• Title/Summary/Keyword: manufacturing cells

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Electrochemical Characteristics of the Oxygen Electrode for Alkaline Fuel Cells -Impregnation of Silver Catalyst on Carbon Black with Colloidal Method- (알칼리형 연료전지용 산소극의 전기화학적 특성고찰 -콜로이드 방법에 의한 카본블랙상 은촉매담지-)

  • Lee, Hong-Ki;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.701-709
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    • 1992
  • Silver particles were impregnated on carbon black with colloidal method and used as catalyst for oxygen electrode in alkaline fuel cell. With the addition of sodium dodecylbenzenesulfonate in $AgNO_3$ and $NaBH_4$solution, colloidal solution was made and confirmed with electrophoresis test. Effects of particle size on electrode performance were studied and $200{\AA}$ of silver particle size shown the highest value of mass activity. The aggromeration of silver particle was Influenced with surfactant amount, stirring time and heat treatment. Considering the increase of particle size caused of operating temperature, recommendable particle size of silver catalyst for manufacturing the electrode was $100{\AA}$. Dispersity of carbon black was investigated and reagglomeration was appeared after homogenizing 30 sec.

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Decision Tree based Scheduling for Static and Dynamic Flexible Job Shops with Multiple Process Plans (다중 공정계획을 가지는 정적/동적 유연 개별공정에 대한 의사결정 나무 기반 스케줄링)

  • Yu, Jae-Min;Doh, Hyoung-Ho;Kwon, Yong-Ju;Shin, Jeong-Hoon;Kim, Hyung-Won;Nam, Sung-Ho;Lee, Dong-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.1
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    • pp.25-37
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    • 2015
  • This paper suggests a decision tree based approach for flexible job shop scheduling with multiple process plans. The problem is to determine the operation/machine pairs and the sequence of the jobs assigned to each machine. Two decision tree based scheduling mechanisms are developed for static and dynamic flexible job shops. In the static case, all jobs are given in advance and the decision tree is used to select a priority dispatching rule to process all the jobs. Also, in the dynamic case, the jobs arrive over time and the decision tree, updated regularly, is used to select a priority rule in real-time according to a rescheduling strategy. The two decision tree based mechanisms were applied to a flexible job shop case with reconfigurable manufacturing cells and a conventional job shop, and the results are reported for various system performance measures.

Measurement of Electrical Conductivity of Glass Melter at High Temperature (유리 용융물의 고온에서 전기 전도도 측정)

  • Kim, Taesam;Kil, Daesup;Jung, Hunsaeng;Kang, Eunhee;Yoon, Soksung
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.775-780
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    • 2000
  • The electrical conductivity of glass melter at high temperature has been measured. The conductivity is an important physical property for the research and the manufacturing process of glass. Because high temperature is an inconvenient situation to measure the conductivity of glass melter, we have made a platinum crucible and electrode and have measured the conductivity at high temperature. KCl solution, of which concentration is adjusted to the conductivity of glass melter, is used to get parameters of the conductivity cell. A measuring circuit is composed with an AC 1 kHz sine wave generator and an operational amplifier. The cell constants are determined from the measured voltages and the equivalent conductances of KCl solution. Various cells are tested to find a suitable shape for high temperature experiment. The results are compared by cell size, electrode depth, and cell configuration. The conductivity of the borosilicate melter is $0.053{\Omega}^{-1}cm^{-1}$ at $1,450^{\circ}C$.

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Research Trend of Organic/Inorganic Composite Membrane for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지용 유.무기 복합막의 연구개발동향)

  • Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.155-170
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    • 2012
  • Fuel cells have been considered as alternative power generation system in the twenty-first century because of eco-friendly system, high power density and efficiency compare with petroleum engine system. Proton exchange membranes (PEMs) are the key components in fuel cell system. Currently, Nafion has been used in fuel cell system. However, Nafion has disadvantages such as low conductivity at high temperature and high cost. The researchers have focused to reach the high properties such as high proton conductivity, low permeability to fuel, good chemical/thermal stability, good mechanical properties and low manufacturing cost. Various methods have been developed for preparation of proton exchange membrane with high performance and commercialization of fuel cell system. The hybrid organic/inorganic membrane has the potentials to provide a unique combination of organic and inorganic properties with improved proton conductivity and mechanical property at high temperatures. So, this paper presents an overview of research trend for the composite membranes prepared by organic/inorganic system using various inorganic materials.

Heat Treatment of Cu0.9In0.7Ga0.3Se2 Powder Layer with a Mixture of Selenium and Ceramic Powder (셀레늄과 세라믹 혼합분말을 사용한 Cu0.9In0.7Ga0.3Se2 분말층의 소결거동 연구)

  • Song, Bong-Geun;Hwang, Yoonjung;Park, Bo-In;Lee, Seung Yong;Lee, Jae-Seung;Park, Jong-Ku;Lee, Doh-Kwon;Cho, So-Hye
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.115-119
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    • 2014
  • $Cu(In,Ga)Se_2$ (CIGS) thin films have been used as a light absorbing layer in high-efficiency solar cells. In order to improve the quality of the CIGS thin film, often selenization step is applied. Especially when the thin film was formed by non-vacuum powder process, selenization can help to induce grain growth of powder and densification of the thin film. However, selenization is not trivial. It requires either the use of toxic gas, $H_2Se$, or expensive equipment which raises the overall manufacturing cost. Herein, we would like to deliver a new, simple method for selenization. In this method, instead of using a costly two-zone furnace, use of a regular tube furnace is required and selenium is supplied by a mixture of selenium and ceramic powder such as alumina. By adjusting the ratio of selenium vs. alumina powder, selenium vaporization can be carefully controlled. Under the optimized condition, steady supply of selenium vapor was possible which was evidently shown by large grain growth of CIGS within a thin powder layer.

Influence of the Thin Anode Geometry on the Performance of Molten Carbonate Fuel Cells (얇은 연료극 구조가 용융탄산염 연료전지 성능에 미치는 영향)

  • Seo, Dong-Ho;Park, Dong-Nyeok;Yoon, Sung-Pil;Han, Jong-Hee;Oh, In-Hwan
    • Journal of Hydrogen and New Energy
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    • v.22 no.5
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    • pp.599-608
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    • 2011
  • The Ni-Al anodes of the molten carbonate fuel cell (MCFC) with three different structures were successfully fabricated in order to reduce the thickness of the anode down to 0.3 mm; one was the non-supported anode made by a conventional tape casting method, and others were the supported anodes made by lamination or direct casting on the nickel screen. It was seen from the physical analyses and cell operation that the supported thin anodes made by direct casting showed good mechanical strength and cell performance because of a good contact between the anode materials and the support. The single cell using the above anode showed the cell voltage of 0.858 V at the current density of 150$mA/cm^2$ with the nitrogen cross-over of only 0.6% at the operation time of 1,000 h, which was similar to the performance of the conventional thick (0.7 mm) anode. The ability to utilize a thin configuration of anode should cut down the amount of nickel alloy and consequently reduce its manufacturing cost.

Front-side Texturing of Crystalline Silicon Solar Cell by Micro-contact Printing (마이크로 컨텍 프린팅 기법을 이용한 결정질 실리콘 태양전지의 전면 텍스쳐링)

  • Hong, Jihwa;Han, Yoon-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.11
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    • pp.841-845
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    • 2013
  • We give a textured front on silicon wafer for high-efficiency solar cells by using micro contact printing method which uses PDMS (polydimethylsiloxane) silicon rubber as a stamp and SAM (self assembled monolayer)s as an ink. A random pyramidal texturing have been widely used for a front-surface texturing in low cost manufacturing line although the cell with random pyramids on front surface shows relatively low efficiency than the cell with inverted pyramids patterned by normal optical lithography. In the past two decades, the micro contact printing has been intensively studied in nano technology field for high resolution patterns on silicon wafer. However, this promising printing technique has surprisingly never applied so far to silicon based solar cell industry despite their simplicity of process and attractive aspects in terms of cost competitiveness. We employ a MHA (16-mercaptohexadecanoic acid) as an ink for Au deposited $SiO_2/Si$ substrate. The $SiO_2$ pattern which is same as the pattern printed by SAM ink on Au surface and later acts as a hard resist for anisotropic silicon etching was made by HF solution, and then inverted pyramidal pattern is formed after anisotropic wet etching. We compare three textured surface with different morphology (random texture, random pyramids and inverted pyramids) and then different geometry of inverted pyramid arrays in terms of reflectivity.

Study and Application of the New Stick Make Up Product Using Clay Minerals as Binder & Buffer.

  • Kim, Sang-Je;Shin, Dong-Uk;Cho, Pan-Gu;Jung, Chul-Hee
    • Proceedings of the SCSK Conference
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    • 1999.10a
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    • pp.97-110
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    • 1999
  • The new stick make-up product was studied by using a gel, which is a viscous complex formed with clay minerals, vitamins A and I and fluorinated liquid polymer with a 1500 molecular weight. The gel cannot be obtained with any random combination of clay minerals and the ingredients described above. It takes the sequential manufacturing method as follows to get this kind of gel. Firstly, clay minerals and liquid polymers have ·to be pre-mixed in order to saturate the liquid polymers with the clay minerals. Then tile on-processed gel has to be finely crystallized. The clay minerals, which are the core elements for this gel, were used as a function of Binder & Buffer and liquid polymer was mixed together for the deterioration of the surface tension of each component and to from a functional film in the gel. This liquid polymer was combined with clay minerals because it is not miscible with most oils and solvents. Waxes have a function of keeping a solid status in the stick. We reduced the usage of waxes by putting clay minerals as buffer in the proportion of 0.5 : 1 with oil phase. Ceramide takes care of the skin when used regularly and maintains the skin’s moisture. Vitamins A and I contribute to preventing skin’aging by the activation of skin cells. We could get the stable viscous gel, which has about 80% oil phase using clay minerals and liquid polymer, The crystal 1 me structures of gel were surface-chemical1y-analyzed using SEM and Image Analyzer and were thermodynamically analyzed using DSC, Surface tension test and softness were done by Rheometer. In the end, these characteristics were verified by consumer panel tests in Seoul, Baegeon and Pusan in Korea and Hokkaido, Oska and Miyazaki in Japan with correlation to the climate.

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Structure of the Tripartite Multidrug Efflux Pump AcrAB-TolC Suggests an Alternative Assembly Mode

  • Kim, Jin-Sik;Jeong, Hyeongseop;Song, Saemee;Kim, Hye-Yeon;Lee, Kangseok;Hyun, Jaekyung;Ha, Nam-Chul
    • Molecules and Cells
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    • v.38 no.2
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    • pp.180-186
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    • 2015
  • Escherichia coli AcrAB-TolC is a multidrug efflux pump that expels a wide range of toxic substrates. The dynamic nature of the binding or low affinity between the components has impeded elucidation of how the three components assemble in the functional state. Here, we created fusion proteins composed of AcrB, a transmembrane linker, and two copies of AcrA. The fusion protein exhibited acridine pumping activity, suggesting that the protein reflects the functional structure in vivo. To discern the assembling mode with TolC, the AcrBA fusion protein was incubated with TolC or a chimeric protein containing the TolC aperture tip region. Three-dimensional structures of the complex proteins were determined through transmission electron microscopy. The overall structure exemplifies the adaptor bridging model, wherein the funnel-like AcrA hexamer forms an intermeshing cogwheel interaction with the ${\alpha}$-barrel tip region of TolC, and a direct interaction between AcrB and TolC is not allowed. These observations provide a structural blueprint for understanding multidrug resistance in pathogenic Gram-negative bacteria.

A Review of Withering in the Processing of Black Tea

  • Deb, Saptashish;Jolvis Pou, K.R.
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.365-372
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    • 2016
  • Purpose: Tea is the most frequently consumed drink worldwide, next to water. About 75% of the total world tea production includes black tea, and withering is one of the major processing steps critical for the quality of black tea. There are two types of tea withering methods: physical and chemical withering. Withering can be achieved by using tat, tunnel, drum, and trough withering systems. Of these, the trough withering system is the most commonly used. This study focuses on the different types of withering, their effect on the various quality attributes of tea, and other aspects of withering methods that affect superior quality tea. Results: During physical withering, tea shoots loose moisture content that drops from approximately 70-80% to 60-70% (wet basis). This leads to increased sap concentration in tea leaf cells, and turgid leaves become flaccid. It also prevents tea shoots from damage during maceration or rolling. During chemical withering, complex chemical compounds break down into simpler ones volatile flavor compounds, amino acids, and simple sugars are formed. Withering increases enzymatic activities as well as the concentration of caffeine. Research indicates that about 15% of chlorophyll degradation occurs during withering. It is also reported that during withering lipids break down into simpler compounds and catechin levels decrease. Improper withering can cause adverse effects on subsequent manufacturing operations, such as maceration, rolling, fermentation, drying, and tea storage. Conclusion: Freshly harvested leaves are conditioned physically and chemically for subsequent processing. There is no specified withering duration, but 14-18 h is generally considered the optimum period. Proper and even withering of tea shoots greatly depends on the standards of plucking, handling, transportation, environmental conditions, time, and temperature. Thus, to ensure consumption of high quality tea, the withering step must be monitored carefully.