathematical formulation of the process. The most optimal configuration for continuous flow-biosorption seems to the packed-bed column which gets gradually from the feed to the solution exit end. Owing to the com-petitive ion exchange taking place in the column, one or more of the metals present even at trace levels may overshot the acceptable limit in the column effluent before the breakthrough point of the trargeted metal. Occurrence of 'overshoot's and impact on havey metal removal has not been analyzed enough. New trends in biosorption are discussed in this review.

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3D 프린팅 된 금속-고분자 맞물림 구조의 유도 가열 공정을 이용한 접합 기술 연구 (A Study on Joining Technology of 3D Printed Metal-polymer Interlocking Structures Using an Induction Heating Process)

  • 육주찬;김영서;박석희
    • 한국기계가공학회지
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    • 제21권2호
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    • pp.87-93
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    • 2022
  • The demand for metal-polymer joining technology have been increasing, especially in the industrial fields of automotive and aerospace, which require the manufacturing of various lightweight parts. Conventional joining processes have technical hurdles on aspects such as thermal degradation, need for chemical surface treatment, or complicated process settings. These issues can be alleviated by employing interlocking structures for the metal-polymer joined interface. In this study, we joined 3D-printed metal and polymer parts, which were featured with 3D-printed interlocking structures at their interface. By using high frequency induction heating, the joined region could be locally heated to reduce the thermal degradation and distortion of polymer parts. In addition, through the adjustment of interface morphologies and compression conditions, the polymer flow could be optimized to completely fill the interlocking grooves on metal parts, thereby achieving high joining strength. This suggests feasible guidelines for manufacturing metal-polymer joined structures involving 3D-printed architectures.

용탕주조법을 이용한 금속복합재료 제조공정의 열전달 해석 (Numerical Modeling of Heat Transfer for Squeeze Casting of MMCs)

  • 정창규;변현중;정성욱;남현욱;한경섭
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.319-324
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    • 2001
  • A finite element model for the process of squeeze casting for metal matrix composites (MMCs) in cylindrical mold is developed. The fluid flow and the heat transfer are the fundamental phenomena in the squeeze casing process. To describe heat transfer with solidification of molten aluminum, the energy equation in terms of temperature and enthalpy are applied to two dimensional axisymmetric model which is similar to the experimental system. And one dimensional flow model is employed to simulate the transient metal flow. The direct iteration technique was used to solve the resulting nonlinear algebraic equations. A computer program is developed to calculate the enthalpy, temperature and fluid velocity. Cooling curves and temperature distribution during infiltration and solidification are calculated for pure aluminum. The temperature is measured and recorded experimentally. At two points of the perform inside and one point of the mold outside, thermocouple wire are installed. The time-temperature data are compared with the calculated cooling curves. The experimental results show that the finite element model can estimate the solidification time and predict the cooling process.

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A MECHANISM OF DEEP WELD PENETRATION IN GAS TUNGSTEN ARC WELDGING WITH ACTIVATING FLUX

  • Manabu Tanaka;Hidenori Terasaki;Masao Ushio;John J. Lowke;Yang, Chun-Li
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.76-81
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    • 2002
  • The dramatic increase in the depth of a weld bead penetration has been demonstrated by welding a stainless steel in GTA (Gas-Tungsten-Arc) process with activating flux which consists of oxides and halides. However, there is no commonly agreed mechanism fer the effect of flux on the process. In order to make clear the mechanism, each behavior of the arc md the weld pool in GTA process with activating flux is observed in comparison with a conventional GTA process. A constricted anode root is shown in GTA process with the activating flux, whereas a diffuse anode root is shown in the conventional process. These anode roots are related strongly to metal vapor from the weld pool and the metal vapor is also related to temperature distributions on the weld pool surface. Furthermore, it is suggested that a balance between the Marangoni force and the drag force of the cathode jet should dominate the direction of re-circulatory flow in the weld pool. The electromagnetic force encourages the inward re-circulatory flow due to the constricted anode root in the case with flux. The difference in flow direction in the weld pool changes the geometry or depth/width ratio of weld bead penetration.

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Cut Cell을 고려하는 주조유동 해석 방법 (NUMERICAL METHOD FOR MOLTEN METAL FLOW SIMULATION WITH CUT CELL)

  • 최영심;홍준호;황호영
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2011년 춘계학술대회논문집
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    • pp.518-522
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    • 2011
  • Cartesian grid system has mainly been used in the casting simulation even though it does not nicely represent sloped and curved surfaces. These distorted boundaries cause several problems. A special treatment is necessary to clear these problems. A cut cell method on Cartesian grids has been developed to simulate three-dimensional mold filling Cut cells at a cast-mold interface are generated on Cartesian grids. Governing equations were computed using volume and areas of cast at cut cells. In this paper, we propose a new method that can consider the cutting cells which are cut by casting and mold based on the patial cell treatment (PCT). This method provides a better representation of geometry surface and will be used in the computation of velocities that are defined on the cell boundaries in the Cartesian gird system. Various test examples for several casting process were computed and validated. The analysis results of more accurate fluid flow pattern and less momentum loss owing to the stepped boundaries in the Cartesian grid system were confirmed. We can know the momentum energy at the cut cell is conserved by using the cut cell method. By using the cut cell method. performance of computation gets better because of reducing the whole number of meshes.

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