• 유변학
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• 제9권4호
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• pp.133-139
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• 1997

PC(polycarbonate), SAN(styren-acrylonitrile)공중합체, 그리고 충격 보강제를 근간 으로 하는 다성분계 고분자 블렌드에 대하여 고정된 사출조건에서 블렌드의 조성에 따른 weldline강도의 변화를 조사하였다. 블렌드의 전체적인 함량에 있어서 PC가 그함량이 높아 연속상이 되는 경우가 비교적 높은 weldline강도를 나타내지만 PC함량이 감소함에 따라서 급격한 저하가 발생하여 채-continuity의 성향이 강한 50%부근에서 최소 값을 보였다. PC 함량이 고정되었을 때에는 분산상의 점도가 증가할수록 weldline 강도가 향상되었는데 이는 weldline의 형성 시에 발생하는 분수형 흐름장에 의한 분산상의 배향이 억제되어 외부 응력 에 대하여 균일하게 대응할수 있는 형태학을 유지하는 효과로 설명된다. 충격보강제의 변경 과 상용화제의 적용으로부터 얻은 결과를 종합하여 볼 때 다성분계 고분자 블렌드의 weldline강도는 구성성분간의 상용성 뿐만 아니라 유변학적인 조건이 만족되어야 효과적으 로 향상될수 있다.

• Tribology and Lubricants
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• 제18권5호
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• pp.345-350
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• 2002

Recently, as the development of manufacturing technique on SMC(sheet molding compound), various numerical and experimental approaches to injection and compression molding have been investigated. Injection and compression molding, however, has so various cases with complicated boundary condition that it is difficult to analyze mold characteristics precisely. In addition, since a slight change in process variables can significantly change the resulting mold thickness, a proper design is important to compression molding process. Therefore, in this study, the effects of various parameters on compression molding process have been investigated using FEM(finite element method) to formulate the melt front advancement during the mold filling process. To verify the results of present analysis, they are compared with those of reference. The results show a strong effect of initial charge volume, injection time and pressure as a result of variations in the rectangular charge shape.

• Carbon letters
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• 제11권4호
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• pp.311-315
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• 2010

In this work, the effect of glycidyl methacrylate grafted multi-walled carbon nanotubes (GMA-MWCNTs) on the viscoelastic behaviors of polypropylene (PP) based nanocomposites was studied. The GMA-MWCNTs/PP was prepared using a bravender at $200^{\circ}C$ by melt mixing as a function of GMA-MWCNT content. The viscoelastic behaviors of GMA-MWCNTs/PP nanocomposites were measured by a rheometer. It was found that the GMA-MWCNTs were homogeneously dispersed in the PP matrix. The GMA-MWCNTs/PP nanocomposites showed higher storage modulus, loss modulus, and shear viscosity compared to pure PP nanocomposites and the maximum value was shown at 2.0 wt% GMA-MWCNTs loading. These results were probably attributed to the strong interfacial interaction between the GMA-MWCNT and the PP matrix.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2001년도 가을 학술발표회 논문집
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• pp.440-443
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• 2001

Polymer/layered silicate nanocomposites have recently received considerable attention from both academia and industry as an effective way to overcome the shortcomings of conventional polymer. When the silicate layers are exfoliated and randomly distributed in polymer matrix, the nanocomposites exhibit improved mechanical, thermal and barrier properties. (omitted)

• Journal of Advanced Marine Engineering and Technology
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• 제32권4호
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• pp.570-577
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• 2008

Magnesium alloys are potentially useful as structural materials due to higher strength/weight ratio, heat conductivity and recyclability compared to other alloys. These alloys have attracted the interest of modern manufacturing such as the automobile, computer, communication and consumer electronic appliances industries. Hence welding techniques are required to be developed for these applications. Laser are known to be an excellent tool for them. This paper presents the laser weldability of AZ31 magnesium alloy with CW Nd:YAG laser. The low viscosity and surface tension of the melt pool make magnesium more difficult to weld than steel. As a result of this study, optimal process parameters could be obtained without weld defects. Also it was certain that cutting methods had influence on butt weldability.

• Macromolecular Research
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• 제12권1호
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• pp.85-93
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• 2004

We have prepared poly(ethylene terephthalate) (PET) nanocomposites filled with two different types of fumed silicas, hydrophilic (FS) and hydrophobic (MFS) silicas of 7-nm diameter, by in situ polymerization. We then investigated the morphological changes, rheological properties, crystallization behavior, and mechanical properties of the PET nanocomposites. Transmission electron microscopy (TEM) images indicate that the dispersibility of the fumed silica was improved effectively by in situ polymerization; in particular, MFS had better dispersibility than FS on the non-polar PET polymer. The crystallization behavior of the nanocomposites revealed a peculiar tendency: all the fillers acted as retarding agents for the crystallization of the PET nanocomposites. The incorporation of fumed silicas increased the intrinsic viscosities (IV) of the PET matrix, and the strong particleparticle interactions of the filler led to an increased melt viscosity. Additionally, the mechanical properties, toughness, and modules of the nano-composites all increased, even at low filler content.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.36-37
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• 2006

This study aims to investigate the usage of nano-scale particles in a micro metal injection molding ($\mu$-MIM) process. Nanoscale particle is effective to improve transcription and surface roughness in small structure. Moreover, the effects of hybrid micro/nano particles, Cu/Cu and SUS/Cu were investigated. Small dumbbell specimens were produced using various feedstocks prepared by changing binder content and fraction of nano-scale Cu particle (0.3 and $0.13{\mu}m$ in particle size). The effects of adding the fraction of nano-scale Cu powder on the melt viscosity of the feedstock, microstructure, density and tensile strength of sintered parts were discussed.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 춘계학술대회 논문집
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• pp.39-42
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• 2005

For mass production, usually injection mold has multi-cavity which is filled through geometrical balanced runner system. Despite geometrical balanced runner system, filling imbalances between cavity to cavity have always been observed. These filling imbalances are one of the most significant factors to affect quality of plastic parts when molding plastic parts in multi-cavity injection mold. Filling imbalances are results from non-symmetrical shear rate distribution within melt as it flows through the runner system. It has been possible to decrease filling imbalance by optimizing processing conditions, but it has not completely eliminated this phenomenon during injection molding processing. This paper presents a solution of these filling imbalances through using 'runner core pin'. The runner core pin which is developed in this study creates a symmetrical shear distribution within runner. As a result of using runner core pin, a remarkable improvement in reducing filling imbalance was confirmed.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 금형가공,미세가공,플라스틱가공 공동 심포지엄
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• pp.13-16
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• 2005

For mass production, usually injection mold has multi-cavity which is filled through geometrical balanced runner system. Despite geometrical balanced runner system, filling imbalances between cavity to cavity have always been observed. These filing imbalances are one of the most significant factors to affect quality of plastic parts when molding plastic parts in multi-cavity injection mold. Filling imbalances are results from non-symmetrical shear rate distribution within melt as it flows through the runner system. It has been possible to decrease filling imbalance by optimizing processing conditions, but it has not completely eliminated this phenomenon during injection molding processing. This paper presents a solution of these filling imbalances through using 'runner core pin'. The runner core pin which is developed in this study creates a symmetrical shear distribution within runner. As a result of using runner core pin, a remarkable improvement in reducing filling imbalance was confirmed.

• Bulletin of the Korean Chemical Society
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• 제16권1호
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• pp.17-21
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• 1995

A new series of polyarylate copolyesters were prepared by melt polycondensation of 1,4-diacetoxy-2,5-(α-phenylisopropyl)benzene with mixture of terephthalic acid and isophthalic acid in varying ratio. And their general properties such as the glass transition temperature, crystalline melting temperature, crystallinity and solubility were studied. The intrinsic viscosity values of the present polymers measured in a mixed solvent of phenol/p-chlorophenol/1,1,2,2-tetrachloroethane ranged from 0.45 to 0.66 depending on the composition and molecular weight. The copolyesters containing greater than 20 mole % of isophthalic acid were found to be amorphous, whereas the homopolymer derived from terephthalic acid was semicrystalline with a melting point of 414℃. The glass transition temperatures of the polymers ranged from 165 to 180℃ depending on the composition. The copolyesters containing 50 mole % and greater of isophthalic acid moiety were soluble at room temperature in such common solvents as tetrahydrofuran, chloroform and N,N-dimethylformamide.