• Title/Summary/Keyword: mass transfer model

Search Result 643, Processing Time 0.026 seconds

토양내 총 NAPL과 공기접촉 NAPL의 측정을 위한 분별 NAPL 분배 추적자 기술의 개발

  • 최경민;김헌기
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2004.09a
    • /
    • pp.29-32
    • /
    • 2004
  • Gaseous partitioning tracer test has been used for determining the volume and spatial distribution of residual non-aqueous phase liquid (NAPL) in the unsaturated soils. In this study, an experimental method for measuring the content of gas-exposed NAPL as well as that of total NAPL in a sand during air sparging was developed. Two different gaseous phase NAPL-partitioning tracers were used; n-pentane, with very low water solubility, was used as the tracer that partitions into NAPL that is only in contact with the mobile gas, and chloroform, with fairly good water solubility, was selected for detecting total NAPL content in the sand. Helium and difluromethanewere used as the non- reactive tracer and water-partitioning tracers, respectively. Using n-decane as a model NAPL (NAPL saturation of 0.018), 25.6% of total NAPL was detected by n-pentane at the water saturation of 0.68. Oniy 9.1% of total NAPL was detected by n-pentane at the water saturation of 0.84. This result implies that the quantity of gas-exposed NAPL increased about three times when the water saturation decreased from 0.84 to 0.68. At the water saturation of 0.68, more than 90% of total NAPL was detected by chloroform while 65.8% of total NAPL was detected by chloroform at the water saturation of 0.84. Considering that the removal rate of NAPL during air sparging for NAPL-contaminated aquifer is expected to be greatly dependent upon the spatial arrangement of NAPL phase with respect to the mobile gas, this new approach may provide useful information for investigating the mass transfer process during air-driven remedial processes fer NAPL-contaminated subsurface environment.

  • PDF

Removal of Trihalomethane Using Activated Carbon (활성탄(活性炭)을 이용(利用)한 Trihalomethane의 제거(除去)에 관한 연구(研究))

  • Chung, Tai Hak;Chung, Jae Chul
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.3 no.1
    • /
    • pp.73-79
    • /
    • 1983
  • Activated carbon has been widely used in water and wastewater treatment for removal of trace organics. The objective of this study was to define adsorption characteristics of trihalomethane(THM) on granular activated carbon(GAC) surfaces by laboratory experiments. Synthetic samples were prepared by adding chloroform into distilled and deionized water. The experiments conducted were a batch run and isotherm studies with five different temperature-pH levels. Adsorption of THM on GAC at an equilibrium condition was well described by the Freundlich isotherm equation. Lower temperature favored the adsorption, but the effect of pH was negligible. Utilizing the results of a batch run and the isotherm results, three parameters, mass transfer coefficient, pore diffusion coefficient, and surface diffusion coefficient, were evaluated by comparing with simulation results of an adsorption model. The results also showed that the pore diffusion was much greater than the surface diffusion.

  • PDF

A REVIEW OF CANDU FEEDER WALL THINNING

  • Chung, Han-Sub
    • Nuclear Engineering and Technology
    • /
    • v.42 no.5
    • /
    • pp.568-575
    • /
    • 2010
  • Flow Accelerated Corrosion is an active degradation mechanism of CANDU feeder. The tight bend downstream to Gray loc weld connection, close to reactor face, suffers significant wall thinning by FAC. Extensive in-service inspection of feeder wall thinning is very difficult because of the intense radiation field, complex geometry, and space restrictions. Development of a knowledge-based inspection program is important in order to guarantee that adequate wall thickness is maintained throughout the whole life of feeder. Research results and plant experiences are reviewed, and the plant inspection databases from Wolsong Units One to Four are analyzed in order to support developing such a knowledge-based inspection program. The initial thickness before wall thinning is highly non-uniform because of bending during manufacturing stage, and the thinning rate is non-uniform because of the mass transfer coefficient distributed non-uniformly depending on local hydraulics. It is obvious that the knowledge-based feeder inspection program should focus on both fastest thinning locations and thinnest locations. The feeder wall thinning rate is found to be correlated proportionately with QV of each channel. A statistical model is proposed to assess the remaining life of each feeder using the QV correlation and the measured thicknesses. W-1 feeder suffered significant thinning so that the shortest remaining life barely exceeded one year at the end of operation before replacement. W-2 feeder showed far slower thinning than W-1 feeder despite the faster coolant flow. It is believed that slower thinning in W-2 is because of higher chromium content in the carbon steel feeder material. The average Cr content of W-2 feeder is 0.051%, while that value is 0.02% for W-1 feeder. It is to be noted that FAC is reduced substantially even though the Cr content of W-2 feeder is still very low.

Research on an Optimal Trickling Surface of the Regenerator in a Solar Air-conditioning System (태양열 이용 냉난방 공조시스템중 재생기의 최적 재생면 구조에 관한 연구)

  • Kim, B.C.;Choi, K.H.;Kum, J.S.
    • Solar Energy
    • /
    • v.18 no.3
    • /
    • pp.185-195
    • /
    • 1998
  • The high viscosity of a LiCl(lithium chloride) solution as an absorbent in a solar energy regenerator causes a channeling phenomenon on the solar powered absorber plate surface when the solution is trickling down for regenerating itself. As this channeling phenomenon affects badly the heat and mass transfer, it is pertinent that this phenomenon be studied. Since regenerating performance of the solar energy regenerator depends on how the solution uniformly flows on the plate surface, an experiment on the structure of the plate surface for a model regenerator was conducted. Various shapes and structures of the plat surface down which the LiCl solution trickled were tested, and it was found that a tiered surface showed the highest water evaporation rate leaving more potential energy concentrating LiCl on the plate. It was also observed that the water evaporation rate depended largely on the pitch and height of the disturbing rods. In addition, the wider the contact area is and the longer the solution's flow time, the better the solar energy regenerator's performance.

  • PDF

Mass Transfer and Optimum Processing Conditions for Osmotic Conditions of Potatoes prior to Air Dehydration (열풍건조 전 감자의 삼투압농축시 물질이동과 공정의 최적화)

  • Kim, Myung-Hwan
    • Korean Journal of Food Science and Technology
    • /
    • v.22 no.5
    • /
    • pp.497-502
    • /
    • 1990
  • The effect of sugar concentration, immersion time and temperature on water loss, solid gain or loss, and sugar molality of potatoes during osmotic concentration was analyzed by a response surface methodology (RSM), and those values were predicted by using a second degree polynomial regression model. Effect of osmotic concentration and blanching on vitamin C retention of air dried potatoes (6% MC: wet basis) was also evaluated. The most significant factor was sugar concentration for water loss, solid gain or loss, sugar molality, rate parameter and retention of vitamin C. Second and third factors were immersion time and temperature respectively. Water loss and solid gain were rapid in the first 10 min and then levelled off. A 44.6% of water loss was observed during osmotic concentration using a sugar solution $(60\;Brix,\;80^{\circ}C$) with 20 min of immersion time. Dried potatoes after osmotic concentration had higher vitamin C content than dried potatoes after blanching. Optimum regions for osmotic concentration process of potatoes were $60-70^{\circ}C$ of immersion temperature, 60 Brix of sugar solution and 16-20 min of immersion time based on above 30% of water loss and 50% of vitamin C retention.

  • PDF

A Study of Design of Hollow Fiber Membrane Modules for using in Artificial Lung by the PZT Actuator

  • Kim, Gi-Beum;Kim, Seong-Jong;Hong, Chul-Un;Lee, Yong-Chul;Kim, Min-Ho
    • Journal of Biomedical Engineering Research
    • /
    • v.27 no.4
    • /
    • pp.143-153
    • /
    • 2006
  • The purpose of this work was to assess and quantify the beneficial effects of gas exchange, while testingto the various frequencies of the sinusoidal wave that was excited by the PZT actuator, for patients suffering from acute respiratory distress syndrome (ARDS) or chronic respiratory problems. Also, this paper considered a simulator to design a hollow type artificial lung, and a mathematical model was used to predict a behavior of blood. This simulation was carried out according to the Montecarno's simulation method, anda fourth order Runge-Kutta method was used to solve the equation. The experimental design and procedure are then applied to the construction of a new device to assess the effectiveness of the membrane vibrations. As a result, the vibration method is very effective in the increase of gas transport. The gas exchange efficiency for the vibrating intravascular lung assist device can be increased by emphasizing the following design features: consistent and reproducible fiber geometry, and most importantly, an active means of enhancing convective mixing of water around the hollow fiber membranes. The experimental results showed the effective performance of the vibrating intravascular lung assist device. Also, we concluded that important design parameters were blood flow rates, fiber outer diameter and oxygen pressure drop. Based on the present results, it was believed that the optimal level of blood flow rates was 200$cm^3$/min.

Characteristic Study on Effect of the Vent Mixer to Supersonic Fuel-Air Mixing with Stereoscopic-PIV Method (3차원 PIV 기법을 사용한 벤트혼합기가 초음속 연료-공기 혼합에 미치는 특성 연구)

  • Kim, Chae-Hyoung;Jeung, In-Seuck;Choi, Byung-Il;Kouchi, Toshinori;Masuya, Goro
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.16 no.4
    • /
    • pp.50-56
    • /
    • 2012
  • Vent mixer can provide main flow directly into a recirculation region downstream of the mixer to enhance fuel-air mixing efficiency. Based on experimental results of three-dimensional velocity, vorticity and turbulent kinetic energy obtained by a stereoscopic PIV method, the performance of the vent mixer was compared with that of the step mixer which was used as a basic model. Thick shear layers of the vent mixer induced the increase of the penetration height. The turbulent kinetic energy mainly distributed along a boundary layer between the main flow and the jet plume. This turbulent field activates mass transfer in a mixing region, leading to the mixing enhancement.

Comprehensive Consideration on the Discharge of Gases from Pressurized Vessels through Pressure Relief Devices (압력용기로부터 압력방출장치를 통한 가스 방출에 관한 포괄적 고찰)

  • Chung, Chang-Bock
    • Journal of the Korean Society of Safety
    • /
    • v.35 no.6
    • /
    • pp.32-45
    • /
    • 2020
  • The problem of determining the discharge rates of gases from pressurized vessels through pressure relief devices was dealt with comprehensively. First, starting from basic fluid flow equations, detailed modeling procedures were presented for isentropic nozzle flows and frictional flows in a pipe, respectively. Meanwhile, physical explanations were given to choking phenomena in terms of the acoustic velocity, elucidating the widespread use of Mach numbers in gas flow models. Frictional flows in a pipe were classified into adiabatic, isothermal, and general flows according to the heat transfer situation around the pipe, but the adiabatic flow model was recommended suitable for gas discharge through pressure relief devices. Next, for the isentropic nozzle flow followed by adiabatic frictional flow in the pipe, two equations were established for two unknowns that consist of the Mach numbers at the inlet and outlet of the pipe, respectively. The relationship among the ratio of downstream reservoir pressure to upstream pressure, mass flux, and total frictional loss coefficient was shown in various forms of MATLAB 2-D plot, 3-D surface plot and contour plot. Then, the profiles of gas properties and velocity in the pipe section were traced. A method to quantify the relationship among the pressure head, velocity head, and total friction loss was presented, and was used in inferring that the rapid increase in gas velocity in the region approaching the choked flow at the pipe outlet is attributed to the conversion of internal energy to kinetic energy. Finally, the Levenspiel chart reproduced in this work was compared with the Lapple chart used in API 521 Standatd.

A Numerical Study of Cathode Block and Air Flow Rate Effect on PEMFC Performance (고분자전해질 연료전지의 환원극 블록과 공기 유량 영향에 대한 전산 해석 연구)

  • Jo, Seonghun;Kim, Junbom
    • Applied Chemistry for Engineering
    • /
    • v.33 no.1
    • /
    • pp.96-102
    • /
    • 2022
  • Reactants of PEMFC are hydrogen and oxygen in gas phases and fuel cell overpotential could be reduced when reactants are smoothly transported. Numerous studies to modify cathode flow field design have been conducted because oxygen mass transfer in high current density region is dominant voltage loss factor. Among those cathode flow field designs, a block in flow field is used to forced supply reactant gas to porous gas diffusion layer. In this study, the block was installed on a simple fuel cell model. Using computational fluid dynamics (CFD), effects of forced convection due to blocks on a polarization curve and local current density contour were studied when different air flow rates were supplied. The high current density could be achieved even with low air supply rate due to forced convection to a gas diffusion layer and also with multiple blocks in series compared to a single block due to an increase of forced convection effect.

Wind-induced mechanical energy analyses for a super high-rise and long-span transmission tower-line system

  • Zhao, Shuang;Yan, Zhitao;Savory, Eric;Zhang, Bin
    • Wind and Structures
    • /
    • v.34 no.2
    • /
    • pp.185-197
    • /
    • 2022
  • This study aimed to analyze the wind-induced mechanical energy (WME) of a proposed super high-rise and long-span transmission tower-line system (SHLTTS), which, in 2021, is the tallest tower-line system with the longest span. Anew index - the WME, accounting for the wind-induced vibration behavior of the whole system rather than the local part, was first proposed. The occurrence of the maximum WME for a transmission tower, with or without conductors, under synoptic winds, was analyzed, and the corresponding formulae were derived based on stochastic vibration theory. Some calculation data, such as the drag coefficient, dynamic parameters, windshielding areas, mass, calculation point coordinates, mode shape and influence function, derived from wind tunnel testing on reducedscale models and finite element software were used in calculating the maximum WME of the transmission tower under three cases. Then, the influence of conductors, wind speed, gradient wind height and wind yaw angle on WME components and the energy transfer relationship between substructures (transmission tower and conductor) were analyzed. The study showed that the presence of conductors increases the WME of transmission towers and changes the proportion of the mean component (MC), background component (BC) and resonant component (RC) for WME; The RC of WME is more susceptible to the wind speed change. Affected by the gradient wind height, the WME components decrease. With the RC decreasing the fastest and the MC decreasing the slowest; The WME reaches the its maximum value at the wind yaw angle of 30°. Due to the influence of three factors, namely: the long span of the conductors, the gradient wind height and the complex geometrical profile, it is important that the tower-line coupling effect, the potential for fatigue damage and the most unfavorable wind yaw angle should be given particular attention in the wind-resistant design of SHLTTSs