• Title/Summary/Keyword: maximum stability temperature

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Stability of superconductor by integration formula

  • Seol, S.Y.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.3
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    • pp.1-5
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    • 2019
  • The superconductor stability theories are consistently described by the integral formula. If the defined stability function is a simple decreasing function, it becomes a cryogenic stability condition. If the stability function has a maximum value and a minimum value, and the maximum value is less than 0, then it is a cold-end recovery condition. If the maximum value is more than 0, it can be shown that the unstable equilibrium temperature, that is, the MPZ (minimum propagation zone) temperature distribution can exist. The MPZ region is divided into two regions according to the current ratio. At the low current ratio, the maximum dimensionless temperature is greater than 1, and at the relatively high current ratio, the maximum dimensionless temperature is less than 1. In order to predict the minimum quench energy, the dimensionless energy was obtained for the MPZ temperature distribution. In particular, it was shown that the dimensionless energy can be obtained even when the MPZ maximum temperature is 1 or more.

Decreased entropy of unfolding increases the temperature of maximum stability: Thermodynamic stability of a thioredoxin from the hyperthermophilic archaeon Methanococcus jannaschii

  • Lee, Duck-Yeon;Kim, Kyeong-Ae;Kim, Key-Sun
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.1
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    • pp.1-18
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    • 2004
  • A thioredoxin from hyperthermophile, Methanococcus jannashii (MjTRX) was characterized by use of the differential scanning calorimetry to understand the mechanisms of thermodynamic stability. MjTRX has an unfolding transition temperature of 116.5$^{\circ}C$, although the maximum free energy of the unfolding (9.9 Kcal/mol) is similar to that of E. coli thioredoxin (ETRX, 9.0 Kcal/mol). However, the temperature of maximum stability is higher than ETRX by 20$^{\circ}C$, indicating that the unfolding transition temperature increased by shifting the temperature of maximum stability. MjTRX has lower enthalpy and entropy of the unfolding compared to ETRX maintaining a similar free energy of the unfolding. From the structure and the thermodynamic parameters of MjTRX, we showed that the unfolding transition temperature of MjTRX is increased due to the decreased entropy of the unfolding. Decreasing the unfolded state entropy and increasing the folded state entropy can decrease the entropy of the unfolding. In the case of MjTRX, the increased number of proline residues decreased the unfolded state entropy and the increased enthalpy in the folded state increased the folded state entropy.

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Thermal Stability of Grubbs' Catalyst and Its Reactivity with Self-healing Agents (Grubbs' Catalyst의 열안정성 및 자가치료제와의 반응성 평가)

  • Yoon, Sung Ho;Shi, Ya Long;Feng, Jun;Jang, Se Yong
    • Composites Research
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    • v.28 no.6
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    • pp.395-401
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    • 2015
  • This study investigated the thermal stability of Grubbs' catalyst and its reactivity with self-healing agents for self-healing damage repair. Four types of Grubbs' catalyst supplied by manufacturers were considered and each catalyst was tested in as-received and grinded conditions. Four types of self-healing agents were prepared by varying the mixing ratio of dicyclopentadiene (DCPD) and 5-ethylidene-2-norbonene (ENB). Heat flows as a function of temperature were measured through a differential scanning calorimetry (DSC) to determine the thermal stability of catalysts. Reaction heats of self-healing agents with the catalyst were measured to evaluate the reactivity of the catalyst. For this evaluation, Fluka Chemika Grubbs' catalyst was used based on the maximum temperature and the time to reach the maximum temperature. According to the results, catalysts had different shapes depending on the manufacturer and the results showed that the smaller the size of the catalyst the higher the reactivity with self-healing agents. As the ENB ratio in self-healing agents increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. As the amount of the catalyst increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. Considering the thermal stability of the catalyst and its reactivity with the self-healing agent, combination of 0.5 wt% catalyst and the D3E1 self-healing agent was optimal for self-healing damage repair. Finally, as the thermal decomposition may occur depending on the environmental temperature, the catalyst must not be exposed to temperature higher than that is necessary to maintain the thermal stability of the catalyst.

Stability analysis of an uncooled segment of superconductor

  • Seol, S.Y.
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.3
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    • pp.8-12
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    • 2017
  • If the part of the HTS magnet is exposed to the outside of the cryogenic coolant due to the fluctuation of the height of the cooling liquid or the vapor generation, the uncooled part becomes very unstable. In this paper, the unstable equilibrium temperature distribution of the uncooled part of a superconductor is obtained, and the maximum temperature and energy are calculated as a function of the uncooled length. Similar to the superconductor stability problem, the current sharing model was applied to derive the theoretical formula and calculated by numerical integration. We also applied a jump model, which assumes that joule heat is generated in all of the uncooled segment, and compares it with the current sharing model results. As a result of the analysis, the stable equilibrium state and the critical uncooled length in the jump model are not shown in the current sharing model. The stability of the conductors to external disturbances was discussed based on the obtained temperature distribution, maximum temperature, and energy.

Effect of Siloxane Oligomer on Thermal Stability and Internal Stress of Epoxy Resins (실록산 올리고머가 에폭시 수지의 열안정성 및 내부응력에 미치는 영향)

  • Kwak, Geun-Ho;Park, Soo-Jin;Park, Jun-Ha;Kim, Kong-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.701-706
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    • 1999
  • The effect of siloxane oligomer content on thermal stability and internal stress of DGEBA epoxy resin was investigated. Siloxane-epoxy polymers having terminal epoxy group were prepared by reaction of siloxane-DDM prepolymer with DGEBA epoxy resin. Thermal stability was studied in terms of the initial decomposition temperature(IDT), temperature of maximum rate of weight loss($T_{max}$), integral procedural decomposition temperature(IPDT), and decomposition activation energy($E_t$) using TGA data. The thermal stability increased with increasing the siloxane oligomer content and showed a maximum value in the case of 5 wt% siloxane oligomer content in the blend system. While, the coefficient of thermal expansion(${\alpha}_r$) and the flexural modulus($E_r$) allowed us to study internal stress of the blend system. As the content of siloxane oligomer increases, the internal stress systematically decreases as decreasing both ${\alpha}_r$ and $E_r$.

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Scaling Factor Design Based Variable Step Size Incremental Resistance Maximum Power Point Tracking for PV Systems

  • Ahmed, Emad M.;Shoyama, Masahito
    • Journal of Power Electronics
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    • v.12 no.1
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    • pp.164-171
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    • 2012
  • Variable step size maximum power point trackers (MPPTs) are widely used in photovoltaic (PV) systems to extract the peak array power which depends on solar irradiation and array temperature. One essential factor which judges system dynamics and steady state performances is the scaling factor (N), which is used to update the controlling equation in the tracking algorithm to determine a new duty cycle. This paper proposes a novel stability study of variable step size incremental resistance maximum power point tracking (INR MPPT). The main contribution of this analysis appears when developing the overall small signal model of the PV system. Therefore, by using linear control theory, the boundary value of the scaling factor can be determined. The theoretical analysis and the design principle of the proposed stability analysis have been validated using MATLAB simulations, and experimentally using a fixed point digital signal processor (TMS320F2808).

A Study on Properties of Retentive Asphalt Concrete (보수성 아스팔트 콘크리트의 특성에 관한 연구)

  • Jang, Seck-Soo;Lee, Seung-Han;Jung, Yong-Wook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.565-568
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    • 2006
  • This study was retentive material into the porosities of the permeable asphalt concrete, we developed retentive asphalt concrete which can absorb water in rain and decrease the temperature of the pavement through the vaporization of rainwater. The experimental results showed that the maximum stability appeared in the 5.0% types of both AP-5 and SBS PMA. Between these two types, the maximum stability of the asphalt with AP-5 was 480kg, which means it met the stability requirement for walkways but didn't meet the requirement for roadways. On the other hand, the maximum stability of the asphalt concrete with SBS PMA was 676kg, which was 176 kg higher than the requirement for roadways(500kg) and satisfy the requirement of KS. The retentive material was 56.4% in the type of the retentive material with 30% diatomaceous earth, 66.6% in 50% type, 87.5% in 70% type. In the aspect of thermal properties, the retentive asphalt concrete can lower the surface temperature by about 15 degrees lower than the normal asphalt concrete can. This effect could be made by the evaporation cooling effect and the surface albedo. It should be noted that the evaporation cooling effect cools it by about 10 degrees and the surface albedo by about 5 degrees.

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Activity and stability of purified amylase produced by streptomyces aureofaciens 77

  • Ibrahim, A.N.;Ahmed, F.H.;Ibrahim, M.M.K.;Arafa, M.A.I.
    • Archives of Pharmacal Research
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    • v.13 no.1
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    • pp.33-37
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    • 1990
  • The effects of pH values, temperature and some elements on the amylolytic activity and stability of the purified S. aureofacienc 77 amylase were studied in this investigation. The purified enzyme showed its maximum activity at pH 6 within 8 min incubation at $40^{\circ}C$. None of the tested 6 metals showed on stimulatory effect on the enzymatic activity, $Fe^{+++}$, $Cu^{++}$ and $Hg^{++}$ at high dose inhibited the enzyme activity to great extent as compared with $Zn^{++}$, $Mn^{++}$ and $Fe^{++}$ whih gave less effect in this respect. The enzyme liquor was found to be thermolabile, since it lost completely its activity after 4 days incubation under room temperature and showed maximum activity during this period as a result of additions of $Ca^{++}$and NaCl, Gradual reduction was however recorded until activity reached 30% after 60 days of incubation.

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Enhancement of Thermal Stability in Photoluminescence by Carbonization of Porous silicon (다공성실리콘의 탄화를 이용한 PL의 열적안정성 증진)

  • 최두진;서영제;전희준;박홍이;이덕희
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.467-472
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    • 1997
  • Porous silicon was prepared by an anodic etching. The pore size was about 10 nm at an etching time of 20 sec and a current density of 20 mA/$\textrm{cm}^2$. The porous layer was composed of an micro-porous layer (0.6 ${\mu}{\textrm}{m}$) and a macro-porous layer (10 ${\mu}{\textrm}{m}$). Room temperature PL with maximum peak 6700$\AA$ appeared. The peak disappeared by an oxidation reaction when the porous silicon was heated to 100~20$0^{\circ}C$ in atmosphere. In order to avoid the oxidation a heat treatment was done in H2 atmosphere. The micro-pore and Si column, which formed quantum well, were collapsed by the high temperature. The PL maximum peak of heated sample was gradually red-shifted and showed about 300$\AA$ red-shift at 50$0^{\circ}C$. The intensity of PL was maintained to high temperatures in lower pressures. The porous Si was carbonized in C2H2+H2 gas in order to increase thermal stability. The carbonization of the porous Si prevented red-shift of the maximum PL peak caused by sintering effect at high temperatures, and the carbonized porous Si showed Pl signal at higher temperatures by above 20$0^{\circ}C$ than the sample in H2 atmosphere.

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Enhancement of Dimensional Stability of Compressed Open Cell Rigid Polyurethane Foams by Thermo-Mechanical Treatment

  • Ahn, WonSool
    • Elastomers and Composites
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    • v.50 no.1
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    • pp.30-34
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    • 2015
  • Thermo-mechanical treatment process of a compressed open-cell rigid polyurethane foam (OC-RPUF), which was fabricated for the vacuum insulation panel (VIP), was studied to obtain an optimum condition for the dimensional stability by the relaxation of compressive stress. Thermo-mechanical deformation of the sample OC-RPUF was shown to occur from about $120^{\circ}C$. Yield stress of 0.36 MPa was shown at about 10% yield strain. And, densification of the foam started to occur from 75% compressive strain and could be continued up to max. 90%. Compression set of the sample restored after initial compression to 90% at room temperature was ca. 82%. Though the expansion occurred to about twice of the originally compressed thickness in case of temperature rise to $130^{\circ}C$, it could be overcome and the dimensional stability could be maintained if the constant load of 0.3 MPa was applied. As the result, a thermo-mechanical treatment process, i.e, annealing process at temperature of $130{\sim}140^{\circ}C$ for about 20 min as is the maximum compressed state at room temperature, should be required for dimensional stability as an optimum condition for the use of VIP core material.