• 제목/요약/키워드: membrane processes

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Plasma Modification of Polymers

  • D´Agostino, Riccardo;Favia, Pietro;Fracassi, Francesco;Palumbo, Fabio
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.41-46
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    • 2003
  • Plasma processes developed in our laboratory, of interest for biomaterials, barrier coatings for food packaging and corrosion protection, are briefly reviewed in this contribution. Particular attention is devoted to diagnostics aimed to rationalize plasma-surface interactions and to identify parameters and correlations to be utilized for process control.

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Separators far Li-Ion Secondary Batteries (리튬이온 2차전지용 분리막)

  • Nam Sang Yong;Lee Young Moo;Lee Chang Hyun;Park Ho Bum;Rhim Ji Won;Ha Seong Yong;Kang Jong Seok
    • Membrane Journal
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    • v.14 no.4
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    • pp.263-274
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    • 2004
  • The polymeric membrane, a component of battery devices such as Li-ion battery (LIB) and Li-polymer battery (LPB), is a typical material in which the carrier mobility dominates the battery performance. In this paper, the state-of-the-art of membranes for secondary battery is described in terms of membrane properties. Several prerequisites, which are related to stability of battery devices, are discussed to design and prepare suitable polymeric membranes. In addition, physical requirements of membranes and their measurement methods are described to develop applicable polymeric membranes in membrane preparation processes.

Evaluation of Design Parameter on Residuals Treatment Facilities in Membrane Water Treatment Plants (막여과 정수장에서의 배출수처리시설 설계인자 평가)

  • Moon, Yong-Taik;Seo, In-Seok;Kim, Hong-Suck;Park, No-Suk;Ahn, Hyo-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.138-146
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    • 2006
  • The characteristics of backwash and concentrate discharges depend upon the quality of the water being treated and the net recovery of the membrane system. This paper is to indicate a design methods on the capacities of residuals treatment facilities in membrane processes for drinking water. We operated a demonstration membrane plant with a recovery rate of 90% for designing G-water treatment plant. We investigated on design parameter (optimum coagulant dosage and surface loading rate etc.) to design efficiently the residuals treatment facilities. The settling test was conducted with 1m columns dosing PACl to kaolin and membrane residuals under the experimental condition that discharge permit was under a 60mg/L. When the quantity of membrane residuals was $1,575m^3/day$, the estimated results for 1st thickener demonstrated the surface loading rate of 14.4m/day, detention time of 5.83hr, available depth of 3.5m.

Evaluation of a Thermophilic Two-Phase Anaerobic Digestion Coupled with Membrane Process for Garbage Leachate Treatment (음식물 탈리액 처리를 위한 막결합형 고온 2상 혐기성 소화 공정의 평가)

  • Lee, Eun-Young;Jun, Duk-Woo;Lee, Sang-Hwa;Bae, Jae-Ho;Kim, Jeong-Hwan;Kim, Young-O
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.21-27
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    • 2012
  • This study evaluated the performance of a thermophilic two-phase anaerobic digestion (TTPAD) coupled with membrane process treating garbage leachate. The pilot-scale treatment system is consisted of thermophilic acidogenic reactor (TAR) and thermophilic methanogenic reactor (TMR) coupled with an ultrafiltration (UF) membrane unit. The hydraulic retention time of TAR and TMR were 4 and 20 days, respectively. Effluent TCOD and SCOD of the TTPAD were $25\;{\pm}\;6\;and\;12\;{\pm}\;3$ g/L, respectively, and the corresponding TCOD and SCOD removal efficiencies were 77% and 81%, respectively. Propionate was major acids as 75% in the effluent. Scum formation was not observed in TTPAD, which might be resulted from complete lipid degradation. However, TTPAD was appeared to be sensitive to free ammonia toxicity. The UF membrane was operated with constant pressure filtration at average TMP 1.3 atm. Permeate flux had a range of 15-30 $L/m^2/hr$. With UF membrane, TCOD removal increased from 77% to 93%, and this SS free effluent would be beneficial to subsequent processes such as ammonia stripping.

Pervaporation of Ketone from Water Using Silicalite-1 Membrane (Silicalite-1 분리막을 이용한 수용액으로부터 케톤의 투과증발 분리)

  • 이용택;오윤진;안효성;이혜련
    • Membrane Journal
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    • v.13 no.4
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    • pp.229-238
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    • 2003
  • Pervaporation is mainly used to separate liquid mixtures because it exhibits a high selectivity compared with traditional distillation processes and it is known to be an energy saying separation process. Zeolite membranes show better thermal. mechanical, chemical stability than polymer membranes and especially silicalite-1 membrane can effectively separate organic compounds from water because of its high hydrophobicity. In this study, volatile organic compounds of ketone are separated by pervaporation using silicalite-1 membrane. As a feed concentration of acetone and MEK increases, a permeation flux of acetone and MEK increases while a selectivity decreases.

Development of a Numerical Model for Cake Layer Formation Process on Membrane (멤브레인 케이크 레이어 형성 과정 모사를 위한 수치 모델의 개발)

  • Kim, Kyung-Ho;Shin, Jae-Ho;Lee, Sang-Hwan;Lee, Ju-Hee
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.6
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    • pp.35-44
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    • 2011
  • Membrane filtration has become firmly established as a primary process for ensuring the purity, safety and efficiency of treatment of water or effluents. Several researches have been performed to develop and design membrane systems in order to increase the accuracy and performance of the processes. In this study, a lattice Boltzmann method for the cake layer has been developed using particle dynamics based on an immersed boundary method and the cake layer formation process on membrane has been numerically simulated. Case studies including various particle sizes were also performed for a microfiltration process. The growth rate of the cake layer thickness and the permeation flow rate along the membranes were predicted. The results of this study agreed well with that of previous experiments. Effects of various particle diameters on the membrane performance were studied. The cake layer of a large particle tended to be growing fast and the permeation flow going down rapidly at the beginning. The layer thickness of a small particle increased constantly and the flow rate was smaller than that of the large particle at the end of simulation time.

Impact of Characteristics of Polymeric Al Coagulants PACl and Alum on Membrane Flux and Fouling of Microfiltration (PACl 및 Alum 응집제 특성이 정밀여과막 투과수량 및 막오염에 미치는 영향)

  • Jin, Yong-Chul;Choi, Yang-Hun;Kweon, Ji-Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.231-240
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    • 2011
  • The objectives of this research are to investigate coagulation efficiencies of two coagulants l.e., alum and polyaluminum chloride and to understand effects of the coagulants on membrane fouling in microfiltration. The turbidity of supernatant from alum coagulation was increased with increasing doses whereas the turbidity from PACl coagulation was maintained at the low values. The observed injection volume of PACl for the same removal was approximately 30 percent less than alum, which produced a low sludge volume. The settling velocity of PACl flocs was greater than alum flocs. The results corresponded well with floc size measurements. Flux decline from alum coagulation was significant due in part to small sizes of flocs. At the low dose, alum floc had less specific cake resistance than PACl floc. However, as the dosage was increased, the increases in specific cake resistances of alum was substantial. Alum coagulation pretreatment needs careful operation to reduce membrane fouling by flocs. In general, PACl coagulants were more effective than alum coagulants for pretreatment of membrane processes because PACl showed the better performance in coagulation and membrane fouling.

Dehydration Characteristics of i-Propyl Alcohol Aqueous Solution through NaA Zeolite Membrane (NaA 제올라이트 막에 의한 이소프로필 알코올 수용액의 탈수 분리 특성)

  • 최호상;김재홍;이석기;박헌휘
    • Membrane Journal
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    • v.12 no.3
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    • pp.158-164
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    • 2002
  • This study was carried out the fundamental experiment to investigate the pervaporation process through NaA zeolite membrane for recycling the wasted isopropyl alcohol(IPA) in semiconductor cleaning processes. The NaA zeolite membrane used showed the excellent separation performance for full range of feed concentration and at high temperature operation. At 80 in operation temperature and 90 wt% IPA in feed concentration the separation performance was obtained about $1,500 g/m^2/hr$ in the permeation flux and more than 1,000 in the separation factor. In continuous operation of dehydration of IPA the average permeation flux was obtained about $1,000 g/m^2/hr$ at 80 and 90 wt% IPA feed concentration.

Perfluorinated Sulfonic Acid Ionomer Membranes for Valued Chemical Production (과불소계 술폰화 이오노머막을 이용한 고부가가치 화학품 제조)

  • Shim, Jae Goo;Park, In Kee;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.2
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    • pp.152-158
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    • 2016
  • The Chlor-alkali (CA) membrane cell is a major electrolysis system to produce valued chemicals such as chlorine gas and sodium hydroxide. The CA membrane process has been attracted in the industries, since it has relatively low energy consumption when compared with other CA processes. The key component in CA process is perfluorinated sulfonic acid ionomer membranes, which provide ion-selectivity and barrier properties to produced gases. Unfortunately, there is limited information to determine which factors should be satisfied for CA applications. In this study, the influences of PFSA membranes on CA performances are disclosed. They include ion transport behaviors, gas evolution capability, and chemical/electrochemical resistances under CA operation conditions.