• 제목/요약/키워드: mesogen

검색결과 66건 처리시간 0.027초

Study on Electro-opt ic Characteristics in the Optically Compensated Splay Cell with UV-curable Reactive Mesogen

  • Kim, Seong-Su;Jeon, Eun-Jeong;Lee, Myong-Hoon;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.327-329
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    • 2008
  • We have studied the optically compensated splay (OCS) mode using reactive mesogen monomer to reduce critical voltage, setting voltage and phase transition time from initial bend to splay state. The high pretilt angle from vertical alignment was formed through the polymerization of UV curable RM monomer at the surfaces. In this way, orientation of the LC with OCS can be achieved without setting voltage.

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Synthesis and Mesomorphism of Polymers with Banana-Shaped Mesogens in the Main Chain

  • Choi, E-Joon;Zin, Wang-Cheol;Kim, Young-Chul;Paek, Sang-Hyon;Chien, Liang-Chy;Samulski, Edward T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.171-174
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    • 2006
  • In this work, we report the synthesis and characterization of azomethine-ester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.

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Reactive Mesogen Mixtures for Integrated Optical Films

  • Lee, Hee-Kyu;Lee, Seung-Eun;Cumming, S.A.;Verrall, M.;Parri, O.;Harding, R.;Marden, S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.266-269
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    • 2003
  • TFT LCD mode has some well-documented performance limitations, namely limited viewing angle, inversion of the gray scale levels and poor luminance efficiency because of the necessity of using crossed polarisers attached to the display cell. During the last few years many initiatives have been undertaken to solve these problems by incorporation birefringent films of various designs into the LCD module. Controlling the optical performance of LCDs often requires combination of liquid crystal material properties, cell parameters and optical films. Such optical films have traditionally been made with stretched polymer materials such as polycarbonate, but recently coated liquid crystalline materials have been used to give improved optical films which can greatly enhance the performance of LCDs. We have now developed reactive mesogen materials to add ultra-thin optical layers into the display structure, and these allow the potential for many new applications.

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Flexible bistable chiral splay nematic display mode using reactive mesogens

  • Bae, Kwang-Soo;Lee, You-Jin;You, Chang-Jae;Kim, Jae-Hoon
    • Journal of Information Display
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    • 제12권4호
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    • pp.195-198
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    • 2011
  • Proposed herein is a flexible bistable chiral splay nematic display mode with an enhanced memory retention time under external distortion. By adopting the polymerized reactive-mesogen structure mixed in a liquid crystal layer, local anchoring energy is generated on the boundary between the polymer structures, and the relaxation from the ${\pi}$-twisted state to the initial splay state could be interrupted. As a result, the memory retention time becomes significantly longer, and the stability against the external distortion is enhanced.

Synthesis and Liquid Crystalline Properties of Hyperbranched Aromatic Polyesters Consisting of Azoxybenzene Mesogens and Polymethylene Spacers

  • Park, Young-Suk;Lee, Jun-Woo;Jin, Jung-Il
    • Bulletin of the Korean Chemical Society
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    • 제23권9호
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    • pp.1201-1210
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    • 2002
  • A new series of hyperbranched aromatic polyesters containing azoxybenzene mesogens and polymethylene spacers were prepared by polymerizing AB2 type monomers that have the isophthaloyl dicarboxylic acid terminal at one end and the p-oxyp henol terminal at the other end. The monomers contain a built-in azoxybenzene mesogen that is linked to the terminal groups through polymethylene spacers. The polyesters prepared were characterized by solution viscosity, differential scanning calorimetry, X-ray diffractometry and polarizing microscopy. All of the polyesters were found to be thermotropic (nematic). Their glass-transition temperatures and mesophase temperature ranges were very sensitive to the length of the two spacers existing in the repeating unit. The degree of branching of one of the polyesters was determined by the NMR spectroscopy and found to be 0.56.

광경화성 단분자를 이용한 Z-shape PVA 모드에서의 투과율 향상에 관한 연구 (Electro-optical characteristics of PVA (Z-shape) mode using the UV curable reactive mesogen (RM))

  • 조인영;황성진;김성민;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.437-438
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    • 2008
  • The Conventional patterned vertical alignment (PVA) device shows a very high contrast ratio at normal direction and does not require rubbing process. However it has a disclination area in which the liquid crystal can be collision in the boundary domain region. In this paper, we studied PVA(Z-shape) device in which the liquid crystal can be tilted down in multiple directions stably because the surface pretilt angle is controlled by photopolymerization of the UV - curable reactive mesogen (RM) under a proper condition. Consequently, the device shows improved electro optical properties as compared to conventional PVA mode.

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ECB 셀에서 UV 경화성 RM 단분자에 의한 선경사각 조절 및 전기적 특성에 관한 연구 (Study on Controlling Pretilt Angle and Electrical Characteristics in ECB cell by Polymerized Reactive Mesogen monomer)

  • 전은정;김성수;임영진;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.397-398
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    • 2008
  • We have studied the electrically controlled birefringence (ECB) mode using reactive mesogen (RM) monomer to control pretilt angle and improve electrical characteristics. The measure of capacitance confirmed new pretilt angle by RM monomer, and Voltage Holding Ratio (VHR) was increased more than normal ECB cell.

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Synthesis and Characterization of New Azomethine Polymers Containing Bent-Core Mesogen with Sharp Bend Angle

  • Kim, Eun-Chol;Choi, E-Joon;Ok, Chang-Woo;Zin, Wang-Choel
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.553-555
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    • 2007
  • Six azomethine polymers containing bent-core mesogen were synthesized with variation of a bent structure of central core (1,2-dioxyphenylene or 2,3-dioxynaphthylene), and a lateral halogen substituent (X = H, F or Cl ). The properties of the polymers were characterized by FT-IR, NMR spectroscopy, DSC, polarizing optical microscopy, and X-ray diffractometry.

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반응성 메조겐을 이용한 폴리머 광도파로 편광 변환기 (Integrated Optical Wave Plates Fabricated by Incorporating Reactive Mesogen in Polymer Waveguide)

  • 도현수;추우성;오민철
    • 한국광학회지
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    • 제22권5호
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    • pp.219-222
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    • 2011
  • 광도파로에 일체형으로 제작 가능한 편광 변환기는 다양한 기능의 광집적회로를 구성하기 위한 필수적인 부품이다. 반응성 메조겐은 액정디스플레이의 파장판 제작을 위하여 널리 사용되는 재료이며, 본 연구에서는 반응성 메조겐과 폴리머 광도파로를 이용하여 집적형 편광 변환기를 제작하였다. 반응성 메조겐과 액정을 혼합한 용액을 광도파로에 직교하게 형성된 홈에 삽입하고 전계를 인가하여 액정 분자를 특정 방향으로 정렬 한 뒤 UV 를 조사하여 RM 분자를 경화시켜주면 광도파로를 가로지르는 파장판을 형성할 수 있다. 파장판의 특성은 두께를 결정짓는 홈의 폭과 액정 분자의 정렬 상태 및 복굴절 크기에 의해 결정된다. 폴리머 광도파로의 중앙에 제작된 편광변환기는 1550 nm 파장에서 편광변환효율이 90 %에 이르게 됨을 확인하였다.