• Title/Summary/Keyword: material balance

Search Result 529, Processing Time 0.024 seconds

Study of Self-assembled Organic Layer Formation at the HATCN/Au Interface

  • Kim, Ji-Hoon;Won, Sangyeon;Kwon, Young-Kyun;Kahng, Se-Jong;Park, Yongsup
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.150.2-150.2
    • /
    • 2013
  • We elucidate the mechanism of the self-assembled organic layer formation at the organic/metal interface of hexaaza-triphenylene-hexacarbonitrile (HATCN)/Au(111) by first-principles calculations and Lowtemperature scanning tunneling microscope (STM). In this work, we used HATCN to deposit organic material which is well known as an efficient OLED charge generation material. Low-temperature STM measurements revealed that self-assembled hexagonal porous structure is formed at terraces of Au(111). We also found that the hexagonal porous structure has chirality and forms only small (<1000 $nm^2$) phaseseparated chiral domains that can easily change their chiral phase in subsequence STM images at 80 K. To explain the mechanism of these observation, we calculated the molecular-molecular and molecule-surface interaction energies by using density functional theory method. We found that the change of their chiral phase resulted from the competition between the two energies. These results have not only verified our experimental observations, but also revealed the delicate balance between different interactions that caused the self-assembed structures at the surface.

  • PDF

Investigation of blasting impact on limestone of varying quality using FEA

  • Dimitraki, Lamprini S.;Christaras, Basile G.;Arampelos, Nikolas D.
    • Geomechanics and Engineering
    • /
    • v.25 no.2
    • /
    • pp.111-121
    • /
    • 2021
  • Large deformation and rapid pressure propagation take place inside the rock mass under the dynamic loads caused by the explosives, on quarry faces in order to extract aggregate material. The complexity of the science of rock blasting is due to a number of factors that affect the phenomenon. However, blasting engineering computations could be facilitated by innovative software algorithms in order to determine the results of the violent explosion, since field experiments are particularly difficult to be conducted. The present research focuses on the design of a Finite Element Analysis (FEA) code, for investigating in detail the behavior of limestone under the blasting effect of Ammonium Nitrate & Fuel Oil (ANFO). Specifically, the manuscript presents the FEA models and the relevant transient analysis results, simulating the blasting process for three types of limestone, ranging from poor to very good quality. The Finite Element code was developed by applying the Jones-Wilkins-Lee (JWL) equation of state to describe the thermodynamic state of ANFO and the pressure dependent Drucker-Prager failure criterion to define the limestone plasticity behavior, under blasting induced, high rate stress. A progressive damage model was also used in order to define the stiffness degradation and destruction of the material. This paper performs a comparative analysis and quantifies the phenomena regarding pressure, stress distribution and energy balance, for three types of limestone. The ultimate goal of this research is to provide an answer for a number of scientific questions, considering various phenomena taking place during the explosion event, using advanced computational tools.

Analysis of Thermal Runaway Phenomenon Caused by ZnO Varistor Operation Using Finite Element Method (유한요소법에 의한 ZnO 바리스터 동작 시 발생되는 열폭주 현상 해석)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.35 no.4
    • /
    • pp.372-376
    • /
    • 2022
  • Since the ZnO varistor is a semiconductor device, the internal thermal distribution during the varistor operation is recognized as an important factor in the performance and deterioration of the varistor. For an optimal varistor structure design, the thermal runaway phenomenon during the varistor operation was interpreted using the Comsol 5.2 analysis program by a finite element analysis. The maximum temperature of the center measured in the cross section of the ZnO varistor was confirmed to increase as the temperature moved from the lower electrode to the center towards the upper electrode up to 572.6 K. The electrodes are thinned so that the influence of the Schottky barrier is not great. The heat gradient balance is determined to be improved when the electrode of the hybrid form is introduced. The thickness, density, pore distribution, impurity uniformity, and particle size of the ZnO varistor are required, and it is determined that the pyrolysis gradient will be improved regardless of the electrode thickness. When these results are applied to design the ZnO varistor, the optimal structure of the ZnO varistor can be obtained.

Solution-Processed Quantum Dot Light-Emitting Diodes with TiO2 Nanoparticles as an Electron Transport Layer and a PMMA Insulating Layer (TiO2를 전자수송층으로 적용하고 PMMA 절연층을 삽입한 용액공정 기반 양자점 전계 발광 소자의 활용)

  • Kim, Bomi;Kim, Jungho;Kim, Jiwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.35 no.1
    • /
    • pp.93-97
    • /
    • 2022
  • We report highly efficient quantum dot light-emitting diodes (QLEDs) with TiO2 nanoparticles (NPs) as an alternative electron transport layer (ETL) and poly (methyl methacrylate) (PMMA) as an insulating layer. TiO2 NPs were applied as ETLs of inverted structured QLEDs and the effect of the addition of PMMA between ETL and emission layer (EML) on device characteristics was studied in detail. A thin PMMA layer supported to make the charge balance in the EML of QLEDs due to its insulating property, which limits electron injection effectively. Green QLEDs with a PMMA layer produced the maximum luminance of 112,488 cd/m2 and a current efficiency of 25.92 cd/A. We expect the extended application of TiO2 NPs as the electron transport layer in inverted structured QLEDs device in the near future.

Taiwan Agricultural Ecosystem Plant Investigation Methodology for Evaluating Agricultural Ecosystem Services

  • Tsai, Jenn-Kuo;Chen, Chi-Ling
    • Proceedings of the National Institute of Ecology of the Republic of Korea
    • /
    • v.3 no.1
    • /
    • pp.7-12
    • /
    • 2022
  • Farming practices that balance environmental friendliness with biodiversity are increasingly valuable. Wild plants on farmlands compete for nutrients with crops and create a crucial microhabitat and resources for animals such as natural enemies. Investigating farmlands and their surrounding plants with limited human and material resources has become an essential aspect of evaluating the agricultural ecosystem services. This study investigated plants in six agricultural long-term ecological research sites in Taiwan from 2017 to 2020 to determine the ideal season for investigation. Cluster analysis was performed to group habitats with similar plant composition, and the species-area curves of the clusters in each season were created. The results indicated that the agricultural ecosystem could be divided into farmlands, banks, orchards, and tea gardens. The habitats were divided into farmland, bank, Chia-Yi orchard, Gu-Keng orchard, and tea garden clusters. Ground plant cover can be investigated all year with at least 18 quadrats. However, if human and material resources are limited, 10 quadrats should be the minimum for farmlands in autumn and for the other microhabitats in spring. The minimum number of quadrats is 10 for banks, 17 for orchards, and 9 for tea gardens.

Friction and Wear Properties of Cu and Fe-based P/M Bearing Materials

  • Tufekci Kenan;Kurbanoglu Cahit;Durak Ertugrul;Tunay R. Fatih
    • Journal of Mechanical Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.513-521
    • /
    • 2006
  • The performances of porous bearings under different operating conditions were experimentally investigated in this study. Material groups studied are 90%Cu + 10%Sn bronze and 1%C + % balance Fe iron-based self-lubricating P/M bearings at constant (85%) density. In the experiments, the variation of the coefficient of friction and wear ratio of those two different group materials for different sliding speeds, loads, and temperatures were investigated. As a result, the variation of the friction coefficient-temperature for both constant load, and constant sliding speed, friction coefficient-average bearing pressure, PV-wear loss and temperature-wear loss curves were plotted and compared with each other for two materials, separately. The test results showed that Cu-based bearings have better friction and wear properties than Fe-based bearings.

Residence Time Distribution in the Chromatographic Column: Applications in the Separation Engineering of DNA

  • Park, Young G.
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • v.8 no.2
    • /
    • pp.117-125
    • /
    • 2003
  • Experimental and theoretical works were performed for the separation of large polyelectrolyte, such as DNA, in a column packed with gel particles under the influence of an electric field. Since DNA quickly orient in the field direction through the pores, this paper presents how intraparticle convection affects the residence time distribution of DNAs in the column. The concept is further illustrated with examples from solid -liquid systems, for example, from chromatography Showing how the column efficiency is improved by the use of a n electric field. Dimensionless transient mass balance equations were derived, taking into consideration both diffusion and electrophoretic convection. The separation criteria are theoretically studied using two different Peclet numbers in the fluid and solid phases. These criteria were experimentally verified using two different DNAs via electrophoretic mobility measurements. which showed how the separation position of the DNAs varies in the column in relation to the Peg/Pef values of an individual DNA. The residence time distribution was solved by an operator theory and the characteristic method to yield the column response.

A Study on the Analysis of Various Characteristics for the High Pressure are Discharge System (고압 아아크 방전시스템의 각종 특성 해석에 관한 연구)

  • 지철근;박왕열;이진우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.5 no.4
    • /
    • pp.35-42
    • /
    • 1991
  • Recently, HID lamps have been considered as important in regard to the trend of energy saving, and increasingly and diversely used in various ways. This paper will show the simulating models concerning high-pressure arc discharge system directly applicable for its design and manufacture, and analyze its various characteristics. For warm-up characteristics, the evaporating process of inner atoms is described in terms of second-order differential equation: for the thermal conduction from are axis to discharge wall and outer bulb, its transfer process is introduced according to five first-order differential equations. Under the steady state satisfying LTE, the time-variant characteristics are suggested by means of time-dependent energy balance equation derived from fluid equations, approximation of radiation energy and material functions in the discharge tube. The simulating models concerning these equations are then applied for high-pressure mercury lamp.

  • PDF

Operating Performance Analysis of 2.4MW FuelCell System (MCFC) (2.4MW급 발전용 연료전지시스템의 운전 성능분석)

  • Kang, MinKwan;Kim, Yunmi;Kim, Minki;Lee, Sanghoon;Cho, Yinjung
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.11a
    • /
    • pp.84.2-84.2
    • /
    • 2010
  • 발전용 연료전지시스템은 지구 온난화의 주요 원인인 $CO_2$의 발생을 기존 발전시스템에 비해 현저히 줄일 수 있는 친환경, 고효율 발전시스템으로서 분산형 발전이 가능한 혁신적인 발전시스템이다. 또한 전기 생산과 동시에 열을 발생시켜 소형열병합 발전을 함으로써 에너지효율을 극대화 할 수 있다. 본 논문에서는 2.4MW급 발전용 연료전지시스템 프로세스 모델링을 통해 얻은 결과 값인 Heat and Material Balance 데이터와 실제운전중인 데이터를 비교, 분석하여 운전시간, 온도, 고도 및 운전조건에 따른 출력특성을 파악함으로써 향후 프로세스 설계 시 정확도를 높일 수 있을 것이다.

  • PDF

Study on Sales Amount of Enterprise and Labor Employment (기업의 매출액과 종업원고용에 관한 고찰)

  • Son Jong-Ho;Im Jun-Sik
    • Management & Information Systems Review
    • /
    • v.12
    • /
    • pp.181-201
    • /
    • 2003
  • An employee employment of Enterprise must consider efficiency, balance attribute and effectiveness as important variable. but Our country's Enterprise reduce the personnel without basic guide line about employee employment. because Our country's Enterprise thinks of personnel expenses or sales amount decrease as important variable. Therefore, Research background sets out that there is no basic guideline for employment management one of the most important elements in Enterprise administration. and I examined employment control's concept and concept about softness of labor market in theoretical background setting. Also, was abreast of employment control effect, case study and literature research about employment control's basis. Finally, In fluctuation change of Enterprise's employee number, I examined which relation is formed in comparison with sales amount, net profit and the employee number of individual Enterprise using investment analysis material of Stock Company focused on Enterprise that stock is listed on the stock exchange.

  • PDF