• Title/Summary/Keyword: mercury intrusion porosimetry (MIP)

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Comparison of the Mercury Intrusion Porosimerty, Capillary Flow Porometry and Gas Permeability of Eleven Species of Korean Wood

  • Jang, Eun-Suk;Kang, Chun-Won;Jang, Sang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.6
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    • pp.681-691
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    • 2018
  • The typical methods of mercury intrusion porosimetry (MIP) and capillary flow porometry (CFP) were used to evaluate the pore size of cross-section of wood and the effect of the pore structure on the permeability of wood was analyzed in this study. The results of this study were as followings: The pore size of wood measured by CFP was larger than that measured by MIP except for Lime tree, Korean red pine and Paulownia. Among the three pore types of porous materials defined by IUPAC (through pores, blind pores, and closed pores), only through pores are related to permit fluid flow. MIP measures the pore size of both through pores and blind pores, while CFP measures the pore size of only constricted through pores. Therefore, pore size measured by MIP was not related to gas permeability, however pore size measured by CFP had a proportional relationship with gas permeability.

A Study on the Compressive Strength & Pore Structure of Shotcrete using for Mine Ready-mixed Materials (광산용 레디믹스트 재료를 사용한 숏크리트의 압축강도 및 공극구조에 대한 고찰)

  • Lee, Heung-Soo;Kim, Dong-Min;Choi, Seung-Kyung;Lee, Ju-Hoe
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1517-1521
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    • 2009
  • A variation of pore structure of shotcrete matrix was experimented by Mercury Intrusion Porosimetry, and the relation with compressive strength was also examined. As a result of the Mercury Intrusion Porosimetry(MIP) test, RM-P1 Batch the macropore diameter of the RM-BFS2 and RM-BFS3 Batch than to have a relatively macropore can see a lot of long-term durability performance degradation. Also, K and N Batch the current is applied to the mine if the factors on shotcrete durability performance of the macropore volume of the entire appears to be a long-term durability performance in the fall.

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A simplified directly determination of soil-water retention curve from pore size distribution

  • Niu, Geng;Shao, Longtan;Sun, De'an;Guo, Xiaoxia
    • Geomechanics and Engineering
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    • v.20 no.5
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    • pp.411-420
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    • 2020
  • Numbers fitting-curve equations have been proposed to predict soil-water retention curve (SWRC) whose parameters have no definitude physical meaning. And these methods with precondition of measuring SWRC data is time-consuming. A simplified directly method to estimate SWRC without parameters obtained by fitting-curve is proposed. Firstly, the total SWRC can be discretized into linear segments respectively. Every segment can be represented by linear formulation and every turning point can be determined by the pore-size distribution (PSD) of Mercury Intrusion Porosimetry (MIP) tests. The pore diameters governing the air-entry condition (AEC) and residual condition (RC) can be determined by the PSDs of MIP test. The PSD changes significantly during drying in SWR test, so the determination of AEC and RC should use the PSD under corresponding suction conditions. Every parameter in proposed equations can be determined directly by PSD without curve-fitting procedure and has definitude physical meaning. The proposed equations give a good estimation of both unimodal and bimodal SWRCs.

Realistic pore structure of Portland cement paste: experimental study and numerical simulation

  • Ma, Hongyan;Li, Zongjin
    • Computers and Concrete
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    • v.11 no.4
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    • pp.317-336
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    • 2013
  • In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

Pore Structure and Heat of Microhydration Analysis of Blast Furnace Slag Containing Alkaline Activator (알칼리 자극제 혼입 고로슬래그 미분말의 공극구조 및 미소수화열 분석)

  • Park, Ji-Woong;Park, Hee-Gon;Kim, Woo-Jae;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.20-21
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    • 2017
  • In this study, fundamental properties by pore structure and heat of microhydration test were determined. As a result of pore structure analysis, BS(AA) specimen showed showed the maximum peak value of significantly lower incremental intrusion than the maximum peak value of incremental intrusion at smaller pore size than that of BS. As a result of heat of microhydration test, the maximum heating value was in the order of OPC > BS > BS(AA), and initial drying shrinkage and compressive strength of BS(AA) were expected to be improved.

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A Study on the Drain Performance & Pore Structure of Cellular Mortar which Drain Material of the Composite Lining Method (Composite 라이닝 공법의 배수공 재료인 경량기포모르타르의 공극구조와 배수성능에 대한 고찰)

  • Choi, Hee-Sup;Ma, Sang-Joon;Lee, Heung-Soo;Seo, Shin-Seok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.425-426
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    • 2009
  • As a result of the Mercury Intrusion Porosimetry(MIP) test, FCR Batch with the continuous voids in excellent permeability is appeared with the Cellular Mortar that is most suitable which Drain Material of the Composite Lining Method.

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Effect of curing temperature on microstructure of blast furnace slag concrete (양생온도가 고로슬래그 콘크리트의 미세구조에 미치는 영향)

  • Lee, Kyu-Dong;Lee, Chang-Soo;Seol, Jin-Seong;Jun, Myeong-Il
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.817-820
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    • 2006
  • This study investigated on the differentiation of microstructure of blast furnace slag concrete(BBSC) using Mercury Intrusion Porosimetry(MIP). From the test result, it was found that the BBSC did not show shortcomings of high temperature curing. The BBSC gives more fineness microstructure than that of plain concrete when it is cured same curing condition. The curing age making stable structure to poor surroundings was 28, 14, 7 days for blast furnace concrete cured at 5, 20, $30^{\circ}C$, respectively.

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Experimental study of the effect of microstructure on the permeability of saturated soft clays

  • Chen, Bo;Sun, De'an;Jin, Pan
    • Geomechanics and Engineering
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    • v.18 no.1
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    • pp.49-58
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    • 2019
  • The effect of microstructure on the permeability of two saturated marine clays was studied through a series of falling head permeability tests and mercury intrusion porosimetry (MIP) tests. The key findings from this experimental study include the following results: (1) The permeability of undisturbed specimens is larger than that of reconstituted specimens at the same void ratio due to different soil fabrics, i.e., the pore size distributions (PSDs), even though they have the similar variation law in the permeability versus void ratio. (2) Different permeabilities of undisturbed and reconstituted specimens at the same void ratio are mainly caused by the difference in void ratio of macro-pores based on the MIP test results. (3) A high relevant relation between $C_k$ ($C_k$ is the permeability change index) and $e*_{10}$, can be found by normalizing the measured data both on undisturbed or reconstituted specimens. Hence, the reference void ratio $e*_{10}$, can be used as a reasonable parameter to identify the effect of soil fabric on the permeability of saturated soft clays.

Effects of dry density and water content on compressibility and shear strength of loess

  • Guo, Yexia;Ni, Wankui;Liu, Haisong
    • Geomechanics and Engineering
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    • v.24 no.5
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    • pp.419-430
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    • 2021
  • Investigation on the compressibility and shear strength of compacted loess is of great importance for the design and operation of engineering infrastructures in filling area. In this study, the mechanical behaviors of Yan'an compacted loess are investigated at various dry densities and water contents by conducting one dimensional compression and direct shear tests. And the elastic compressibility, plastic compressibility, yield stress and strength are obtained from the experiments. Results show that when water content increases, plastic compressibility parameter increases, but yield stress decreases. However, the increase of dry density leads to a decrease in plastic compressibility parameter but an increase in yield stress. In addition, elastic compressibility parameter is found to be a constant which is irrelevant to water content and dry density. As for strength, cohesion and internal friction angle is directly proportional to dry density, but inversely proportional to water content. Moreover, the mercury intrusion porosimetry (MIP) and scanning electron microscope (SEM) tests were also performed to observe the pore size distribution and microstructure of the specimens. Finally, by using results of MIP and SEM tests, the compressibility and strength behaviours of Yan'an compacted loess are explained from the perspective of pore-size distribution and microstructure.

Effect of Phosphate-to-binder and Water-to-binder Ratio on Magnesia-potassium Phosphate Cement (마그네시아-인산칼륨 시멘트에 대한 인산염 비 및 물-결합재비의 영향)

  • Lee, Kyung-Ho;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.275-281
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    • 2017
  • This study examined the effect of water-to-binder ratio (W/B) and phosphate-to-binder ratio (P/B) on the flow, setting time, compressive strength development, and pH variation of magnesium-potassium phosphate composites, MKPC mortars. Ten mortars mixtures were prepared with the W/B varying from 20% to 40% at each P/B of 0.3 or 0.5. The hydration products and microstructural pore distribution of the MKPC pastes were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). The initial flow and setting time of MKPC mortars tended to decrease with an increase of P/B, indicating that the final setting time was shortened by approximately 24% when P/B increased from 0.3 to 0.5. The slope of the early-strength development measured in the MKPC mortars was considerably higher than that of cement concrete specified in code provisions. For obtaining a relatively good 28-day strength (above 30 MPa) and a near neutral pH (below 9.0) in MKPC mortars, the P/B and W/B need to be selected as 0.5 and 30%, respectively. The strubite-K crystal increased with the increases of P/B and W/B, which leads to the decrease of the macro-capillary pores.