• Title/Summary/Keyword: membrane processes

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Performance Enhancement of Ion-Exchange Membranes Using Nanomaterials (나노물질을 이용한 이온교환막의 성능 향상)

  • Moon-Sung Kang
    • Membrane Journal
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    • v.33 no.6
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    • pp.315-324
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    • 2023
  • Ion-exchange membrane (IEM), is a key component that determines the performance of the electro-membrane processes. In this review, the latest research trends in improving the performance of IEMs used in various electro-membrane processes through modification using carbon-based and metal-based nanomaterials are investigated. The nanomaterials can be introduced into IEMs through various methods. In particular, carbon-based nanomaterials can strengthen their interaction with polymer chains by introducing additional functional groups through chemical modification. Through this, not only can the ion conductivity of IEM be improved, but also the permselectivity can be improved through the sieving effect through the layered structure. Meanwhile, metal-based nanomaterials can improve permselectivity through sieving properties using the difference in hydration radius between target ions and excluded ions within a membrane by using the property of having a layered or porous structure. In addition, depending on the characteristics of the binder used, ion conductivity can be improved through interaction between nanomaterials and binders. From this review, it can be seen that the properties of IEMs can be effectively controlled using carbon-based and metal-based nanomaterials and that research on this is important to greatly improve the performance of the electro-membrane process.

Scale-up Fabrication of Flat Sheet Membrane by Using a Roll-to-Roll Process (롤투롤 공정을 활용한 평판형 분리막의 대면적 제조 연구)

  • Dong Hyeok Baek;Youngmin Yoo;In-Chul Kim;You-In Park;Seung-Eun Nam;Young Hoon Cho
    • Membrane Journal
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    • v.34 no.1
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    • pp.79-86
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    • 2024
  • The flat sheet membrane, one of the representative forms of polymeric membranes, is widely used from material research in laboratories to commercial membrane production due to its ease of fabrication. Porous polymeric flat sheet membranes used in microfiltration and ultrafiltration are mainly fabricated through phase separation processes, utilizing non-solvent-induced and vapor-induced phase separation methods. However, due to the nature of phase separation processes, variations between samples can easily occur depending on the surrounding environment and the experimenter, making it difficult to ensure reproducibility. Therefore, for scaling up and ensuring reproducibility of developed membrane fabrication technologies, there is a need for a controlled environment continuous large-area production device, such as a roll-to-roll manufacturing system. This research compared the changes in membrane characteristics due to differences in manufacturing environments when scaling up laboratory-scale fabrication technologies to roll-to-roll processes using knife and slot die coaters. By optimizing the continuous manufacturing process factors, uniformity of the membrane was ensured during large-area production.

Exploration on new model of selectively preferential sorption-facilitated transport with fixed site carriers

  • Congjie, Gao;Liguang, Wu
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.152-154
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    • 2004
  • A new model of selectively preferential sorption-facilitated transport with fixed site carriers was advanced in this paper. A number of experiments were arranged to demonstrate the ideal above. Preliminary results were obtained from the experiments, and shown the model was applicable for many membrane processes, such as RO, ED, gas separation and liquid membranes etc.

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Drinking Water Treatment by RO Membrane Processes (R/O막을 이용한 먹는물 처리)

  • 김권일
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.09a
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    • pp.105-120
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    • 1996
  • 본 발표에서는 세계적으로 가장 안전한 물처리방법으로 인정받고 있는 R/O막에 대하여 개발역사, 제조공정 및 설비에 대하여 소개하였다. 그리고 국내에서 최초로 개발된 제일합섬의 "CSM" R/O membrane과 전세계적으로 널리 사용되고 있는 R/O막에 대한 각 Grade 및 믈성에 대하여 설명하고, 종류에 따라서 NaCl, MgSO$_{4}$, 질산성 질소, 6가 크롬의 제거능력실험을 통하여 용도에 맞는 R/O막의 선책기준을 제시하였다. 또한, R/O막으로 먹는물 처리 System을 설계할 수 있는 간단한 Procedure 및 R/O system운전의 가장 큰 문제점인 Fouling의 생성과정 및 제거방법에 대하여 소개하고 미국 및 일본의 R/O막을 이용한 먹는물 처리 System실적에 대하여 언급하였다.대하여 언급하였다.

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Effect of Hydraulic Pressure on Organic Fouling in Pressure Retarded Osmosis (PRO) Process (압력지연삼투 (PRO) 공정에서 유도용액에서의 압력이 유기물 파울링에 미치는 영향)

  • Suh, Dongwoo;Yoon, Hongsik;Yoon, Jeyong
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.133-138
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    • 2015
  • Pressure retarded osmosis (PRO) process is one of membrane processes for harvesting renewable energy by using salinity difference between feed and draw solutions. Power is generated by permeation flux multiplied by hydraulic pressure in draw side. Membrane fouling phenomena in PRO process is presumed to be less sever, but it is inevitable. Membrane fouling in PRO process decreases water permeation through membrane, resulting in significant power production decline. This study intended to investigate the effect of hydraulic pressure in PRO process on alginate induced organic fouling as high and low hydraulic pressures (6.5 bar and 12 bar) were applied for 24 h under the same initial water flux. In addition, organic fouling in draw side from the presence of foulant (sodium alginate) in draw solution was examined. As major results, hydraulic pressure was found to be not a significant factor affecting in PRO organic fouling as long as the same initial water flux is maintained, inidicating that operating PRO process with high hydraulic pressure for efficient energy harvesting will not cause severe organic fouling. In addition, flux decline was negligible from the presence of organic foulant in draw side.

Prediction evaluation of problems happened of Sheet Metal Forming Process Using Shell Element (쉘 요소를 이용한 박판성형공정의 불량 예측 평가)

  • Ko Hyung-Hoon;Lee Chan-Ho;Kang Dong-Kyu;Sul Nam-Ki;Lee Kwang-Sik;Jong Dong-Won
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.481-484
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    • 2005
  • The AutoForm previously used the membrane element and it accomplished sheet metal forming analysis. The membrane analysis has been widely applied to various sheet metal forming processes because of its time effectiveness. However, it's well known that the membrane analysis can not provide correct information for the processes which have considerable bending effects. In this research it tried to compare the analysis results which use the shell element which is applied newly in the AutoForm commercial software with actual experimental results. The shell element is compromise element between continuum element and membrane element. The Finite element method by using shell element is the most efficient numerical method. From this research, it is known that FEA by using shell element can predict accurately the problems happened in actual experimental auto-body panel.

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A Pilot Study on Air Flotation Processes for Retrofitting of Conventional Wastewater Treatment Facilities (하수처리시설의 Retrofitting을 위한 파일럿 규모 공기부상공정 연구)

  • Park, Chanhyuk;Hong, Seok-Won;Lee, Sanghyup;Choi, Yong-Su
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.329-336
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    • 2008
  • The pilot study was conducted to evaluate the applicability of air flotation(AF) processes combined with biological nutrient removal(BNR) for the retrofitting of conventional wastewater treatment facilities. The BNR system was operated in pre-denitrification and intermittent aeration; developed ceramic membrane diffusers were installed to separate the solid-liquid of activated sludge at the bottom of a flotation tank. Before performing a pilot scale study, the size distribution of microbubbles generated by silica or alumina-based ceramic membrane diffusers was tested to identify the ability of solid-liquid separation. According to the experimental results, the separation and thickening efficiency of the alumina-based ceramic membrane diffuser was higher than the silica-based ceramic membrane diffuser. In a $100m^3/d$ pilot plant, thickened and return sludge concentration was measured to be higher than 15,000mg SS/L, therefore, the MLSS in the bioreactor was maintained at over 3,000mg SS/L. The effluent quality of the AF-BNR process was 4.2mg/L, 3.7mg/L, 10.6mg/L and 1.6mg/L for $BOD_5$, SS, T-N and T-P, respectively. Lastly, it was revealed that the unit treatment cost by flotation process is lower than about $1won/m^3$ compared to a gravity sedimentation process.

Progresses and new perspectives of integrated operations for a sustainable industrial growth

  • Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.11-14
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    • 1998
  • 1. Introduction : Research progresses in Chemistry and Chemical Engineering have been made during the last decades with important contributions to the industrial development and to the quality of our life. An interesting case is related to the membrane science and technology continuous impact to innovative processes and products, particularly appropriate for a sustainable industrial growth. Membrane operations have been familiar for many years to biologists and chemists working in their laboratorier or studying biological phenomena. Only recently engineers started to operate in' this area. The preparation of asymmetric CA membranes at University of California, Los Angeles in the early 60s is generally recognized as a crucial moment for membranology (1). Loeb and Sourirajan with their discovery of how to increase significantly the permeability of polymeric membranes without significant changes in their selectivity, made realistic the possibility of their use in large scale operations for desalting brackish and sea water by reverse osmosis and for various other molecular separations in different industrial areas. Reverse osmosis is today a well recognized basic unit operations, togheter with ultrafiltration, crossflow microfiltration,. nanofiltration, all pressure driven membrane processes. Already in 1992 more than 4 milIions m$^3$/day were the total capacity of RO desalination plants and in 1995 more than 180.000 m$^2$ of ultrafiltration membranes were installed for the treatment of wheys and milk (2) (3).

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Finite Element Analysis of Sheet Metal Forming Process Using Shell Element (쉘 요소를 이용한 박판성형공정의 유한요소해석)

  • Ko Hyung-Hoon;Lee Chan-Ho;Kang Dong-Kyu;Sul Nam-Ki;Lee Kwang-Sik;Jung Dong-Won
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.122-125
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    • 2005
  • The AutoForm previously used the membrane element and it accomplished sheet metal forming analysis. The membrane analysis has been widely applied to various sheet metal forming processes because of its saving time effectiveness. However, it's well known that the membrane analysis can not provides correct information for the processes which considerable bending effects. From this time research it tried to compare the formation analysis result which uses the shell element which is applied newly in the AutoForm and actual products. The shell element is compromise method between continuum analysis and membrane analysis. The Finite element method by using shell element is the most economical numerical method. From analysis results, FEA by using shell element can estimate accurately the problems happened in actual auto-body panel.

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Diffusion-based determination of protein homodimerization on reconstituted membrane surfaces

  • Jepson, Tyler A.;Chung, Jean K.
    • BMB Reports
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    • v.54 no.3
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    • pp.157-163
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    • 2021
  • The transient interactions between cellular components, particularly on membrane surfaces, are critical in the proper function of many biochemical reactions. For example, many signaling pathways involve dimerization, oligomerization, or other types of clustering of signaling proteins as a key step in the signaling cascade. However, it is often experimentally challenging to directly observe and characterize the molecular mechanisms such interactions-the greatest difficulty lies in the fact that living cells have an unknown number of background processes that may or may not participate in the molecular process of interest, and as a consequence, it is usually impossible to definitively correlate an observation to a well-defined cellular mechanism. One of the experimental methods that can quantitatively capture these interactions is through membrane reconstitution, whereby a lipid bilayer is fabricated to mimic the membrane environment, and the biological components of interest are systematically introduced, without unknown background processes. This configuration allows the extensive use of fluorescence techniques, particularly fluorescence fluctuation spectroscopy and single-molecule fluorescence microscopy. In this review, we describe how the equilibrium diffusion of two proteins, K-Ras4B and the PH domain of Bruton's tyrosine kinase (Btk), on fluid lipid membranes can be used to determine the kinetics of homodimerization reactions.