• Title/Summary/Keyword: measuring impedance

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Degradation Evaluation of PEM Water Electrolysis by Method of Degradation Analysis Used in PEMFC (고분자전해질 연료전지 열화 분석방법에 의한 PEM 수전해 열화 평가)

  • Oh, Sohyeong;Yang, Jinwon;Chu, Cheun-Ho;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.1-5
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    • 2021
  • The PEM(Proton Exchange Membrane)water electrolysis uses the same PEM electrolyte membrane as the PEM fuel cell and proceeds by the same reaction but the opposite direction. The PEM fuel cell has many methods of degradation analysis since many studies have been conducted on the degradation and durability of the membrane and catalyst. We examined whether PEM fuel cell durability evaluation method can be applied to PEM electrolytic durability evaluation. During the PEM electrolytic degradation process, LSV(Linear sweep voltammetry), CV(Cyclic voltammetry), Impedance, SEM(Scanning Electron Microscope) and FT-IR(Fourier Transform Infrared spectroscopy) were analyzed and compared under the same conditions as the PEM fuel cell. As the PEM fuel cell, hydrogen passing through the membrane was oxidized at the Pt/C electrode, and the hydrogen permeation current density was measured to analyze the degree of degradation of the PEM membrane. Electrode degradation could be analyzed by measuring the electrode active area (ECSA) by CV under hydrogen/nitrogen flowing conditions. While supplying hydrogen and air to the Pt/C electrode and the IrO2 electrode, the impedance of each electrode was measured to evaluate the durability of the electrode and membrane.

Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System (3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향)

  • Khan, Md. Al-Masrur;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.82-92
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    • 2022
  • This study aims to investigate the effect of total electrochemical cell resistance (TECR) on electrochemical impedance (EI) measurements of reinforced concrete (RC) by electrochemical impedance spectroscopy (EIS) using a three-electrode system. A series of experimental study is performed to measure electrochemical behavior of a steel bar embedded in a concrete cube specimen, with a side length of 200 mm, in various experimental conditions. Main variables include concrete dry conditions, coupling resistance between sensing electrodes and concrete surface, and area of the counter electrode. It is demonstrated that EI values remains stable when the compliant voltage of a measuring device is sufficiently great compared to the potential drop caused by TECR of concrete specimens. It is confirmed that the effect of the coupling resistance of TECR is far more influential than other two factors (concrete dry conditions and area of the counter electrode). The results in this study can be used as a fundamental basis for development of a surface-mount sensor for corrosion monitoring of reinforced concrete structures exposed to wet-and-dry cycles under marine environment.

A Clinical Study on Growth of Children Based on Analyzing Body compositions And Measuring Bone Age (체성분 분석과 골연령 측정을 통한 취학 전 아동의 성장에 대한 임상연구)

  • Yun, Hye-Jin;Lee, Yu-Jin;Han, Baek-Jung
    • The Journal of Pediatrics of Korean Medicine
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    • v.23 no.2
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    • pp.131-144
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    • 2009
  • Objectives : The purpose of this study is to have better data and to make efficient clinical reviews on pre-school children's growth based on two measurements; Body composition for measuring body volume and bone age for potential growth. Methods : The study was conducted with 221 children(118 of boys and 103 of girls) from three kindergartens. Body compositions(soft lean mass, body fat mass, percent body fat) were measured by bioelectrical impedance analysis, bone age was measured by bone density through ultrasonic image of calcaneus. Results and Conclusions : 1. The higher level on weight or BMI, the more averages of soft lean mass, body fat mass, percent body fat. 2. The average bone ages and bone age-chronological age were lower in under 50 percentile's group, but it was higher in upper 50 percentile's group. Also, children with high BMI had older in bone ages and bone age-chronological age. 3. The higher in height percentile based on the bone age; there were more soft lean mass. 4. The averages of bone age and bone age-chronological age were significantly decreased, the more percentiles of height according to bone age were big, they were higher than total average in under 50 percentile's group of height, lower than total average in over 50 percentile's group of height in both boys and girls. 5. The average of MPH were significantly decreased in top percentiles of children's height distribution. Also, in the upper percentiles of height distribution based on bone age were big in only boys. 6. The body compositions(soft lean mass, body fat mass, percent body fat) were related to body volume growth, which can he measured by weight or BMI. The bone age, bone age-chronological age, and MPH were related in terms of hight. The body volume growth was a little hit related with potential growth.

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A Study on a Prototype of ECG-Sensing ClothingBased on Textile Electrode for Lifestyle Monitoring (섬유전극을 기반으로 한 라이프스타일 모니터링용 ECG-센싱의류의 프로토타입 연구)

  • Kang, Da-Hye;Cho, Ha-Kyung;Song, Ha-Young;Cho, Hyun-Seung;Lee, Joo-Hyeon;Lee, Kang-Hwi;Koo, Su-Min;Lee, Young-Jae;Lee, Jeong-Whan
    • Science of Emotion and Sensibility
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    • v.11 no.3
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    • pp.419-426
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    • 2008
  • In order to develop "textile electrode - sensing clothing" which is a sort of smart clothing to measure electric activities of heart, we propose possible ways to develop textile electrode and design of sensing clothing, ultimately aiming to develop "ECG sensing clothing for lifestyle monitoring". Conventional sensors for measuring typical electric activities of heart keep certain distance between measuring electrodes to measure signals for electric activities of heart, but these sensors often cause inappropriate factors (e.g. motional artifacts, inconvenience of use, etc) for monitoring natural cardiac activities in our daily life. In addition, most of textile electrodes have made it difficult to collect data due to high impedance and unstable contact between skin and electrodes. To overcome these questions, we minimized distance between electrodes and skin to maximize convenience of use. And in order to complement contact between skin electrodes, we modified textile electrode's form and developed ways to design clothing. As a result, we could find out clinical significance by investigating possible associations of clinical electrocardiogram (ECG) with variation of distance between electrodes, and could also demonstrate clinically significant associations between textile electrode developed herein and clothing.

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A Study on the Noise Absorption of Textiles for Interiors (실내장식용 섬유소재의 흡음성에 관한 연구)

  • Choi, In-Ryu;Bang, Hey-Kyong
    • The Research Journal of the Costume Culture
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    • v.20 no.4
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    • pp.475-484
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    • 2012
  • The purpose of this study is to help to prevent daily noises by measuring the noise absorption coefficient of the non-woven fabrics and wallpapers which are commonly used in lining and noise absorption coefficient of lining curtain. Seven types of fiber materials for the interior decoration, one non-woven fabric for the wallpaper linings, and two types of textiles for curtain linings are used as the experimental materials in this study. The noise absorption coefficient of the noise absorbents were measured by using impedance tube. And the thermal transmittance were measured by using thermal transmittance tester. The results of this study are as follows; Observing the noise absorption efficiency of each experimental materials, the combination of fiber materials and linings, the noise absorption efficiency of cotton, polyester and silk were similar and for the experimental materials of flax, rayon, acrylic and nylon were resulted the similar noise absorption efficiency. The result of combination of fiber material and black fabric was highest among the combined linings. For the combination of fiber material and non-woven fabric, double layers of non-woven fabric resulted slightly higher noise absorption coefficient result than single layer of non-woven fabric. The thermal transmittance and the sound absorbents of experimental materials were affected by the thickness, density and layer of air of the experimental materials.

Ultrasonic Speed and Isentropic Compressibility of 2-propanol with Hydrocarbons at 298.15 and 308.15 K

  • Gahlyan, Suman;Verma, Sweety;Rani, Manju;Maken, Sanjeev
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.668-678
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    • 2017
  • Intermolecular interactions were studied for binary mixtures of 2-propanol + cyclohexane, n-hexane, benzene, toluene, o-, m- and p-xylenes by measuring ultrasonic speeds (u) over the entire range of composition at 298.15 K and 308.15 K. From these results the deviation in ultrasonic speed was calculated. These results were fitted to the Redlich-Kister equation to derive the binary coefficients along with standard deviations between the experimental and calculated data. Acoustic parameters such as excess isentropic compressibility ($K_s^E$), intermolecular free length ($L_f$) and available volume ($V_a$) were also derived from ultrasonic speed data and Jacobson's free length theory. The ultrasonic speed data were correlated by Nomoto's relation, Van Dael's mixing relation, impedance dependence relation, and Schaaff's collision factor theory. Van Dael's relation gives the best prediction of u in the binary mixtures containing aliphatic hydrocarbons. The ultrasonic speed data and isentropic compressibility were further analyzed in terms of Jacobson's free length theory.

The Effect of External DC Electric Field on the Atmospheric Corrosion Behaviour of Zinc under a Thin Electrolyte Layer

  • Liang, Qinqin;YanYang, YanYang;Zhang, Junxi;Yuan, Xujie;Chen, Qimeng
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.54-59
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    • 2018
  • The effect of external DC electric field on atmospheric corrosion behavior of zinc under a thin electrolyte layer (TEL) was investigated by measuring open circuit potential (OCP), cathodic polarization curve, and electrochemical impedance spectroscopy (EIS). Results of OCP vs. time curves indicated that the application of external DC electric field resulted in a negative shift of OCP of zinc. Results of cathodic polarization curves measurement and EIS measurement showed that the reduction current of oxygen increased while charge transfer resistance ($R_{ct}$) decreased under the external DC electric field. Variation of OCP negative shift, reduction current of oxygen, and $R_{ct}$ increase with increasing of external DC electric field strength as well as the effect of external DC electric field on double-layer structure in the electrode/electrolyte interface and ions distribution in thin electrolyte layer were analyzed. All results showed that the external DC electric field could accelerate the corrosion of zinc under a thin electrolyte layer.

A New Directional Coupler Type Partial Discharge Sensor Installed on the Power Lead of Rotating Machine

  • Yi, Sang-Hwa;Hwang, Don-Ha;Park, Wee Sang
    • Journal of Electrical Engineering and Technology
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    • v.11 no.6
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    • pp.1769-1776
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    • 2016
  • For on-line partial discharge (PD) monitoring of rotating machines, a novel sensor is proposed, which can be installed on the power lead inside the terminal box of the machine. The sensor has been designed to have high capacitance, and minimal reflection of measured pulses. As a sensitivity of the sensor, transfer impedance $Z_t$ has been measured and compared to conventional coupler-type sensors. A simple method is presented for measuring $Z_t$ of coupler sensors, using a vector network analyzer and a practical lead-cable of rotating machine. Through this method, it became possible to measure the $Z_t$ of coupler sensors including the installation environment of them. The $Z_t$ of the proposed sensor is higher than that of same sized other conventional couplers at frequencies between 30 and 92 MHz. Another sensitivity test has been performed using a PD calibrator as a test pulse source. The proposed sensor has higher measured peak voltage than the conventional coupler type sensors when the same charges were input.

A Numerical Analysis of Eddy-Current Electromagnetic Field for the In-Process Measurement of Case Depth in Laser Surface Hardening Processes (레이저 표면경화공정에서 경화층깊이의 실시간 측정을 위한 와전류 전자기장의 이론적 해석)

  • 박영준;조형석;한유희
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.3
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    • pp.529-539
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    • 1994
  • In laser heat treatment process of steels, the thin layer of substrate is rapidly heated to the austenitizing temperature and subsequently cooled at a very fast rate due to the self-quenching effect. Consequently, it is transformed to martensitic structure which has low magnetic permeability. This observation facilitates the use of a sensor measuring the change of electromagnetic field induced by the hardening layer. In this paper, the eddy-current electromagnetic field is analyzed by a finite element method. The purpose of this analysis is to investigate how the electrical impedance of the sensor's sensing coil varies with the change in permeability. To achieve this, a numerical model is formulated, taking into consideration the hardening depth, distance of the sensor from the hardened surface and the frequency driving the sensor. The results obtained by numerical simulation show that the eddy-current measurement method can feasibly be used to measure the changing hardening depth within the frequency range from 10 kHz to 50 kHz.

A Study on the Prevalence of Obesity and the Related Factors Among High School Girls (인문계와 실업계 여고생의 비만실태와 관련요인에 관한연구)

  • 유영순
    • Journal of the Korean Home Economics Association
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    • v.32 no.3
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    • pp.185-196
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    • 1994
  • The prevalence of obesity by measuring the amount of body fat and its related factors were investigated in 315 high school girls living in Seoul. Average body fat amount and body fat percentage measured by the body impedance analysis were 14.2$\pm$5.2kg and 25.9$\pm$7.0% respectively. Mean body mass index(BMI) was 2.1$\pm$2.7kg/m2 and 6.7% of the subjects showed over 25kg/m2 Correlative analysis reveal that the body fat percentage was significantly correlated to both relative body weight and BMI(r=0.66, P<0.01, r=0.68, P<0.01) Relative body weight of the subjects showed positive correlation to those of their mother and father. It was shown that many students skipped breakfast often and did not have a pleasant meal with enough time. There was no relationship between adiposity and dietary nutrient or energy intake. When subgroups of the subjects attending a non-vocational high school and those attending a vocational or technical school were compared obesity was more prevalent in the former. Therefore the burden caused by preparing the university entrance examination seems to play an important role in fat deposition.

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