• Title/Summary/Keyword: material tests

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Mechanical behavior and microstructural characterization of different zirconia polycrystals in different thicknesses

  • Arcila, Laura Viviana Calvache;Ramos, Nathalia de Carvalho;Campos, Tiago Moreira Bastos;Dapieve, Kiara Serafini;Valandro, Luiz Felipe;de Melo, Renata Marques;Bottino, Marco Antonio
    • The Journal of Advanced Prosthodontics
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    • v.13 no.6
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    • pp.385-395
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    • 2021
  • PURPOSE. To characterize the microstructure of three yttria partially stabilized zirconia ceramics and to compare their hardness, indentation fracture resistance (IFR), biaxial flexural strength (BFS), and fatigue flexural strength. MATERIALS AND METHODS. Disc-shaped specimens were obtained from 3Y-TZP (Vita YZ HT), 4Y-PSZ (Vita YZ ST) and 5Y-PSZ (Vita YZ XT), following the ISO 6872/2015 guidelines for BFS testing (final dimensions of 12 mm in diameter, 0.7 and 1.2 ± 0.1 mm in thicknesses). Energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses were performed, and mechanical properties were assessed by Vickers hardness, IFR, quasi-static BFS and fatigue tests. RESULTS. All ceramics showed similar chemical compositions, but mainly differed in the amount of yttria, which was higher as the amount of cubic phase in the diffractogram (5Y-PSZ > 4Y-PSZ > 3Y-TZP). The 4Y- and 5Y-PSZ specimens showed surface defects under SEM, while 3Y-TZP exhibited greater grain uniformity on the surface. 5Y-PSZ and 3Y-TZP presented the highest hardness values, while 3Y-TZP was higher than 4Y- and 5Y-PSZ with regard to the IFR. The 5Y-PSZ specimen (0.7 and 1.2 mm) showed the worst mechanical performance (fatigue BFS and cycles until failure), while 3Y-TZP and 4Y-PSZ presented statistically similar values, higher than 5Y-PSZ for both thicknesses (0.7 and 1.2 mm). Moreover, 3Y-TZP showed the highest (1.2 mm group) and the lowest (0.7 mm group) degradation percentage, and 5Y-PSZ had higher strength degradation than 4Y-PSZ group. CONCLUSION. Despite the microstructural differences, 4Y-PSZ and 3Y-TZP had similar fatigue behavior regardless of thickness. 5Y-PSZ had the lowest mechanical performance.

A Study on Optimization of Perovskite Solar Cell Light Absorption Layer Thin Film Based on Machine Learning (머신러닝 기반 페로브스카이트 태양전지 광흡수층 박막 최적화를 위한 연구)

  • Ha, Jae-jun;Lee, Jun-hyuk;Oh, Ju-young;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.55-62
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    • 2022
  • The perovskite solar cell is an active part of research in renewable energy fields such as solar energy, wind, hydroelectric power, marine energy, bioenergy, and hydrogen energy to replace fossil fuels such as oil, coal, and natural gas, which will gradually disappear as power demand increases due to the increase in use of the Internet of Things and Virtual environments due to the 4th industrial revolution. The perovskite solar cell is a solar cell device using an organic-inorganic hybrid material having a perovskite structure, and has advantages of replacing existing silicon solar cells with high efficiency, low cost solutions, and low temperature processes. In order to optimize the light absorption layer thin film predicted by the existing empirical method, reliability must be verified through device characteristics evaluation. However, since it costs a lot to evaluate the characteristics of the light-absorbing layer thin film device, the number of tests is limited. In order to solve this problem, the development and applicability of a clear and valid model using machine learning or artificial intelligence model as an auxiliary means for optimizing the light absorption layer thin film are considered infinite. In this study, to estimate the light absorption layer thin-film optimization of perovskite solar cells, the regression models of the support vector machine's linear kernel, R.B.F kernel, polynomial kernel, and sigmoid kernel were compared to verify the accuracy difference for each kernel function.

Experimental Evaluation of Hydrate Formation and Mechanical Properties of Limestone Calcined Clay Cement (LC3) According to Calcination Temperature of Low-Quality Kaolin Clay in Korea (국산 저품질 고령토의 소성온도에 따른 석회석 소성점토 시멘트(LC3)의 수화물 생성 및 기계적 특성 평가)

  • Moon, Jae-Geun;Her, Sung-Wun;Cho, Seong-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.252-260
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    • 2022
  • In Korea, low-quality kaolin has significantly greater reserves and superior economic efficiency than high-purity kaolin. However, the utilization is low because it does not match the demand conditions of the market, and it is difficult to find a suitable source of demand. The purpose of this study is to derive the possibility and optimal calcination temperature of domestic low-quality kaolin that can be used as a raw material for limestone plastic clay cement (LC3). Isothermal calorimetry, X-ray diffraction analysis, Thermogravimetric Analysis, and compressive strength tests were conducted to evaluate hydrate generation and mechanical properties of LC3 paste according to calcination temperatures (600 ℃, 700 ℃, 800 ℃, 900 ℃). As a result, although 50 % of the clinker was replaced, the domestic low-quality kaolin clay produced calboaluminate hydrate and C(A)SH from the 3rd day of hydration, showing almost equal or higher strength to OPC, and there was a big difference in strength depending on the firing temperature.

Evaluation of the Stability of Ipseok-dae Columnar Joints in Mudeungsan National Park Using 3DEC (3DEC을 이용한 무등산국립공원 입석대 주상절리대의 안정성 평가)

  • Noh, Jeongdu;Kang, Seong Sueng
    • The Journal of Engineering Geology
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    • v.32 no.3
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    • pp.351-361
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    • 2022
  • Numerical analysis performed to predict the behavior of Ipseok-dae columnar joints in Mudeungsan National Park to understand their stability and movement. The numerical analysis technique, 3DEC, is based on the discrete element method that can analysis discontinuities. The analysis used data for material properties derived from laboratory tests, which found that average density was 2.68 kN/m3, average normal stiffness was 3.15 GPa/m, average shear stiffness was 1.00 GPa/m, average cohesion was 0.51 MPa, and the average friction angle was 33°. The Ipseok-dae columnar joints were modeled on the basis of the field survey data for 15 joints located between the observation platform and the hiking trail. The numerical analysis assessed the behavior of each columnar joint by interpreting the displacement of the edges of its upper and lower surfaces. The greatest maximum displacement was found in columnar joint No. 6, and the greatest minimum displacement was found in joint No. 11. Analyzing the movements of five discontinuities in joint No. 11 indicated that the maximum displacement occurred at the 2nd level. The other levels were ordered 5th, 4th, 1st, and 3rd in terms of subsequent greatest displacements. Considering the total displacement in the 15 studied joints, the Ipseok-dae columnar joints are judged to be stable. However, considering the cultural and historical value of Mudeungsan National Park, it is regarded that the currents slope stability should be maintained by monitoring the individual rock blocks of the joints.

Experiments of Water Mist System Application for Rack Storage (랙크식 창고에 대한 미분무 시스템 적용성 실험)

  • Myoung, Sang-Yup;Kim, Jong-Hoon
    • Journal of the Society of Disaster Information
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    • v.16 no.4
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    • pp.627-637
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    • 2020
  • Purpose: This experimental study was conducted to find out whether a water-mist fire suppression system can be applied to C.E.P., a representative combustible material of a rack storage. Method: First, it was confirmed whether the water-mist fire-extinguishing system used in this experiment was capable of extinguishing oil fires. After that, the C.E.P. boxes were loaded in the same small space as used in the oil fire experiment, and then the experiment was conducted on three scenarios; door opening, door closing, and door closing and increasing the internal load. The scenario was set considering the opening and space size conditions, which are important factors for the water-mist fire suppression. Result: Oil fire suppression tests have shown that fires are well extinguished in both the door open and closed conditions. In case of a fire of C.E.P. boxes in the same space condition as an oil fire, the fire was not extinguished in the door open condition. Fires were extinguished in the case with the door closed condition, but the afterglow was confirmed. Conclusion: In the oil fire suppression test, a water-mist fire suppression system extinguished a fire in both the door open and closed conditions. However, for the C.E.P fire, it was possible to extinguish only under the door closed condition, and there was a possibility of re-ignition.

Development of Real-Time Scheduling System for OHT Mission Planning (OHT 작업 계획을 위한 실시간 스케줄링 시스템 개발)

  • Lee, Bok-Ju;Park, Hee-Mun;Kwon, Yong-Hwan;Han, Kyung-Ah;Seo, Kyung-Min
    • KIPS Transactions on Computer and Communication Systems
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    • v.10 no.7
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    • pp.205-214
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    • 2021
  • For smart manufacturing, most semiconductor sites utilize automated material handling systems(AMHS). As one of the AMHSs, the OHT control system(OCS) manages overhead hoist transports(OHT) that move along rails installed on the ceiling. This paper proposes a real-time scheduling system to efficiently allocate and control the OHTs in semiconductor logistics processes. The proposed system, as an independent subsystem within the OCS, is interconnected with the main subsystem of the OCS, so that it can be easily modified without the effect of other systems. To develop the system, we first identify the functional requirements of the semiconductor logistics process and classify several types of control scenarios of the OHTs. Next, based on SEMI(Semiconductor Equipment and Materials International) standard, we design sequence diagrams and interface messages between the subsystems. The developed system is interoperated with the OCS main subsystem and the database in real time and performs two major roles: 1) OHT dispatching and 2) pathfinding. Six integrated tests were carried out to verify the functions of the developed system. The system was normally operated on six basic scenarios and two exception scenarios and we proved that it is suitable for the mission planning of the OHTs.

Investigation on Resistance to Hydrogen Embrittlement of High Nitrogen Austenitic Steels for Hydrogen Pipe by the Disc Pressure Test and the Tensile Test on Hydrogen Pre-charged Specimens (디스크 시험 및 수소처리 인장시험에 의한 수소배관용 고질소 스테인리스강의 내수소취성 평가 연구)

  • Dong-won, Shin;Min-kyung, Lee;Jeong Hwan, Kim;Ho-seong, Seo;Jae-hun, Lee
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.16-23
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    • 2022
  • In this study, characteristics of effect on hydrogen gas was investigated to hydrogen embrittlement by disk and tensile tests. The developed and commercial alloy was fabricated to a plate material made from an alloy ingot. The prepared materials were processed in the form of a disk to measure rupture pressure by hydrogen and helium gas at a rate of 0.1 to 1,000 bar/min. In the hydrogen pre-charged tensile test, a specimen was hydrogenated using an anode charging method, and the yield strength, ultimate tensile strength, elongation, and reduction in area rate were carried by a strain rate test. Also, the microstructure was observed to the fracture surface of the tensile test specimen. As a result, the developed materials satisfied endurable hydrogen embrittlement, and the fractured surface showed a brittleness fracture surface with a depth of several ㎛, but dimple due to ductile fracture could be observed.

Effect of Binder and Electrolyte on Electrochemical Performance of Si/CNT/C Anode Composite in Lithium-ion Battery (리튬이온 이차전지에서 Si/CNT/C 음극 복합소재의 전기화학적 성능에 대한 바인더 및 전해액의 효과)

  • Choi, Na Hyun;Kim, Eun Bi;Yeom, Tae Ho;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.327-333
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    • 2022
  • In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF6 (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.

Development and Effects of the Project to Increase Lacquer Production During the Japanese Colonial Era (일제강점기 옻칠 증산(增産) 사업의 전개와 영향)

  • KANG, Yeongyeong
    • Korean Journal of Heritage: History & Science
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    • v.55 no.3
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    • pp.22-44
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    • 2022
  • Lacquer, in addition to high-end crafts such as lacquerware inlaid with mother-of-pearl, was an important strategic material used in a wide range of fields such as industry, architecture, and munitions during the Japanese colonial era. In particular, as the demand for lacquer used in munitions soared in the 1940s when the war started, a ticket system was introduced to restrict its distribution. Meanwhile, Japan experienced a chronic shortage of lacquer as a result of the rapidly increasing demand for it, and thus went on to import Chinese lacquer after the late 19th century. After the 1910s, the market share of Chinese lacquer reached 90%, and the local situation in China began to affect the supply and demand for lacquer in Japan. To counteract the issue, the Japanese government increased the production of lacquer in Joseon. As for the project to increase lacquer production in Joseon, objective indicators were prepared through a number of tests in the 1910s and 20s, which paved the way for the project to begin in earnest in the 1930s. Lacquer trees were planted and training classes on how to collect lacquer were held throughout the country. The Japanese government promoted the lacquer production industry as a promising side job for Koreans. The project, implemented in various parts of the country, reaped fruitful results, and it provided the basis for lacquer production in Korea that has continued to this day. At that time, the major regions in the southern part of the country where the project was concentrated were Wonju, Okcheon, and Hamyang, regions that are still known today as major production sites. The improved method of collecting lacquer taught to Koreans by the Japanese has now become the main method of collecting lacquer in Korea. This study attempts to identify the current status of the project to increase lacquer production through various records from the Japanese colonial era with a view to contributing to the study of modern lacquer craft history.

UV/H2O2 Oxidation for Treatment of Organic Compound-spilled Water (UV/H2O2 산화를 활용한 유기오염물질 유출수 처리용 공정 연구)

  • Kim, Nahee;Lee, Sangbin;Park, Gunn;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.10
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    • pp.5-12
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    • 2022
  • In this study, we investigated the UV/H2O2 process to treat organic compound-spilled water. In consideration of usage and properties, benzene, toluene, phenol, and methyl ethyl ketone were selected as representative organic compounds. The selected material was first removed by natural volatilization and aeration that simulated the pretreatment of the prcoess. After that, UV/H2O2 oxidation experiments were conducted under various H2O2 concentration conditions. Benzene and toluene were mostly volatilized before reaching the oxidation process due to high volatility. Considering the volatility, oxidation experiments were performed at an initial concentration of 5 mg/L for benzene and toluene. The UV/H2O2 oxidation process achieved 100% of benzene and toluene removal after 20 minutes under all hydrogen peroxide concentration conditions. The phenol was rarely removed from the volatile experiments and oxidation tests were performed at an initial concentration of 50 mg/L. The process showed 100 % phenol removal after 30 minutes under 0.12 v/v% of hydrogen peroxide concentration condition. Methyl ethyl ketone was removed 58 % after 2 hours of volatile experiments. The process showed 99.7% Methyl ethyl ketone removal after 40 minutes under 0.08 v/v% of hydrogen peroxide concentration condition. It was confirmed that the UV/H2O2 process showed high decomposition efficiency for the four selected organic compounds, and identified the amount of hydrogen peroxide in classified organic contaminants.