• Membrane and Water Treatment
• /
• v.7 no.6
• /
• pp.507-520
• /
• 2016

The effect of ZnO on cellulose acetate in the removal of benzophenone-3 (BP-3) was investigated. The benzophenone-3 (BP-3) which is an endocrine disrupting chemical (EDC) was completely removed (100%) from the drinking water using Cellulose Acetate (CA) and zinc oxide (ZnO) composite membranes. The membranes were prepared by DIPS method and the filtration experiments were conducted by dead end filtration unit. The macrostructure of the membrane were studied by ATR-IR and XRD Spectra's. Atomic force microscopy (AFM) and Scanning electron microscopy (SEM) were used to study the micro properties of the membranes. The laboratory experiments such as water uptake study and pure water flux performed to confirm the increasing hydrophilicity. The enhancing hydrophilicity was confirmed with respect to higher the concentration of nanoparticles. Evaluation of BP-3 removal was carried in different experimental conditions, such as, different Trans membrane pressure and different concentration of feed. The membrane with low pressure showed better performance by rejecting 100% of BP-3. However, 1 ppm, 3 ppm and 6 ppm of feed solution was used and among them 3 ppm of feed solution gives 100% rejection. The ZnO nanoparticales enhances the performance of CA membrane by showing maximum rejection.

• Journal of Korean Association for Spatial Structures
• /
• v.16 no.2
• /
• pp.39-45
• /
• 2016

Membrane structure is a system that is stabilized by maintaining a tensile state of the membrane material that originally cannot resist the bending or pressure. Also, it is a system that allows the whole membrane structure to bear external loads caused by wind or precipitation such as snow, rain and etc. Tension relaxation phenomenon can transpire to the tension that is introduced to the fabric over time, due to the innate characteristics of the membrane material. Thus, it is important to accurately understand the size of the membrane tension after the completion of the structures, for maintenance and management purposes. The authors have proposed the principle of theoretically and indirectly measuring the tension by vibrating the membrane surface with sound waves exposures against the surface, which is compartmentalized by a rectangular boundary, and by measuring the natural frequency of the membrane surface that selectively resonates. The authors of this paper measured the tension of preexisting membrane structure for its maintenance by using the developed portable measurement equipment. Through analyzing the measurement data, the authors review the points that should be improved and the technical method for the new maintenance system of membrane tension.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.33 no.12
• /
• pp.33-38
• /
• 2005

The large deformation of inflatable membrane structure is numerically and experimentally considered in this paper. The numerical algorithm of wrinkling based on Miller and Hedgepeth membrane theory is developed using user material(UMAT) subroutine written by FORTRAN. Wrinkled area and deformed shapes of inflatable membrane structures are investigated by using ABAQUS with UMAT subroutine of wrinkling algorithm.

• Korean Membrane Journal
• /
• v.1 no.1
• /
• pp.50-58
• /
• 1999

Symmetric asymmetric and composite perfluoropolymer membranes made with HYFLON AD have been prepared and evaluated. Porous and non porous symmetric membranes have been prepared by solvent evaporation with various processing conditions. Non-contact atomic force microscopy (AFM) was used to investigate the membrane morphology in air. Analysis of the images gave quantitative imformation on the surface pore strcture in particular on the pore size distributin. Possible useful uses of porous membranes are envisaged in the field of gas-liquid separations such as membrane contactors (MSc) Molecular Dynamics(MD) simulations structure of HYFLON AD 60X copolymer supporting these results are also reported. Amorphous perfluoropolymer membranes appears to be ideal other than in MCs when separation processes have to be performed in hostile environments i.e. high temperatures and aggressive non-aqueous media such as chemicals and solvents. In these cases HYFLON AD mem-branes can exploit the outstanding resistance of perfluoropolymers.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2000.04a
• /
• pp.47-50
• /
• 2000

• Membrane Journal
• /
• v.3 no.3
• /
• pp.136-139
• /
• 1993

It is well known that the membrane permeation in pervaporation is governed by both the chemical nature of the membrane material and the physical structure of the membrane and also the separation can be achieved by differences in either solubility, size or shape. The solubility of the penerrant in the polymeric membrane can be described qualitively by applying the Hildebrand relation [1] which relates the energy of mixing of the penerrant and the polymer material. Froehling et al. have tried to predict the swelling behavior of polymers for the systems of polyvinylchloride(PVC)-toluene-methanol, PVC-trichloroethylene-nitromethane and PVC-n-butylacetate-nitromethane[2]. The former two systems which do not show the donor/acceptor interactions upon mixing showed the successful results[2]. In addition to this technique, there are several other possible approaches to predict the swelling behaviors of polymers, such as the surface thermodynamic approach[3, 4], the comparison of the membrane polarity with the solvent polarity in terms of Dimroth's solvent polarity value[5].

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2005.11a
• /
• pp.649-653
• /
• 2005

Recently, many membrane structure buildings are constructed with the trend of multi functional and high technological construction. The membrane structure has the characteristics such as distinguished architectural shape which can make variable space creation and can make economic use of material. Therefore, it is in the spotlight of sport complex, various concert hall, and public service buildings. However, the acoustic study of membrane structure has not been following up the increasing demand for the membrane structure. In this study, the acoustic characteristics of membrane structure will be studied and analyzed using architectural acoustic factors based on acoustic design theory And also, the differences between theoretical exhortation value and outcome of study will be studied with the basis of architectural acoustic material study.

• Journal of Korean Association for Spatial Structures
• /
• v.10 no.2
• /
• pp.127-134
• /
• 2010

Membrane structures are now used in various ways throughout the world with the merits of free shape, lightness, durability, sunlight transmittance and homogeneous material. The development of new membrane material opened up new possibility for the design of new building structures. Recently it was mainly used PVC, PVF, PVDF, PTFE, ETFE membrane for using the roofing material of membrane structures. Some problems of architectural membrane have fire proofing, lack of strength, tear resistance, durability and elasticity. For the estimation of this problems, it will be tested the basic mechanical properties of membrane material about tensile strength, tearing resistance and repeated loading behavior. Elastic modulus is 337.30~1257.63N/$mm^2$, and strain is 17.90~26.91%.

• Membrane Journal
• /
• v.25 no.5
• /
• pp.456-463
• /
• 2015

In this study, we synthesize novel silane based inorganics for preparation of the polymer electrolyte membrane with high proton conductivity under high temperature condition and developed membranes are characterized. SPAES, hydrocarbon based polymer are synthesized and used as main polymeric material. We used sol-gel method to prepare inorganic material with high performance using silica, phosphate and zirconium. Three types of inorganics were prepared by control of the mole ration of each component. As a result of EDX analysis, the inorganic materials are well dispersed in the polymer membrane. The water uptake of the composite membrane is increased by introduction of the hydrophilic inorganic material in the membrane. When the content of the zirconium in the membrane is increased, the proton conductivity of the composite membrane shows the higher value than pure SPAES membrane at the high temperature. And the silica based inorganics effect to increase the proton conductivity under low temperature condition.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2005.11a
• /
• pp.96-101
• /
• 2005

A theory for the material transports through ion exchange membrane has been developed on the basis of nonequilibrium thermodynamics by removing the assumption of solvent flow in the previous paper and applied to a detailed study of the ionic transport properties of new charged mosaic membrane(CMM) system. The CMM having two different fixed charges in the polymer membrane indicated unique selective transport behavior then ion-exchange membrane. The separation behavior of ion transport across the CMM with a parallel array of positive and negative functional charges were investigated. It was well-known the analysis of the volume flux and solute flux based on nonequilibrium thermodynamics. Our suggests preferential salt transport across the charged mosaic membranes. Transport properties of heavy metal ions, $Mg^{2+}$, $Mn^{2+}$and sucrose system across the charged mosaic membrane were estimated. As a result, we were known metal salts transport depended largely on the CMM. The reflection coefficient indicated the negative value that suggested preferential material transport and was independent of charged mosaic membrane thickness.