• Title/Summary/Keyword: membrane resistance

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Prediction of Membrane Fouling Index by Using Happel Cell Model (Happel Cell 모델을 이용한 막오염 지수 예측)

  • Park, Chanhyuk;Kim, Hana;Hong, Seungkwan
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.632-638
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    • 2005
  • Membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI) is an important parameter in design of the integrated RO/NF membrane processes for drinking water treatment. In this study, the effect of particle, membrane and feed water characteristics on membrane fouling index were investigated systematically. Higher fouling index values were observed when filtering suspensions with smaller particle size and higher feed particle concentration. Larger membrane resistance due to smaller pore size resulted in an increased membrane fouling index. The variations of feed water hardness and TDS concentrations did not show any impact on fouling index, suggesting that there were no significant colloidal interactions among particles and thus the porosity of particle cake layer accumulated on the membrane surface could be assumed to be 0.36 according to random packing density. Based on the experimental observations, fundamental membrane fouling index model was developed using Happel Cell. The effect of primary model parameters including particle size ($a_p$), particle concentration ($C_o$), membrane resistance ($R_m$), were accurately assessed without any fitting parameters, and the prediction of membrane fouling index such as MFI exhibited very good agreement with the experimental results.

The Effects of Kanendomycin on the Potassium Permeability of the Rabbit Erythrocyte Membrane (Kanendomycin이 토끼 적혈구막의 포타슘 투과에 미치는 영향)

  • Kim, Jung-Han
    • The Korean Journal of Physiology
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    • v.8 no.1
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    • pp.45-53
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    • 1974
  • The effects of kanendomycin on the potassium permeability in the rabbit erythrocyte membrane are investigated and the results are summarized as follows. 1. Kanendomycin causes the efflux of $K^+\;and\;influx\;of\;Na^+$ across the rabbit erythrocyte membrane. 2. Osmotic resistance of kanendomycin treated erythrocytes is diminished. This diminution of osmotic resistance is more pronounced by increasing concentration of kanendomycin and longer incubation time. But osmotic resistance is rather increased in the presence of lower concentration of kanendomycin. 3. Cysteine and glutathione have little influence on $K^+$ efflux induced by kanendomycin. 4. EDTA has no effect on the increase in $K^+$ outflux by kanendomycin while PCMB augments slightly on $K^+$ outflux. 5. Kanendomycin inhibits $Ca^{++}$ binding competitively to rabbit erythrocyte membrane fragments.

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Pervaporation Separation of Water/Ethanol Mixtures through PBMA/anionic PAA IPN Membrane

  • Jin, Young-Sub;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.86-87
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    • 1996
  • IPN (Interpenetrating Polymer Network) is a mixture of two or more crosslinked polymers with physically interlocked network structures between the component polymers. IPN can be classified as an alloy of thermosets and has the characteristics of thermosets such as the thermal resistance and chemical resistance and also has the characteristics of polymer alloys with enhanced impact resistance and amphoteric properties. The physical interlocking during the synthesis restricts the phase separation of the component polymer with chemical pinning process, thus the control of morphology is possible through variations of the reaction temperature and pressure, catalyst concentration and crosslinking agent concentration. Finely dispersed domain structure can be obtained through IPN synthesis of polymer components with gross immiscibility. In membrane applications, particularly for the separation of liquid mixtures, crosslinked polymer component with specific affinity to the permeate is needed. With the presence of the permeant-inert polymer component, the mechanical strength and the selectivity of the membranes are enhanced by restricting the swelling of the transporting polymer component networks.

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Permeation Behavior of Surfactant through Membrane (계면활성제의 분리막에 대한 투과거동)

  • Ahn, Soon-Cheol;Lee, Kwang-Rae;Kim, Ki-Chang
    • Journal of Industrial Technology
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    • v.18
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    • pp.259-265
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    • 1998
  • The molecular weights of surfactant SDS(M.W. 288) and SLS(M.W. 420) are smaller than the molecular weigh cut-off of cellulose acetate membrane used in this study. However, 20% of SDS and 67% of SLS were rejected by cellulose aectate membrane. The higher rejection rate of SLS than that of SDS is due to the longer hydrophobic chain and greater molecular weight. There was no resistance to permeation rate by membrane fouling. Most of permeation resistance was due to the concentration polarization. Permeation rate was declined with operating time and with increase in concentration of surfactant due to concentration polarization.

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Fouling behaviours of two stages microalgae/membrane filtration system applied to palm oil mill effluent treatment

  • Teow, Yeit Haan;Wong, Zhong Huo;Takriff, Mohd Sobri;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.373-383
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    • 2018
  • Fouling by solids and microorganisms is the major obstacle limiting the efficient use of membrane wastewater treatment. In our previous study, two stages microalgae/membrane filtration system was proposed to treat anaerobic digested palm oil mill effluent (AnPOME). This two stages microalgae/membrane filtration system had showed great potential for the treatment of AnPOME with high removal of COD, $NH_3-N$, $PO_4{^{3-}}$, TSS, turbidity, and colour. However, fouling behavior of the membrane in this two stages microalgae/membrane filtration system was still unknown. In this study, empirical models that describe permeate flux decline for dead-end filtration (pore blocking - complete, intermediate, and standard; and cake layer formation) presented by Hermia were used to fit the experimental results in identifying the fouling mechanism under different experimental conditions. Both centrifuged and non-centrifuged samples were taken from the medium with 3 days RT intervals, from day 0 to day 12 to study their influence on fouling mechanisms described by Hermia for ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO) filtration mode. Besides, a more detailed study on the use of resistance-in-series model for deadend filtration was done to investigate the fouling mechanisms involved in membrane filtration of AnPOME collected after microalgae treatment. The results showed that fouling of UF and NF membrane was mainly caused by cake layer formation and it was also supported by the analysis for resistance-in-series model. Whereas, fouling of RO membrane was dominated by concentration polarization.

Development of MBR System Commercialization Technology Using a Membrane with a Good Fouling Resistance (막 오염 저항성이 우수한 분리막을 이용한 MBR 시스템의 실증화 기술개발)

  • Choi, J.H.;Lee, J.B.;Kim, I.C.
    • Membrane Journal
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    • v.18 no.1
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    • pp.35-43
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    • 2008
  • In this study, we tried to solve membrane fouling with membranes made by fine nano-particle in MBR process. And we confirmed good fouling resistance in pilot test. In this test, we confirmed our membrane with titania out-standing quality by testing in the pilot long-term test by comparing to other company product. Our membrane keep up steadily $20{\sim}25 L/m^2{\cdot}hr$ high flux in $7,000{\sim}13,000mg/L$ MLSS high sludge concentration. In addition to this quality, we studied membrane flux character related membrane arrangement, membrane-air line arrangement, air-line hole size, cleaning solution concentration, treatment method, etc. Using the optimization of this additional parameter, we tried to search method of maximizing membrane quality.

Preparation of Heterogeneous Ion Exchange Membranes and Evaluation of Desalination Performance in Capacitive Deionization (불균질 이온교환막의 제조와 축전식 탈염에서의 탈염 성능 평가)

  • Choi, Jae-Hwan;Lee, Joo-Bong
    • Membrane Journal
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    • v.26 no.3
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    • pp.229-237
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    • 2016
  • We prepared heterogeneous ion exchange membranes (hetero-IEMs) for the application of membrane capacitive deionization (MCDI). Hetero-IEMs were fabricated by compressing the mixture of ion exchange resin powders and liner low density polyethylene (LLDPE). Characterization and MCDI desalination experiments were carried for the fabricated membranes. Electrical resistance of membrane decreased and water content increased with increasing the resin content in the hetero-IEMs. However, transport number indicating permselectivity of membrane was similar with that of commercial homogenesous ion exchange membrane. The results of MCDI desalination experiments showed that the adsorption amount for hetero-IEM was about 90% of that of homogeneous membrane due to the high electrical resistance of hetero-IEM. Although desalination performance of hetero-IEM decreased compared with homogeneous membrane, it was thought to be applicable to MCDI because of simple preparation and low price.

The Effect of Chemical Backwash on Filtration Performance of Batch Membrane Filtration System (회분식 막여과 시스템에서 약품역세가 여과성능에 미치는 영향)

  • Kim, Kwan Yeop;Lee, Eui Jong;Kwon, Jin Sub;Kim, Hyung Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.855-864
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    • 2009
  • The main object of this work was to determine the influence of periodic chemical backwash on filtration resistance in membrane filtration system. In this work Hermia's models were used to investigate the fouling mechanisms involved in the microfiltration of $0.45{\mu}m$ filtered sewage feed. Batch microfiltration experiments were performed at transmembrane pressure 0.4 bar and different feed SCOD concentration (9~67 mgSCOD/L). The results showed that the best fit to experimental data corresponded to the intermediate blocking model followed by the standard and complete blocking model for all the experimental conditions tested. From the simulation results of filtration performance, it was found that in order to maintain sustainable operation of membrane filtration system, irreversible foulant component accumulated continuously on membrane surface and/or pore must be effectively removed. In addition, it was verified that periodic chemical backwash using NaOCl or NaOH effectively improved filtration performance of membrane.

Effect of Concentration Polarization on The Pervaporation of Aqueous Chlorinated-Organic Solution (유기염화물 수용액의 투과증발에 미치는 농도분극의 영향)

  • Cho, Min-Suk;Kim, Seung-Jai;Kim, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.698-703
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    • 1998
  • The pervaporation experiments of aqueous solutions of trichloroethylene (TCE) and chlorobenzene (CB) through the silicone rubber (polydimethylsiloxane, PDMS) membrane were carried out and the effect of concentration polarization on the separation characteristics was investigated. The resistance-in-series model was used to explain the boundary layer resistance. It was clear that the concentration polarization phenomenon had a significant effect on the permeation behavior in the pervaporation separation of the trace organic chlorides from aqueous solutions. With the same membrane thickness, the permeation of TCE, which has a stronger affinity for the PDMS, appeared to be more influenced by the boundary layer resistance than that of CB. The effect of boundary layer resistance was reduced and the membrane resistance became dominant with increasing membrane thickness at a given hydrodynamic condition. The separation factor was increased to approach the intrinsic separation factor of the membrane with its thickness.

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Flame Resistance Performance of Architectural Membranes Using Basalt Woven Fabric (Basalt Woven Fabric을 적용한 건축용 막재의 난연특성)

  • Kim, JiHyeon;Song, Hun;Shin, HyeonUk
    • Fire Science and Engineering
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    • v.30 no.2
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    • pp.35-42
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    • 2016
  • The membrane structure provides high satisfaction with lightweight, improved workability, reduced cost, and a free shape. Thus, its applications expanding. On the other hand, in an architectural membrane that is vulnerable to fire, the development of various architectural membranes with flame resistance is in demand. Therefore, this study applied basalt woven fabric safety for flame resistance, excellent heat insulation and thermal properties on an architectural membrane. The PTFE- coated basalt woven fabric membrane was compared with a PTFE coated glass fiber membrane by DSC/TGA, strength properties, flammability, and incombustibility properties. In addition, this study confirmed the membrane applicability of basalt woven fabric and basalt-glass hybrid woven fabric through a comparison with existing architectural membranes.