• KSBB Journal
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• 제15권6호
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• pp.664-669
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• 2000

미셀 집합체들이 수용액에 존재하는 혼합물로부터 아미노산, 단백질, 그리고 효소와 같은 생물학적 물질의 선돼적인 추출에 유용하게 샤용될 수 있음은 널리 알려져 있다. 본 연 구에서는 가용화 과정에 영향을 미치는 변수들을 확인하기 위하여 AOT와 iso-octane의 유기상에서의 $\alpha$-chymotrypsin 가 용화에 대하여 pH의 영향, 염의 종류와 염의 농도의 영향을 연구하였다. NaCI과 KCI에 대하여서는 pH=5.0에서 최대 효 율을 나타내며, $MgCl_2$ 와 $CaCl_2$ 에 대해서는 pH=7.0에서 최대 효율을 나타내었는데 이와 같은 조건은 모두 $\alpha$-chymo$\sigma$ypsin 의 둥전점 이하 영역이다. 낮은 pH에서는 계변에 단백질이 광범위하게 침전되거나 엉킴현상이 나타나기 때문에 유기상 에서의 단백질 농도를 직접 측정하여 실험오차를 줄였다. 미 셀의 water po이 크기는 물에 대한 계면활성제의 몰 비(Wo) 를 측정하여 추산하였다 .. 1: 1염인 NaCI과 KCI에 대하여 w。 값은 각각 30과 19로 거의 일정하고 $MgCl_2$ 와 $CaCl_2$ 의 1:2염 에 대하여서는 1: 1염의 Wo값보다 훨씬 작은 5 이하의 값을 나타내었다

• 한국세라믹학회지
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• 제22권1호
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• pp.35-39
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• 1985

Synthetic mica $NaMg_{2.5}(Si_4O_{10})F_2 (Na-TSM)$ was treated with HCl solution and H-type exchange resin to investigate the chemical stability and the ion exchange by measuring the dissolution of chemical components and the exchanged $H^+$ ion. The replacement of $Na^+$ ion occurred in contact with HCl solution and H-type ion exchange resin at the surface of Na-TSM particles reached $Na^+$ ions at maximum value of 70~80%. $Mg^{2+}$ ion of octahedral layer became to dissolve from the pH2 solution and th amount of it dissolved in-creased almost proportional to $H^+$ ion concentration from around 0.02N $H^+$ ion equilibrium concentration. The crystalline structure of Na-TSM was destructed by dissolution of Mg2+ ion in cncentrated hydrochloric acid solution and resulted silica gel precipitation.

• 한국산림과학회지
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• 제83권1호
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• pp.32-37
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• 1994

리기다소나무와 잣나무 유묘에 인위적으로 산도를 조절한 인공산성우(pH 3.0, 4.0 및 5.0)와 지하수(pH 6.5)를 1992년 4월부터 1993년 8월까지, 생육기간 중에는 주 2회, 겨울철은 주 1회 1회 5mm의 강도로 처리하였다. 인공산성우를 처리하면서 수종별 침엽의 접촉각(contact angle)을 조사 비교하여 얻은 결과는 다음과 같다. 침엽의 표면과 물방울이 이루는 접촉각을 측정한 결과, 처리산성우의 산도수준이 높을수록 엽령이 높을수록 접촉각의 크기는 낮아졌다. 침엽의 접촉각을 측정 비교하는 방법은 야외에서 침엽수류에 대한 산성우 피해의 조기판단을 위한 매우 효과적인 기준이라 판단된다.

• 분석과학
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• 제6권5호
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• pp.435-442
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• 1993

루빈산이 결합된 카르복시메틸화된 폴리아민-폴리우레아(RCCPPI) 수지가 클로로카르복시메틸화된 폴리아민-폴리우레아(CCPPI) 수지와 루빈산으로부터 1단계 반응에 의하여 합성되었다. 이 수지의 구조는 적외선 분광광도법, 원소분석 및 시차열분석법으로 확인되었다. 이 수지에 대한 중금속 흡착특성은 용액의 pH를 변화시키면서 뱃치법에 의하여 분포계수($K_d$)를 측정하고, 프론탈크로마토그래피법으로 관류점을 측정하여 조사하였다. 중금속 이온용액을 이 수지로 충진된 관에 통과시킴에 의하여 고농도의 나트륨, 칼슘 및 아세트산염 용액 중에 존재하는 미량 중금속 이온을 최적 pH에서 농축 및 회수 정량할 수 있었다. 농축 인자는 25 이상이었고 흡착된 중금속들은 0.025M EDTA 용액(pH 9.0)으로 회수 정량하였다.

• 상하수도학회지
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• 제9권3호
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• pp.99-107
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• 1995

Various humic substances are widely distributed in natural water body, such as rivers and lakes and cause the yellowish or brownish color to water. The evidence that humic substances are precursors of THMs formation in chlorinated drinking water has been reported m the Jiteratures. For the reason of public health as well as aesthetics, needs for humic substances removal have been increased in the conventional water treatment processes. In this research, the characteristics of aluminium coagulation of humic acids and humic acids were investigated. The optimum pH and coagulants dosage to remove these materials simultaneously by coagulation were alto studied. The results are as followed; 1. UV-254 absorptiometry for measuring the concentration of aquatic humic acids showed good applicability and stable results. 2. The optimal pH range for humic acids removal by aluminium coagulation was 5 to 5.5, however, an increase in aluminium coagulant dosage could enhance the removal rate of humic acids in the wide pH range. 3. Coprecipitation of humic acids in the typical pH range of 6.5 to 8 in water treatment processes may require the sweep coagulation mechanism with the excess aluminium coagulant dosage. 4. Using PAC(poly aluminium chloride) or PASS(poly aluminium silica sulfate) as coagulants was able to expand the operating range for removing humic acids. 5. From the coagulation of humic substances(UV-254) and turbidity at pH range of 5.5 - 6.0 and alum dose of 86 ppm, the removal efficiency of turbidity from the reservoir water was above 90% and that of UV-254 was above 70%. 6. By using the reservoir water, the optimum condition of rapid mixing for simultaneous removal of turbidity and UV-254 absorbance was pH of 5.8 and LAS dose of 86 ppm, in this study.

• 한국산업보건학회지
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• 제9권2호
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• pp.100-109
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• 1999

This study evaluates the pretreatment for analysis of benzidine metabolites in urine by measuring the recovery rates according to the temperature and periods of storage of the urine. By the solid phas e extraction, the recovery rates of basic hydrolysis are benzidine 67.4 %, monoacetylbenzidine 105.1 %, and diacetylbenzidine 115.8 %, respectively. By the liquid extraction, the recovery rates of back-extraction into 0.1 M perchloric acid are benzidine 105.7%, monoacetylbenzidine 94.2 %, diacetylbenzidine 72.8 %, respectively. The difference of the recovery rates between the back-extraction into 0.1 M HCl and 0.1 M perchloic acid after basic hydrolysis are 101 % and 98.8 %, respectively. When the recovery rates of the urinary s amples of pH 3, pH 7, pH 12 at $25^{\circ}C$ and $-76^{\circ}C$ are compared for four weeks, there are no differences according to the temperature and the periods of storage. The above results show that the solid phase extraction and back-extraction by 0.1 M perchloric acid after basic hydrolys is are suitable for the analysis of benzidine metabolites. There are no difference of the recovery rates of the urinary samples stored at $25^{\circ}C$ and $-76^{\circ}C$ at pH 3, pH 7, pH 12, respectively for 28 days.

• 대한환경공학회지
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• 제35권3호
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• pp.200-205
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• 2013

전처리 공정은 막의 오염 정도를 제어할 수 있는 유일한 방법이다. 막의 오염 현상은 피할 수 없는 중요한 문제이며 RO 공급수로 적합한 전처리 공정의 선택이 중요하다. 본 연구는 pH, 해수의 탁도, 수온, 응집제 주입량 그리고 SDI 측정 막재질과 같은 SDI 값에 영향을 미치는 인자들을 평가 하기위해 수행되었다. 그 결과 해수의 탁도는 여과수의 SDI 값에 약간의 영향을 미친것으로 조사되었다. 0.45 um 공극 크기를 가지는 SDI 측정 막은 소수성 막 보다 동일한 재질의 친수성 막을 이용하는 것이 분석 결과의 신뢰성과 재현성을 확보할 수 있었다. pH 7.0 이하의 조건에서 pH가 감소할수록 SDI 값은 증가한 것으로 나타났다. 그리고 수온은 SDI 값은 큰 영향을 미친것으로 조사되었다.

• 지질공학
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• 제12권4호
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• pp.439-457
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• 2002

금정산-백양산 일원에 분포하는 50개소의 용천수와 6개소의 지하수에 대하여 9개 물리화학적 성분(온도, pH, Eh, EC, TDS, DO, 염분농도, 알칼리도, 용출량)을 측정하였다. 용천수의 pH는 5.06~8.38, 알칼리도는 7.93~102.21mg/1, EC는 $9.5~270\mu\textrm{s}/cm$, Eh는 64.2~685.9mV, DO는 4.57~12.13mg/l, 용출량은 4.26~182.2ml/s이다. 물리화학적 성분들의 통계적인 특성을 알기 위하여 일반통계분석을 실시하였으며 물리화학적 성분들간의 상관성을 분석하였다. 또한 용천수와 지하수의 물리화학적 성분을 비교하였다. DO, pH, Eh, EC, 알칼리도, 용출량의 공간적인 분포 특성을 알기 위하여 크리깅이 수행되었으며, 계산된 값을 성분들간의 공간적인 분포 비교를 위하여 표준화시켰다. 표준화된 값을 이용한 물리화학적 성분의 등치선도를 작성하여 각각의 성분의 이상대를 파악하였으며 서로 다른 성분들의 이상대를 비교 검토하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.322-322
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• 2010

For boron doping on n-type silicon wafer, around $1,000^{\circ}C$ doping temperature is required, because of the relatively low solubility of boron in a crystalline silicon comparing to the phosphorus case. Boron doping by fiber laser annealing and lamp furnace heat treatment were carried out for the uniformly deposited p-a-Si:H layer. Since the uniformly deposited p-a-Si:H layer by cluster is highly needed to be doped with high temperature heat treatment. Amorphous silicon layer absorption range for fiber laser did not match well to be directly annealed. To improve the annealing effect, we introduce additional lamp furnace heat treatment. For p-a-Si:H layer with the ratio of $SiH_4:B_2H_6:H_2$=30:30:120, at $200^{\circ}C$, 50 W power, 0.2 Torr for 30 min. $20\;mm\;{\times}\;20\;mm$ size fiber laser cut wafers were activated by Q-switched fiber laser (1,064 nm) with different sets of power levels and periods, and for the lamp furnace annealing, $980^{\circ}C$ for 30 min heat treatment were implemented. To make the sheet resistance expectable and uniform as important processes for the $p^+$ layer on a polished n-type silicon wafer of (100) plane, the Q-switched fiber laser used. In consequence of comparing the results of lifetime measurement and sheet resistance relation, the fiber laser treatment showed the trade-offs between the lifetime and the sheet resistance as $100\;{\omega}/sq.$ and $11.8\;{\mu}s$ vs. $17\;{\omega}/sq.$ and $8.2\;{\mu}s$. Diode level device was made to confirm the electrical properties of these experimental results by measuring C-V(-F), I-V(-T) characteristics. Uniform and expectable boron heavy doped layers by fiber laser and lamp furnace are not only basic and essential conditions for the n-type crystalline silicon solar cell fabrication processes, but also the controllable doping concentration and depth can be established according to the deposition conditions of layers.

• 동아시아식생활학회지
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• 제21권6호
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• pp.863-870
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• 2011

In this study, muffins containing Bokbunja, popularly known as a psychological activator and functional material, was made, and its preference levels and qualitative characteristics were evaluated. We measured the height and weight of muffins containing Bokbunja powder. Height decreased when the volume of Bokbunja powder increased (p<0.001). When weight was measured, there was no meaningful difference between the samples, although the Bokbunja powder-containing samples were heavier than the samples not containing Bokbunja powder. When we measured the weight and specific volume of the muffins containing Bokbunja powder, the specific volume decreased when the amount of Bokbunja powder increased (p<0.001). The moisture and pH levels of the muffins not containing Bokbunja powder were 17.04% and pH 8.59, respectively. As the volume of Bokbunja powder increased, the moisture level of Bokbunja muffin increased while the pH decreased, and there was a significant difference (p<0.001). As a result of measuring the colors of muffins, the brightness of the muffins containing Bokbunja powder decreased, and the muffins showed decreased yellowness index and increased redness. In measuring the texture of Bokbunja muffins, hardness decreased as the volume of Bokbunja power increased (p<0.001). Further, springness of the muffins decreased as the volume of Bokbunja powder increased, and there was a significant difference (p<0.001). The chewiness of the muffins not containing Bokbunja powder was higher than any other muffin sample, and there was a significant difference between the samples (p<0.001). Further, the cohesiveness of the decreased as the volume of Bokbunja powder increased (p<0.001). Bokbunja muffins showed a lower gumminess index than those not containing Bokbunja powder (p< 0.05). When the sensual qualities of the muffins were measured, the color, flavor, taste, and softness of all of the samples showed significant differences (p<0.001), and the muffins containing 8% Bokbunja powder showed the highest sensual quality indexes. When the general preference level for the muffins was measured, the muffins containing 8% Bokbunja powder showed the highest index, 7.03${\pm}$0.96. Based on this result, the ideal volume of Bokbunja powder when making muffins is 8%.