• 제목/요약/키워드: mass size

검색결과 2,532건 처리시간 0.028초

Dialysis in double-pass cross-flow rectangular membrane modules with external recycle for improved performance

  • Yeh, Ho-Ming
    • Membrane and Water Treatment
    • /
    • 제2권2호
    • /
    • pp.75-89
    • /
    • 2011
  • The predicting equations for mass transfer rate in cross-flow rectangular dialyzers with double flow and recycle, have been derived by mass balances. The recycling operation has two conflicting effects. One is the desirable effect of the increase in fluid velocity, resulting in an increased mass transfer coefficient. The other is the undesirable effect of the reduction in concentration difference due to remixing, resulting in decreased mass-transfer driving force. In contrast a single-pass device without recycling, considerable improvement in mass transfer is achieved if the cross-flow rectangular dialyzer of same size is operated with double pass and external recycling. It is concluded that recycle can enhance mass transfer, especially for larger reflux ratio.

Determination of the Isotope Ratio for Metal Samples Using a Laser Ablation/Ionization Time-of-flight Mass Spectrometry

  • Song, Kyu-Seok;Cha, Hyung-Ki;Kim, Duk-Hyeon;Min, Ki-Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권1호
    • /
    • pp.101-105
    • /
    • 2004
  • The laser ablation/ionization time-of-flight mass spectrometry is applied to the isotopic analysis of solid samples using a home-made instrument. The technique is convenient for solid sample analysis due to the onestep process of vaporization and ionization of the samples. The analyzed samples were lead, cadmium, molybdenum, and ytterbium. To optimize the analytical conditions of the technique, several parameters, such as laser energy, laser wavelength, size of the laser beam on the samples surface, and high voltages applied on the ion source electrodes were varied. Low energy of laser light was necessary to obtain the optimal mass resolution of spectra. The 532 nm light generated mass spectra with the higher signal-to-noise ratio compared with the 355 nm light. The best mass resolution obtained in the present study is ~1,500 for the ytterbium.

대기 정체와 수용성 에어로졸 입자의 질량크기분포의 관계 (Effect of Air Stagnation Conditions on Mass Size Distributions of Water-soluble Aerosol Particles)

  • 박승식;유근혜
    • 한국대기환경학회지
    • /
    • 제34권3호
    • /
    • pp.418-429
    • /
    • 2018
  • Measurements of 24-hr size-segregated ambient particles were made at an urban site of Gwangju under high pressure conditions occurred in the Korean Peninsula late in March 2018. The aim of this study was to understand the effect of air stagnation on mass size distributions and formation pathways of water-soluble organic and inorganic components. During the study period, the $NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$, water-soluble organic carbon (WSOC), and humic-like substances(HULIS) exhibited mostly bi-modal size distributions peaking at 1.0 and $6.2{\mu}m$, with predominant droplet modes. In particular, outstanding droplet mode size distributions were observed on March 25 when a severe haze occurred due to stable air conditions and long range transport of aerosol particles from northeastern regions of China. Air stagnation conditions and high relative humidity during the study period resulted in accumulation of primary aerosol particles from local emission sources and enhanced formation of secondary ionic and organic aerosols through aqueous-phase oxidations of $SO_2$, $NO_2$, $NH_3$, and volatile organic compounds, leading to their dominant droplet mode size distributions at particle size of $1.0{\mu}m$. From the size distribution of $K^+$ in accumulation mode, it can be inferred that in addition to the secondary organic aerosol formations, accumulation mode WSOC and HULIS could be partly attributed to biomass burning emissions.

황사 시 제주지역 에어로졸의 수농도 특성 (The Characteristics of the Aerosol Number Concentration in Jeju Area During Asian Dust Events)

  • 강창희;허철구
    • 한국환경과학회지
    • /
    • 제22권3호
    • /
    • pp.347-358
    • /
    • 2013
  • The aerosol number concentration have measured with an aerodynamic particle sizer spectrometer(APS) at Gosan in Jeju Island, which is known as background area in Korea, from March 2010 to February 2011. The obtained results of asian dust events and non-asian dust period have been compared. The results show that the entire averaged aerosol number concentration from APS measurement during asian dust events and non-asian dust period are about 341 particles/$cm^3$ and 240 particles/$cm^3$, respectively. During asian dust events, the number concentration in small size ranges(${\leq}0.4{\mu}m$) are similar to non-asian dust period, however, those in large size ranges(${\geq}0.7{\mu}m$) are very higher than non-asian dust period. The contributions of the size resolved number concentration(23 channel in $0.25{\sim}10.0{\mu}m$) to total number concentration in that range are dramatically decreased with increased particle size. The contributions of smaller size ranges(${\leq}0.4{\mu}m$) during asian dust events are very low compared with non-asian dust period, on the other hand, those of larger size ranges(${\geq}0.4{\mu}m$) are higher than non-asian dust period. The number concentration in each size range are strongly correlated with the concentration in adjacent size range. And the total aerosol number concentration are depended on the number concentration in range of smaller than $0.58{\mu}m$ during non-asian dust period and asian dust events. On the other hand, $PM_{10}$ mass concentration has mainly affected with the number concentration in range of smaller than $1.0{\mu}m$ during non-asian dust period, however, during asian dust events, the mass concentration has mainly affected with the number concentration in range of $0.65{\sim}3.0{\mu}m$.

도시지역 낮.밤 대기에어로졸의 입경 별 수용성 유기탄소의 특성 (Characteristic of Size-Resolved Water-Soluble Organic Carbon in Atmospheric Aerosol Particles Observed during Daytime and Nighttime in an Urban Area)

  • 박승식;신동명
    • 한국입자에어로졸학회지
    • /
    • 제9권1호
    • /
    • pp.7-21
    • /
    • 2013
  • Twelve-hour size-resolved atmospheric aerosols were measured to determine size distributions of water-soluble organic carbon(WSOC) during daytime and nighttime, and to investigate sources and formation pathways of WSOC in individual particle size classes. Mass, WSOC, ${NO_3}^-$, $K^+$, and $Cl^-$ at day and night showed mostly bimodal size distributions, peaking at the size range of $0.32-0.55{\mu}m$(condensation mode) and $3.1-6.2{\mu}m$(coarse mode), respectively, with a predominant condensation mode and a minor coarse mode. While ${NH_4}^+$ and ${SO_4}^{2-}$ showed unimodal size distributions which peaked between 0.32 and $0.55{\mu}m$. WSOC was enriched into nuclei mode particles(< $0.1{\mu}m$) based on the WSOC-to-mass and WSOC-to-water soluble species ratios. The sources and formation mechanisms of WSOC were inferred in reference to the size distribution characteristics of inorganic species(${SO_4}^{2-}$, ${NO_3}^-$, $K^+$, $Ca^{2+}$, $Na^+$, and $Cl^-$) and carbon monoxide. Nuclei mode WSOC was likely associated with primary combustion sources during daytime and nighttime. Among significant sources contributing to the condensation mode WSOC were homogeneous gas-phase oxidation of VOCs, primary combustion emissions, and fresh(or slightly aged) biomass burning aerosols. The droplet mode WSOC could be attributed to aqueous oxidation of VOCs in clouds, cloud-processed biomass burning aerosols, and small contributions from primary combustion sources. From the correlations between WSOC and soil-related particles, and between WSOC and sea-salt particles, it is suggested that the coarse mode WSOC during daytime is likely to condense on the soil-related particles($K^+$ and $Ca^{2+}$), while the WSOC in the coarse fraction during nighttime is likely associated with the sea-salt particles($Na^+$).

암반설계정수 산정을 위한 증거이론의 적용 (Application of Evidence Theory for the Evaluation of Mechanical Rock Mass Properties)

  • 정용복;김태혁;최용근;선우춘
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
    • /
    • pp.521-528
    • /
    • 2005
  • The evaluation process of rock mass properties intrinsically contains some uncertainty due to the inhomogeneity of rock mass and the measurement error. Although various empirical methods for the determination of rock mass properties were suggested, there is no way of integrating various information on rock mass properties except averaging. For these reasons, this research introduces evidence theory which can model epistemic uncertainty and yield reasonable rock mass properties through combining various information such as empirical equations, in-situ test results, and so on. Through the application of evidence theory to the real site investigation and in situ experiment results, an interval of deformation modulus, cohesion and friction angle of rock mass were obtained. The ratios between lower and upper bound of those properties ranges from 1.6 to 3.6. Numerical analyses of circular hole using the properties for TYPE-2 rock mass were carried out. The magnitude or size of plastic region and radial displacement in case of lower bound properties is about 4 times larger than that of upper bound properties.

  • PDF

유방 촬영검사에서 사전조사 관전압과 실제조사 관전압 편차에 따른 원인 분석 (Analysis of the cause by Pre Exposure Tube Voltage and Actual Exposure Tube Voltage deviation in Mammography Examination)

  • 조지환;이효영;임인철
    • 한국방사선학회논문지
    • /
    • 제11권2호
    • /
    • pp.79-85
    • /
    • 2017
  • 본 연구에서는 유방촬영검사에서 사전조사 관전압과 실제조사 관전압 편차에 따른 원인분석을 유방압박두께, 유방크기, 체질량지수와 연관하여 규명하고 개선책을 찾고자 하였다. 국민건강보험공단에서 실시하는 유방촬영 검진자 중 40세 이상 여자 377명을 대상으로 조사하였다. 유방촬영검사에서 상하방향촬영에 의한 영상을 참고하여 의료영상저장정보시스템으로 전송되어진 선량 보고서(dose report)의 파라메타 중 사전조사 관전압과 실제조사 관전압의 편차에 따른 유방압박두께, 유방크기, 체질량지수를 분석하였다. 결과로는 유방압박두께가 얇을수록, 유방크기가 작을수록, 체질량지수가 작을수록 관전압 편차가 크게 나타났다. 결론적으로 유방촬영검사에서 유방압박두께와 유방크기에 따른 관전압 설정을 하기 위해 우리나라 실정에 맞는 유방촬영기기의 최소 관전압이 재설정 되어야 할 것이며, 또한 유방압박두께가 얇은 환자나 유방크기가 작은 환자를 검사할 경우 정확한 조사조건 매뉴얼을 만들어 검사함으로서 촬영조건의 편차를 줄여 방사선피폭 경감과 좋은 영상의 화질을 만드는데 노력해야 할 것으로 사료된다.

Characteristics of long-range transported PM2.5 at a coastal city using the single particle aerosol mass spectrometry

  • Cai, Qiuliang;Tong, Lei;Zhang, Jingjing;Zheng, Jie;He, Mengmeng;Lin, Jiamei;Chen, Xiaoqiu;Xiao, Hang
    • Environmental Engineering Research
    • /
    • 제24권4호
    • /
    • pp.690-698
    • /
    • 2019
  • Air pollution has attracted ever-increasing attention because of its substantial influence on air quality and human health. To better understand the characteristics of long-range transported pollution, the single particle chemical composition and size were investigated by the single particle aerosol mass spectrometry in Fuzhou, China from 17th to 22nd January, 2016. The results showed that the haze was mainly caused by the transport of cold air mass under higher wind speed (10 m·s-1) from the Yangtze River Delta region to Fuzhou. The number concentration elevated from 1,000 to 4,500 #·h-1, and the composition of mobile source and secondary aerosol increased from 24.3% to 30.9% and from 16.0% to 22.5%, respectively. Then, the haze was eliminated by the clean air mass from the sea as indicated by a sharp decrease of particle number concentration from 4,500 to 1,000 #·h-1. The composition of secondary aerosol and mobile sources decreased from 29.3% to 23.5% and from 30.9% to 23.1%, respectively. The particles with the size ranging from 0.5 to 1.5 ㎛ were mainly in the accumulation mode. The stationary source, mobile source, and secondary aerosol contributed to over 70% of the potential sources. These results will help to understand the physical and chemical characteristics of long- range transported pollutants.

Real-time measurements and modeling of sodium combustion aerosol dynamics in test chamber to improve the evaluation of SFR containment aerosol behaviour

  • Usha Pujala;Amit Kumar;Subramanian Venkatesan;Sujatha Pavan Narayanam;Venkatraman Balasubramanian
    • Nuclear Engineering and Technology
    • /
    • 제56권9호
    • /
    • pp.3483-3490
    • /
    • 2024
  • The initial size distribution and morphological parameters of sodium aerosols are critical in evaluating the accidental suspended aerosol behaviour in Sodium-cooled Fast Reactor (SFR) containment. Mass-based measurements were more familiar in characterizing the sodium aerosols. Real-time number size distribution measurements are carried out in this study. The sensitivity analysis of sodium aerosol effective density (ρe) in deriving the actual number size distributions from the measured Aerodynamic Particle Size Distributions (APSD) and predicting suspended aerosol dynamics is presented. Tests are conducted in a 1 m3 chamber at 47 ± 3% RH for different initial mass concentrations (M0) of 0.1, 1, and 2.9 g/m3. The initial APSDs measured just after the generation completions are observed to be polydisperse with the count median aerodynamic diameter (CMAD) < 1 ㎛. The literature reported ρe values of sodium aerosols, 2.27, 1.362, and 0.61 g/cm3 are used to derive mobility equivalent PSDs from APSD in each test. The real-time number concentration decay and size growth for four different PSDs are measured and compared with the estimate using nodal method-based code to ascertain the actual parameters. The validated parameters CMD = 0.66 ㎛, σg = 1.96, ρe = 1 g/cm3 and χ = 1 are used for improved estimation of sodium aerosol dynamics in Indian SFR containment with M0 = 4 g/m3 for severe accident scenarios.

Partial Resection of Maxillary Ossifying Fibroma in a Thoroughbred Stallion

  • Lee, Sang-Kyu;Kim, Byung Hyun;Luong, Richard;Jung, Bok-Sun;Im, Hyung-Ho;Lee, Jeonghun;Im, Eo-Jin;Lee, Inhyung
    • 한국임상수의학회지
    • /
    • 제35권3호
    • /
    • pp.107-110
    • /
    • 2018
  • A 5-year-old Thoroughbred race horse was presented to Busan Korea Racing Authority equine hospital with a 3-year history of a slow-growing left rostral maxillary mass. The location and progressive growth of the mass eventually resulted in poor food prehension, quidding and mouth bit placement. The mass was solitary and hard, and covered by normal smooth oral mucosa. Radiographic examination of the maxillae showed a flocculated and mixed radiolucent lesion protruding outward and displacing the 202 and 203 teeth caudally. The 202 tooth was in normal size and the 203 tooth was hypoplastic on radiography. Under general anesthesia, a partial surgical resection of the mass was performed to minimize functional loss and facilitate prompt return to track. After surgery, there was improvement in food intake, mouth bit placement, and cosmetic appearance. Histopathological examination determined the resected maxillay mass to be an ossifying fibroma. However, there was continued growth of remnant mass in the maxilla. Equine ossifying fibroma is a rare condition and primarily affects the rostral mandible, and less commonly, the maxillae. In this case, the lesion was slow-growing, and caused cosmetic and functional impairments, including poor food intake and reduced trainability. Surgical resection was performed, but the effect of treatment was limited due to advanced size / stage of the tumor. Early dental care is suggested for horse owners to prevent belated identification and improve successful treatment of oral disorders like ossifying fibroma.