• Title/Summary/Keyword: mechanical deterioration

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Flame Retardancy and Mechanical Property of Polypropylene/ Nylon Nanocomposite Reinforced with Montmorillonite (몬모릴로나이트로 강화된 폴리프로필렌/ 나일론 나노복합재료의 난연특성 및 기계적 특성)

  • 이종훈;박호식;안인구;이윤희;김연수;이영관;남재도
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.576-582
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    • 2003
  • When the halogenated flame retardant, decabromodiphenyl oxide, was added to the polypropylene/nylon blend, and was compounded with montmorillonite and compatibilizer, maleic anhydride polypropylene, the improvement of flame retardancy and mechanical properties was investigated. The degree of dispersion between polymer resin and inorganic nanoparticles was investigated, and the flame retardancy and mechanical properties was measured quantitatively. XRD results showed that the montrnorillonite was com-pletely exfoliated after polypropylen/nylon nanocomposites was mixed above twice. By compounding with montmorillonite, polypropylene/nylon blend system was overcome the deterioration of flame retardancy. The tensile strength and impact strength were slightly increased, and by compounding with montmorillonite, the additional increase in mechanical properties was obtained. Therefore, the flame retardancy of polypropylene / nylon blend was decreased by adding nylon, but by compounding with inorganic nanoparticle, improvement of the flame retardancy and mechanical properties was obtained.

Characteristics of Expanded Graphite Filled Conductive Polymer Composites for PEM Fuel Cell Bipolar Plates

  • Oh, K.S.;Heo, S.I.;Yun, J.C.;Yang, Y.C.;Han, K.S.
    • Advanced Composite Materials
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    • v.17 no.3
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    • pp.259-275
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    • 2008
  • This study aims to optimize the mechanical and electrical properties of electrically conductive polymer composites (CPCs) for use as a material of bipolar plates for PEM fuel cells. The thin CPCs consisting of conductive fillers and polymer resin were fabricated by a preform molding technique. Expanded graphite (EG), flake-type graphite (FG) and carbon fiber (CF) were used as conductive fillers. This study tested two types of CPCs, EG/FG filled CPCs and EG/CF filled CPCs, to optimize the material properties. First, the characteristics of EG/FG filled CPCs were investigated according to the FG ratio for 7 and $100{\mu}m$ sized FG. CPCs using $100{\mu}m$ FG showed optimal material properties at 60 wt% FG ratio, which were an electrical conductivity of 390 S/cm and flexural strength of 51 MPa. The particle size was an important parameter to change the mechanical and electrical behaviors. The flexural strength was sensitive to the particle size due to the different levels of densification. The electrical conductivity also showed size-dependent behavior because of the different contributions to the conductive network. Meanwhile, the material properties of EG/CF filled CPCs was also optimized according to the CF ratio, and the optimized electrical conductivity and flexural strength were 290 S/cm and 58 MPa, respectively. The electrical conductivity of this case decreased similarly to the EG/FG filled case. On the other hand, the behavior of the flexural strength was more complicated than the EG/FG filled case, and the reason was attributed to the interaction between the strengthening effect of CF and the deterioration of voids.

Ag Nanoparticle Self-Generation and Agglomeration via Laser-Induced Plasmonic Annealing for Metal Mesh-Based Transparent Wearable Heater (레이저 기반 플라즈모닉 어닐링을 통한 은 나노입자 자가 생성 및 소결 공정과 이를 활용한 메탈메쉬 전극 기반 투명 웨어러블 히터)

  • Hwang, Yun Sik;Nam, Ui Yeon;Kim, Yeon Uk;Woo, Yu Mi;Heo, Jae Chan;Park, Jung Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.439-444
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    • 2022
  • Laser-induced plasmonic sintering of metal nanoparticles (NPs) is a promising technology to fabricate flexible conducting electrodes, since it provides instantaneous, simple, and scalable manufacturing strategies without requiring costly facilities and complex processes. However, the metal NPs are quite expensive because complicated synthesis procedures are needed to achieve long-term reliability with regard to chemical deterioration and NP aggregation. Herein, we report laser-induced Ag NP self-generation and sequential sintering process based on low-cost Ag organometallic material for demonstrating high-quality microelectrodes. Upon the irradiation of laser with 532 nm wavelength, pre-baked Ag organometallic film coated on a transparent polyimide substrate was transformed into a high-performance Ag conductor (resistivity of 2.2 × 10-4 Ω·cm). To verify the practical usefulness of the technology, we successfully demonstrated a wearable transparent heater by using Ag-mesh transparent electrodes, which exhibited a high transmittance of 80% and low sheet resistance of 7 Ω/square.

Mechanical and Electrical Failure of ITO Film with Different Shape during Twisting Deformation (비틀림 변형 중 ITO 필름의 시편 형태에 따른 기계적 전기적 파괴 연구)

  • Kwon, Y.Y.;Kim, Byoung-Joon
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.53-57
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    • 2017
  • The most representative transparent electrode in the modern society is ITO (Indium Tin Oxide). ITO is widely used in general for touch panels and displays due to its high electrical and optical properties. However, in general, mechanical deformation causes deterioration and destruction of device properties because ITO is basically vulnerable to mechanical deformation. Therefore, the in-depth understanding on the stability of ITO film during various mechanical deformations is necessary. In this study, the reliability and mechanical properties ITO sample having different length, width, and area were investigated. The electrical stability was estimated according to electrical resistance change. The stability was dropped as the sample length, and width increased and the sample area decreased. The electrical stability of ITO film was correlated with twisting strain including tensile, compressive and shear stress.

Experimental Investigation to Establish Correlation Between Specific Film Thickness and Vibration Signals in Spur Gear System (스퍼 기어의 진동 신호와 비 유막 두께(Specific Film Thickness)의 상관관계에 관한 실험적 연구)

  • Kim, Jong Sik;Amarnath, M.;Lee, Sang Kwon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.9
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    • pp.1005-1012
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    • 2014
  • Gears are critical elements in automobiles, and their use as power transmitting machine elements in engineering applications is quite extensive. In the areas of contact between gear teeth, the condition of a gear is likely to deteriorate due to contact fatigue, wear, material defects, lubrication failure, etc. Thus, it is necessary to monitor its condition to ensure smooth power transmission. Gear teeth deterioration causes failures such as abrasive wear, scuffing, pitting, and spalling. These failures lead to a higher level of vibration signals in the gear system. This paper presents the results of an experiment on the surface fatigue wear of a spur gear system. The correlation between the estimated specific film thickness, statistical parameter of the vibration signals, and Stribeck curve was considered in this study.

Program Development for Material Degradation Evaluation Using Grain Boundary Etching Method (입계부식법을 이용한 열화도 평가 프로그램 개발)

  • Yu, Hyo-Seon;Baek, Seung-Se;Na, Seong-Hun;Kim, Jeong-Gi;Lee, Hae-Mu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.7
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    • pp.1064-1072
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    • 2001
  • It is very important to evaluate material degradation like temper and carbide embrittlements to secure the reliable and efficient operational conditions and to prevent brittle failure in service. The extent of material deterioration can be accurately evaluated by mechanical test such as impact test or creep test. But it is almost impossible to sample a large specimen from in-service plants. Thus, the material degradation evaluation by a non-destructive method is earnestly required. Recently the non-destructive test technique which uses the grain boundary etching characteristics owing to the variation of material structures has been proposed. However the program for material degradation evaluation using the grain boundary etching method(GEM) in Windows 98 domain doesnt be developed now. The aims of this paper are to develop the program and to complete the new master curve equations for the evaluation of material degradation on in-serviced high temperature components.

Lightweight Crane Design by Using Topology and Shape Optimization (위상최적설계와 형상최적설계를 이용한 크레인의 경량설계)

  • Kim, Young-Chul;Hong, Jung-Kie;Jang, Gang-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.7
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    • pp.821-826
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    • 2011
  • CAE-based structural optimization techniques are applied for the design of a lightweight crane. The boom of the crane is designed by shape optimization with the shape of the cross section of the boom as the design variable. The design objective is mass minimization, and the static strength and dynamic stiffness of the system are set as the design constraints. Hyperworks, a commercial analysis and optimization software, is used for shape and topology optimization. In order to consistently change the shape of the elements of the boom with respect to the change in the shape of its cross section, the morphing function in Hyperworks is used. The support of the boom of the original model is simplified to model the design domain for topology optimization, which is discretized by using three-dimensional solid elements. The final result after shape and topology optimization is 19% and 17% reduction in the masses of the boom and support, respectively, without a deterioration in the system stiffness.

Environment Deterioration Characteristics of Polypropylene / Glass Fiber Composites under Moisture Absorption Environment (흡습 환경 하의 폴리프로필렌/유리 섬유 강화 복합재료의 환경 열화 특성)

  • Kim, Yun-Hae;Park, Chang-Wook;Jung, Gyung-Seok;Shin, Seok-Jin
    • Journal of Ocean Engineering and Technology
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    • v.30 no.6
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    • pp.520-525
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    • 2016
  • In this study, a mixture of polypropylene fibers and glass fibers were used to weave polypropylene/glass fiber-reinforced composite panels with characteristics such as highly elongated short fibers, high ductility, anti-fouling, and hydrophobicity as a result of a directional property. Mechanical and environmental tests were carried out with specimens fabricated with this composite panel, and its applicability to shipbuilding and ocean leisure industries was evaluated through a comparison with existing glass fiber-reinforced composite materials. The results of this experiment verified the excellence of the polypropylene/glass-mixed woven fiber-reinforced composite material compared to the existing glass fiber-reinforced composite material. However, the forming process needs to be changed to improve the weak interfacial bonding, and the properties of the composite material itself could be improved through mixed weaving with other fibers after development. Maximizing of the advantages of the polypropylene fibers and overcoming their shortcomings will improve their applicability to the shipbuilding, ocean leisure, and other industries, and increase the value of polypropylene fibers in the composite material market.

Thermo-mechanical analysis of reinforced concrete slab using different fire models

  • Suljevic, Samir;Medic, Senad;Hrasnica, Mustafa
    • Coupled systems mechanics
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    • v.9 no.2
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    • pp.163-182
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    • 2020
  • Coupled thermo-mechanical analysis of reinforced concrete slab at elevated temperatures from a fire accounting for nonlinear thermal parameters is carried out. The main focus of the paper is put on a one-way continuous reinforced concrete slab exposed to fire from the single (bottom) side as the most typical working condition under fire loading. Although contemporary techniques alongside the fire protection measures are in constant development, in most cases it is not possible to avoid the material deterioration particularly nearby the exposed surface from a fire. Thereby the structural fire resistance of reinforced concrete slabs is mostly influenced by a relative distance between reinforcement and the exposed surface. A parametric study with variable concrete cover ranging from 15 mm to 35 mm is performed. As the first part of a one-way coupled thermo-mechanical analysis, transient nonlinear heat transfer analysis is performed by applying the net heat flux on the exposed surface. The solution of proposed heat analysis is obtained at certain time steps of interest by α-method using the explicit Euler time-integration scheme. Spatial discretization is done by the finite element method using a 1D 2-noded truss element with the temperature nodal values as unknowns. The obtained results in terms of temperature field inside the element are compared with available numerical and experimental results. A high level of agreement can be observed, implying the proposed model capable of describing the temperature field during a fire. Accompanying thermal analysis, mechanical analysis is performed in two ways. Firstly, using the guidelines given in Eurocode 2 - Part 1-2 resulting in the fire resistance rating for the aforementioned concrete cover values. The second way is a fully numerical coupled analysis carried out in general-purpose finite element software DIANA FEA. Both approaches indicate structural fire behavior similar to those observed in large-scale fire tests.

Effects of fission product doping on the structure, electronic structure, mechanical and thermodynamic properties of uranium monocarbide: A first-principles study

  • Ru-Ting Liang;Tao Bo;Wan-Qiu Yin;Chang-Ming Nie;Lei Zhang;Zhi-Fang Chai;Wei-Qun Shi
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2556-2566
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    • 2023
  • A first-principle approach within the framework of density functional theory was employed to study the effect of vacancy defects and fission products (FPs) doping on the mechanical, electronic, and thermodynamic properties of uranium monocarbide (UC). Firstly, the calculated vacancy formation energies confirm that the C vacancy is more stable than the U vacancy. The solution energies indicate that FPs prefer to occupying in U site rather than in C site. Zr, Mo, Th, and Pu atoms tend to directly replace U atom and dissolve into the UC lattice. Besides, the results of the mechanical properties show that U vacancy reduces the compressive and deformation resistance of UC while C vacancy has little effect. The doping of all FPs except He has a repairing effect on the mechanical properties of U1-xC. In addition, significant modifications are observed in the phonon dispersion curves and partial phonon density of states (PhDOS) of UC1-x, ZrxU1-xC, MoxU1-xC, and RhxU1-xC, including narrow frequency gaps and overlapping phonon modes, which increase the phonon scattering and lead to deterioration of thermal expansion coefficient (αV) and heat capacity (Cp) of UC predicted by the quasi harmonic approximation (QHA) method.