• 제목/요약/키워드: mass transfer coefficients

검색결과 360건 처리시간 0.027초

오염물질에 대한 입상 활성탄의 흡·탈착 모델링 (Adsorption-Desorption Modeling of Pollutants on Granular Activated Carbon)

  • 왕창근
    • 대한토목학회논문집
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    • 제13권2호
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    • pp.279-285
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    • 1993
  • 여러 오염물질 사이의 흡착 경쟁, 평형, 물질확산의 상호 연관성을 이해하는 것은 효율적인 활성탄 흡착탑 설계 및 운전을 위하여 중요하다. 흡착탑내에서의 오염물질의 확산 및 흡착 현상을 동역학적 및 수학적으로 예측하기 위하여 "Micro-Diameter-Depth Adsorption System" Technique을 개발하여 평형 및 물질확산 계수들을 측정하였다. 활성탄 입자의 외부 "Film Transfer"와 입자 내부에서의 "Surface Diffusion"을 고려한 오염 물질 사이의 흡착경쟁, 탈착, Chromatographic Displacement Effect 등을 Homogeneous Surface Diffusion Model(HSDM)을 이용하여 예측했다. p-Chlorophenol(PCP)/p-Nitrophenol(PNP)의 Breakthrough Curve에서 PCP는 PNP에 의해 Displace되는 현상을 볼 수 있었으며 HSDM은 이를 잘 예측하였다. Dodecylbenzenesulfonate (DBS)는 흡착된 DBS의 일부분이 비가역적 흡착반응을 보인다는 가정하에서 HSDM에 의해 잘 예측될 수 있었다.

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역상 크로마토그래피에서 모멘트 방법과 van Deemter 식을 이용한 고리형 아데노신 일인산의 분리특성 연구 (Analysis of Cyclic Adenosine Monophosphate (cAMP) Separation via RP-HPLC (reversed-phase high-performance liquid chromatography) by the Moment Method and the van Deemter Equation)

  • 이일송;고관영;김인호
    • Korean Chemical Engineering Research
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    • 제53권6호
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    • pp.723-729
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    • 2015
  • 고성능액체크로마토그래피(high-performance liquid chromatography, HPLC)에서 C18(octadecyl silica, ODS) 칼럼에서 고리형 아데노신 일인산(cyclic adenosine monophosphate, cAMP)의 크로마토그램을 얻은 후, 모멘트 분석을 수행하였다. 일반속도 모델(general rate model, GR model)을 기반으로 first absolute moment와 second central moment를 계산하였다. 모멘트 분석의 중요한 세 가지 계수인 분자확산계수(molecular diffusivity, Dm), 외부물질전달계수(external mass transfer coefficient, kf), 입자내부확산계수(intra-particle diffusivity, De)는 각각 Wilke-Chang 식, Wilson-Geankoplis 식을 이용하고 이론단수(theoretical plate number) 식과 van Deemter 식을 비교하여 계산하였다. 실험은 각각 세 가지의 이동상 조성, 용질 농도, 유량 조건에서 수행하였다. Van Deemter 그래프를 그려 모멘트 분석결과를 정성적으로 정리했으며, 이론단 상당높이(height equivalent to a theoretical plate, HETP, Htotal)에 Hax, Hf, Hd가 미치는 영향을 알아보기 위해 van Deemter coefficient를 비교했다. HETP에 가장 큰 영향을 주는 요인은 입자내부확산(Hd)이었으며 외부물질 전달(Hf)는 그 영향이 매우 작았다.

수평평활 세관 내에서의 R-290, R-600a, R-22의 응축열전달과 압력강하 특성 (Condensation Heat Transfer Characteristics and Pressure Drop of R-290, R-600a, and R-22 in Horizontal Smooth Pipes with a Small Diameter)

  • 노건상;손창효
    • 청정기술
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    • 제14권1호
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    • pp.53-60
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    • 2008
  • 본 연구에서는 내경이 각각 5.80 mm와 10.07 mm인 두 개의 수평 이중관열교환기 내에서의 탄화수소계 냉매의 응축열전달과 압력강하에 대한 실험을 35.5210.4kg/m2s의 질량유속과 응축온도인 40C에서 수행하였다. 탄화수소계 냉매 R-290과 R-600a의 응축열전달계수가 프레온계 냉매인 R-22보다 높았다. 응축압력강하는 R-600a > R-290 > R-22 순으로 나타났고, 내경이 5.8 mm인 관 내 보다 10.07 mm인 관 내의 압력강하가 R-600a에서는 615 정도 높았으며, R-290과 R-22에서는 각각 9.812.52.14.6 정도 높게 나타났다. 실험으로 구한 응축열전달계수와 종래의 상관관계식을 비교해 본 결과, 모든 관경에 대해 Haraguchi 등의 상관관계식과 가장 좋은 일치를 보였다.

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Thermal Analysis of a Film Cooling System with Normal Injection Holes Using Experimental Data

  • Kim, Kyung-Min;Lee, Dong-Hyun;Cho, Hyung-Hee;Kim, Moon-Young
    • International Journal of Fluid Machinery and Systems
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    • 제2권1호
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    • pp.55-60
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    • 2009
  • The present study investigated temperature and thermal stress distributions in a film cooling system with normal injection cooling flow. 3D-numerical simulations using the FEM commercial code ANSYS were conducted to calculate distributions of temperature and thermal stresses. In the simulations, the surface boundary conditions used the surface heat transfer coefficients and adiabatic wall temperature which were converted from the Sherwood numbers and impermeable wall effectiveness obtained from previous mass transfer experiments. As a result, the temperature gradients, in contrast to the adiabatic wall temperature, were generated by conduction between the hot and cold regions in the film cooling system. The gradient magnitudes were about 10~20K in the y-axis (spanwise) direction and about 50~60K in the x-axis (streamwise) direction. The high thermal stresses resulting from this temperature distribution appeared in the side regions of holes. These locations were similar to those of thermal cracks in actual gas turbines. Thus, this thermal analysis can apply to a thermal design of film cooling holes to prevent or reduce thermal stresses.

6차 단일종단 이중모드 타원응답 필터의 회로망 파라미터 추출에 관한 연구 (Network Parameters of 6-Pole Dual-Mode Singly Terminated Elliptic Function Filter)

  • Lee, Juseop;Uhm, Man-Seok;Yom, In-Bok;Lee, Seong-Pal
    • 한국통신학회논문지
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    • 제28권7A호
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    • pp.557-562
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    • 2003
  • An output multiplexer of manifold type is widely used in a recent satellite transponder for its mass and volume reduction. For correct operation, the filters of such a multiplexer must be singly terminated. In this paper, a simple synthesis method of a 6-pole dual-mode singly-terminated filter is described. From the transfer function of the filter, network parameters such as in/output terminations and coupling coefficients are obtained easily without complicated matrix algebra such as orthogonal projection and similarity transformation. Two different-structure filters are taken into consideration and the network parameters of each filter have been extracted from the same transfer function. It is shown that the responses of two filters are same to each other since their network parameters are obtained from the same transfer function. The method described in this paper can be applied to the other degree singly terminated filter.

A Study on the Heat Transfer Enhancement of Miniature loop Heat Pipes by Using the Cu Nanofluids

  • Kim, Young-Sik;Jeong, Hyo-Min;Chung, Han-Shik;Tanshen, Md.Riyad;Lee, Dae-Chul;Ji, Myoung-Kuk;Bae, Kang-Youl
    • 동력기계공학회지
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    • 제17권2호
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    • pp.70-77
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    • 2013
  • An experimental study was carried out to understand the heat transfer performance of a miniature loop heat pipes using water-based copper nanoparticles suspensions as the working fluid. The suspensions consisted of deionized water and copper nanoparticles with an average diameter of 80 nm. Effects of the cupper mass concentration and the operation pressure on the average evaporation and condensation heat transfer coefficients, the critical heat flux and the total heat resistance of the mLHPs were investigated and discussed. The pressure frequency also depends upon the evaporator temperature which has been maintained from 60C to 90C. The Investigation shows 60% filling ratio gives the highest inside pressure magnitude of highest number pressure frequency at any of setting of evaporator temperature and 5wt% results the lowest heat flow resistance.

다단 물유동층 열교환기에 의한 보일러 배가스의 폐열 회수 성능에 관한 연구 (A Study on the Heat Recovery from Boiler Exhaust Gas with Multi-stage Water-fluidized-bed Heat Exchanger)

  • 김대기;박상일;김한덕
    • 대한기계학회논문집B
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    • 제25권12호
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    • pp.1776-1783
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    • 2001
  • Heat recovery from boiler exhaust gas with multi-stage water-fluidized-bed heat exchanger is analyzed in this study. The recovered energy here is not only sensible heat but also latent heat contained in the exhaust gas. In this system direct contact heat transfer occurs while exhaust gas passes through water bed and the thermal energy recovered this way is again delivered to the water circulating through heat exchanging pipes within the bed. Thus the thermal energy of exhaust gas can be recovered as a clean hot water. A computer program developed in this study can predict the heat transfer performance of the system. The results of experiments performed in this study agree well with the calculated ones. The heat and mass transfer coefficients can be fecund through these experiments. The performance increases as the number of stage increases. However at large number of stages the increasing rate becomes very low.

로봇 냉각을 위한 수냉식 냉각판의 성능 평가 (Performance Test of Liquid Cooling Type Cold Plates for Robot Cooling)

  • 이석원;강상우;황규대;김서영;리광훈
    • 설비공학논문집
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    • 제20권3호
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    • pp.189-196
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    • 2008
  • The increase of system weight due to installation of cooling devices adds electrical and mechanical loads of humanoid robot, and in return, results in much heat. Therefore, the weight of cooling system is a critical issue for robot cooling. In this study, we propose non-metallic cold plates to deal with such problems. We compare thermal performances between one metallic cold plate and five different types of non-metallic cold plates. A metallic cold plate is totally made of copper. Five non-metallic PC(polycarbonate) cold plates, which are designed to reduce the overall weight of robot cooling system, are composed of a polycarbonate cover with different types of base plate. The overall heat transfer coefficients per unit mass and thermal resistances are obtained for the cold plates. The metallic cold plate shows the best thermal performance. It is interesting to note that the PC cold plate with an aluminum base plate with 18 channels shows the best overall heat transfer coefficient per unit mass. Most polycarbonate cold plates display fairly comparable thermal performance with more reduced system weight compared to the metallic cold plate.

오블롱 셀 플레이트 열교환기에서의 R-l34a, R-407C, R-410A의 응축성능에 관한 실험적 연구 (Study on R-l34a, R-407C, and R-410A Condensation Performance in the Oblong Shell and Plate Heat Exchanger)

  • 박재홍;김영수
    • 대한기계학회논문집B
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    • 제28권12호
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    • pp.1535-1548
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    • 2004
  • Condensation heat transfer experiments were conducted with the oblong shell and plate heat exchanger without oil in a refrigerant loop using R-l34a, R-407C and R-410A. An experimental refrigerant loop has been developed to measure the condensation heat transfer coefficient hr and frictional pressure drop Δpf of the various refrigerants in a vertical oblong shell and plate heat exchanger. The effects of the refrigerant mass flux(40∼80kg/m2s), average heat flux(4∼8kW/m2), refrigerant saturation temperature(30∼40C) and vapor quality of refrigerants on the measured data were explored in detail. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. A comparison of the performance of the various refrigerants revealed that R-410A had the highest heat transfer performance followed by R-l34a, and R-407C had the lowest performance of the refrigerants tested. The pressure drops were also reported in this paper. The pressure drops for R-410A were approximately 45% lower than those of R-l34a. R-407C had 30% lower pressure drops than R-l34a. Experimental results were compared with several correlations which predicted condensation heat transfer coefficients and frictional pressure drops. Comparison with the experimental data showed that the previously proposed correlations gave unsatisfactory results. Based on the present data, empirical correlations of the condensation heat transfer coefficient and the friction factor were proposed.tor were proposed.sed.

고부하 유기성 폐수처리를 위한 분리막 결합형 순산소 고효율 포기장치의 총괄 산소전달효율 평가 (Comparison of Overall Oxygen Transfer Coefficient in the Membrane Coupled High Performance Reactor for a High Organic Loading Wastewater Treatment)

  • 강범희;임경호;이상민
    • 한국물환경학회지
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    • 제26권1호
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    • pp.81-88
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    • 2010
  • This study was conducted to find the capability of comparison of overall oxygen transfer coefficient in the membrane coupled high performance reactor (MPHCR) in treating high organic loading wastewater. Effluent quality had been analyzed while the influent organic loading rate was changed from 2 to 7kgCOD/m3day. The oxygen transfer coefficients had been investigated using two-phase nozzle for operating variables which were internal circulation flowrate (5~8 L/min), air flow rate (0.0125~0.2 L/min), liquid temperature (1020C), and pure-oxygen flow rate (0.0125~0.2 L/min). The overall oxygen transfer coefficient was increased with flowrate of internal circulation and air and high temperature. Especially, internal circulation flow rate showed distinct effect on overall oxygen transfer coefficient due to an increase of gas holdup and air-liquid contract area by two-phase nozzle. In the high range of organic loading rate from 4 to 7kgCOD/m3day, the removable efficiency of COD was 91%. Conventional activated sludge process usually treat organic loading from 0.32 to 0.64kgCOD/m3day however, the MPHCR can treat 10 to 20 times higher if it would be compared to the conventional activated sludge process. Foaming problem often happened and caused biomass wash out of the reactor, therefore, the foaming should be controlled for the enhanced operation.