• 한국진공학회지
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• 제7권s1호
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• pp.30-36
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• 1998

The plasma-spray technique is currently the most frequently used method to produce calcium phosphate coatings. Hydroxyapatite(HAp), one form of calcium phosphate, is preferred by its ability to form a direct bond with living bone, resulting in improvements of implant fixation and faster bone healing. Recently, concerns have been raised regarding the viable use and long-term stability of plasma-spray HAp coatings due to its nature of comparatively thick, porous, and poor bonding strength to metal implants. Thin layers (maximum of few microns) of calcium phosphate were formed by an e-beam evaporation with and without ion bombardments. The Ca/P ration of film was controlled by either using the evaporants having the different ration of Ca/P with addition of CaO, or adjusting the ion beam assist current. The Ca/P ration had great effects on the structure formation after heat treatment and the dissolution bahavior. The calcium phosphate films produced by IBAD exhibited high adhesion strength.

• Journal of Microbiology and Biotechnology
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• 제14권3호
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• pp.607-611
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• 2004

Glycinin, one of the predominant storage proteins in soybeans, was examined as to whether it could be used as a calcium-binding mediator after chemical phosphorylation and enzymatic hydrolysis. Glycinin is composed of six subunits. One of the proglycinin subunits $(A_{la}B_{lb})$ was overexpressed in E. coli to obtain nonphosphorylated proteins with homogeneity. To investigate the enhanced calcium-binding properties of the phosphopeptides, the proglycinin was purified, phosphorylated, and hydrolyzed with trypsin. The proglycinin expressed in E. coli was purified by ammonium sulfate precipitation, ion-exchange chromatography, and cryoprecipitation. Chemical phosphorylation by sodium trimetaphosphate was performed to obtain phosphorylated proglycinin. After the phosphorylation, one-dimensional isoelectric focusing gel electroanalysis confirmed the phosphorylation of the proglycinin. The phosphorylated peptides were then hydrolyzed with trypsin, followed by a binding reaction with calcium chloride. The calcium-bound phosphopeptides were finally separated using immobilized metal $(Ca^{2+})$ chromatography. Consequently, a limited tryptic hydrolysate of the isolated phosphopeptides exhibited an enhanced calcium-binding ability, suggesting the potential of glycinin phosphopeptides as a calcium-binding mediator with greater availability.

• 산업기술연구
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• 제29권A호
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• pp.55-60
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• 2009

Stabilization treatment is one of processes for wastes and their components to reduce their toxicity and migration rates to surroundings. Inorganic binders such as calcium hydroxide, blast furnace slag and red mud were tested for their potential applicability to in-situ stabilization of heavy metal contaminated tailings in the abandoned metal mines. Columns(150mm dia. ${\times}$ 450mm length) filled with mixtures of inorganic binders and tailing from the Geumjang mine with various mixing ratios of binders to tailings, 5%, 7% and 9% were applied artificial rainfall tests for 28 days. Effluents from columns filled with calcium hydroxide and tailing showed high pH's of ~12.5 and a increasing trend of concentration in Pb and Zn with a significant decrease in permeability in terms of elapsed days. Those with burning slag and tailing showed pH's of ~8.5 and significantly low concentrations in heavy metals with a stable permeability. In case of red mud, effluents showed significantly low concentrations in heavy metals but a decreased permeability with pH's of ~10.5. Conclusively, this basic study suggests burning furnace slag be a potential stabilizer for effective treatment of heavy metal contaminated mine tailings.

• 천문학논총
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• 제30권2호
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• pp.489-490
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• 2015

We present population synthesis models for the calcium II triplet (CaT), currently the most popular metallicity indicator, based on high-resolution empirical spectral energy distributions (SEDs). Our new CaT models, based on empirical SEDs, show a linear correlation below [Fe/H] ~ -0.5, but the linear relation breaks down in the metal-rich regime by converging to the same equivalent width. This relation shows good agreement with the observed CaT of globular clusters (GCs) in NGC 1407 and the Milky Way. However, a model based on theoretical SEDs does not show this feature of the CaT and fails to reproduce observed GCs in the metal-rich regime. This linear relation may cause inaccurate metallicity determination for metal-rich stellar populations. We have also confirmed that the effect of horizontal-branch stars on the CaT is almost negligible in models based on both empirical and theoretical SEDs. Our new empirical model may explain the difference between the color distributions and CaT distributions of GCs in various early-type galaxies. Based on our model, we claim that the CaT is not a good metallicity indicator for simple stellar populations in the metal-rich regime.

• 대한치과교정학회지
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• 제37권5호
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• pp.376-385
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• 2007

고정성 장치를 이용한 교정 치료는 심미적 개선이 주목적 중 하나이나, 금속재 브라켓은 치료기간 동안 비심미적으로 보이는 단점이 있다. 이러한 이유로 치아색과 유사한 심미적 브라켓이 선호되었으나 호선과의 마찰저항이 금속재 브라켓보다 큰 것으로 알려져 있다. 본 연구는 최근 개발된 심미적 브라켓의 일종인 인산칼슘재 브라켓의 마찰저항을 측정하고 기존 금속재 브라켓과 금속슬롯 삽입형 도재 브라켓과의 마찰저항의 차이를 구명(究明)해 보고자 하였다. 실험군으로서 인산칼슘 재질의 Hyaline II (Tomy, Tokyo, Japan) 브라켓을, 대조군으로서 metal slot이 삽입된 도자기 재질인 Clarity (3M Unitek, Monrovia, CA, USA) 브라켓과 스테인레스 스틸 금속재 브라켓인 Kosaka (Tomy, Tokyo, Japan) 브라켓을 사용하고, $0.019\;{\times}\;0.025$ 인치 스테인레스 스틸 강선 (3M Unitek, Monrovia, CA, USA)을 이용하며 결찰재는 합성고무링 (Ormco, Glendora, CA, USA)을 사용하였다. 치아의 생리학적 환경을 재현하기 위해 모의 생물학적 모형을 고안하였으며 이에 강선을 삽입하여 load cell (Push & pull gauge, RX-2 AIKOH, Osaka, Japan)로 분당 5 mm로 견인하며 만능시험기(Instron4467, Instron, Norwood, MA, USA)로 마찰저항을 측정하였다. 실험결과, 실험군인 인산칼슘 재질 브라켓의 마찰저항은 대조군인 금속슬롯 삽입형 도재 브라켓 보다 작고 (p < 0.01) 금속재 브라켓의 마찰저항보다 크게 나타나 (p < 0.05), 인산칼슘재 브라켓은 심미적 측면에서 금속재 브라켓을, 효율적 측면에서 금속슬롯 삽입형 도재 브라켓을 대체하여 사용 가능함을 시사하였다.

• 한국재료학회지
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• 제17권8호
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• pp.408-413
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• 2007

Process of the hydroxyapapite(HA) precipitation on bioactive titanium metal prepared by NaOH in a modified-simulated body fluid(mSBF) was investigated by high resolution transmission electron microscope (HRTEM) attached with energy dispersive X-ray spectrometer(EDX). The amorphous titanate phase on titanium surface is form by NaOH treatment and an amorphous titanate incorporated calcium and phosphate ions in the liquid to form an amorphous calcium phosphate. With increasing of soaking time in the liquid, the HA particles are observed in amorphous calcium phosphate phase with a Ca/P atomic ratio of I.30. The octacalcium phosphate (OCP) structure is not detected in HRTEM image and electron diffraction pattern. After a long soaking time, the HA particles grow as needle-like shape on titanium surface and a large particle-like aggregates of needle-like substance were observed to form on titanium surface within needle-like shape. A long axis of needle parallels to c-direction of the hexagonal HA structure.

• 분석과학
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• 제18권6호
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• pp.491-494
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• 2005

The main component governing selectivity in ion-selective electrodes and optodes is the ionophore. For this reason, a member of natural products that possess selective ion-binding properties have long been sought after. By applying this principle, the performance of cyclosporin used as neutral carriers for calcium selective polymeric membrane electrode was investigated. The calcium ion-selective electrode based on cyclosporin gave a good Nernstian response of 26.6 mV per decade for calcium ion in the activity range $1{\times}10^{-6}M$ to $1{\times}10^{-2}M$. The optimized calcium ion-selective electrode displayed very comparable selectivity for $Ca^{2+}$ ion against alkali and alkaline earth metal ions, $Na^{2+}$, and $Mg^{2+}$ in particular.

• Korean Chemical Engineering Research
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• 제59권2호
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• pp.219-224
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• 2021

Ion flotation is an efficient method to remove metal ions from aqueous solution. In this work, ion flotation was applied to calcium removal from aqueous solution. The parameters used included sodium stearate (SS) and sodium dodecyl sulfate (SDS) as collectors, 1-butanol and 1-propanol as frothers, pH, and air-flow rate. An L16 orthogonal array was chosen according to the mentioned factors and levels, and experimental tests were conducted according to the Taguchi orthogonal array. The results showed that all of the factors except one had significant effect on the flotation performance. The percentage contribution of parameters showed that type of frother and type of collector made the greatest (43.14%) and the lowest (9.86%) contribution, respectively. In optimal conditions, the recovery of Ca (II) ion was 45.67%. Also, the results illustrated that the Taguchi method could predict calcium removal from aqueous solution by ion flotation with 2.63%. This study showed that the use of ion flotation was an effective method for Ca (II) ion removal from aqueous solution.

• 한국식품위생안전성학회지
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• 제2권4호
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• pp.201-208
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• 1987

The effects of ginseng on the blood biochemical components of heavy metals poisoning in mice were examined and following results were obtained. Albumin was decreased slightly in the heavy metal administration groups. But Serum Calcium, Glucose were almost the same as that of control group during the period. Heavy metal poisoning mice showed low levels of serum Total protein and A/G ratio. They also showed high levels of serum GOT, GPT, BUN, Cholesterol, Creatinine and Triglycerides. However, the administration of ginseng significantly inhibited the elevation of them.

• 대한금속재료학회지
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• 제47권3호
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• pp.182-187
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• 2009

The molten salt electrolysis is applied to reduce titanium dioxide to titanium metal using calcium chloride as an electrolyte and the reaction mechanism of the reduction process is examined by analyzing the reaction products. The process conditions to obtain titanium metal for $900^{\circ}C$ correspond to 2.9~3.2 V and 24 hours. The reaction products for 2.9 V at $900^{\circ}C$ include irregular-shaped titanium oxides such as $Ti_4O_7$, $Ti_3O_5$ and $Ti_2O_3$ and polyhedral $CaTiO_3$. Using these microstructure analysis, the sequential reaction mechanism for the electrochemical reduction of titanium dioxide to titanium is proposed.